Resultados

Equilibrio
Datos
experimen
tales

Datos
teoricos

Proceso

Punto de
fusin
Punto de
L-V
ebullicin
S-L-V
Punto triple
Punto de
S-L (Hf=
fusin
2662.6J/mol)
normal
Punto de
L-V (Hv=
ebullicin
33001.3 J/mol)
normal
Condiciones
criticas
S-L

L-V (Hv=
31341.53
J/mol)

Evaporaci
n

S-V (Hsub =
35363.9

Sublimaci
n

Datos
claculados

P(mmH
g)

T/(C)

T/(K)

577

280.15

577

70

343.15

37

6.5

279.65

760

280.15

760

80.75

353.9

30552

280.25

553.4

96.7
119.6
577.0
718.7
811.6
437.9
391.0
179.6
21.3
9.2

22
27
70
77
81
2
0
-13
-43
-53

295.15
300.15
343.15
350.15
354.15
275.15
273.15
260.15
230.15
220.15

Ejemplos de clculos
P2=P1 e
P2=P1 e

H vap 1 1
( )
R
T2 T1

H 1 1
( )
R
T2 T1

96.7 mmHg=577 mmHge

437 mmHg=577 mmHg e

L-V
T/(K)

31341.53 J /mol
1
1
(

)
8.314 J / molK 295.15 K 343.15 K

35563.9 J/ mol
1
1
(

)
8.314 J /molK 275.15 K 280.15 K

S-L

P/
(mmHg)

T/(K)

S-V

P/
(mmHg)

T/(K)

280.15

48.8

280.15

577.0

275.15

285.15

61.8

285.15

739.7

273.15

290.15

77.6

290.15

940.3

260.15

P/
(mmHg)
28.85
25.76
11.83

295.15

96.7

295.15

1185.5

230.15
1.40

300.15

119.6

300.15

1483.2

343.15
350.15
354.15
378.95
395.75
412.55
429.35
446.15
462.95
479.75
496.55
513.35
530.15
553.4

577.0
718.7
811.6
1628.9
2484.9
3662.4
5236.5
7288.4
9903.7
13171.5
17182.7
22028.9
27800.7
30552

343.15
350.15
354.15
378.95
395.75
412.55
429.35
446.15
462.95
479.75
496.55
513.35
530.15
553.4

7778.5
9802.3
11141.2
23200.2
36191.3
54448.9
79340.1
112378.3
155202.6
209553.8
277248.0
360150.5
460149.4
630247.8

220.15

0.61