ame y 150 x 10° Pa (presién absoluta), El tanqu tiene ut 1 ajustado que permite cambiar el volumen, Determine la pre- ie tS AM ees EXECUTE: (a), R are constant so poate constant. = f WT, 0.750 m? (430K pn=n| | 2|=1.50%10' Pa) ed Pa iNT 480m |\300K EVALUATE: In pl’ = aRT , Tmust be in kelvins, even if we use a ratio of temp: QU Cr 4-200, oup anu pare uneeuy propuruuual ame we ean mE p= Pye Set Up: From Example 18.4, wee 10 when y =8863 m. Execute: For y=100m, AE <0, so p= pe =0.988p,. The density at sea level is 1.29 than the density at 100 m, EVALUATE: The pressure decreases with altitude, pV” -TeRr, so when the pressure decreases and 7 Consulte a tabla periddica en el Apéndice D y la tabla 14.1, a) j esel valor del oro aproximando al délar mas cercano? b) Si usted en ara an firma de nonita seivil cari al didmotrn do deta? 0 I HI py HE HH HLA HN p=mil. Set Up: For gold, M =196.97 yimol and p=19.3x10' kyim’. The volume ofa sphere of radius rs V’ =r EXECUTE: (a) m,, = 7M =(3.00 mol}(196.97 g/mol) = $90.9 g, The value of this mass of gold is (590.9 g)($14.75/g) =$8720. 0.5909 ky i () /=2-—— Es 6ui0? am’, V=tar" gives p 93el kg (0) _(aB.060° wy)” =A om 21 om Tha dinmatar ie Ye = 190 am:J HQUUH LINK), CURApUIe 2a CHELE LAS CHIEUGAD HuCUEAD UE IU He de tomos; b) la rapidez eficaz de sus moléculas. (Sugerencta: la periddica del Apéndice D da la masa molar (en g/mol) de todos lementoc hain el cimholo animien coresnondiente \ SerUr: M,,=20.180 ghnol, I, =8380 gino and M, =222 gil Execute: (a) K,,=+47" depends only onthe temperature soit is the same foreach species ofa mixture, y= fia. BSAt no oy, tm (h 22 gna 9 Vutr VM 20.18 g/mol Vauts VMy, 20.18 g/mol Yomts= (May . | 22 4g Vincan VM, 983.80 g/mol EVALUATE: The average kinetic energies are the same. The gas atoms with smaller mass have la consiste en un protén y un neutrén. El plasma de deuterones ¢ reactor de fusién nuclear debe calentarse a cerca de 300 millon kelvin. Calcule la rapidez eficaz de los deuterones. {Es una fra apreciable de la rapidez de la luz (¢ = 3.0 X 10° m/s)? b) {Qué te ratura tendria el plasma si la rapidez eficaz de los deuterones of 10? SETUP: Themass ofa deuteron is m =m, +m, =1.673x107 kg+1.675x10" ky=3.35x10" kg. €=300x10' ms, k=1.381x10 Vmolgcule:K , =1,93x108 ms, “= 648010", EXECUTE: (a) v= ie 1 ofr ig Jam aac, a)" (50381810 dolce K) EVALUATE: Even at very high temperatures and for this light nucleus, vis a small fraction of the speed of lightCl MITOgeNO gZuscoso UN)) y COMpurel CON Wi Gel agua uquida. nasa molar del N, es 28.0 g/mol. b) Se calienta 1.00 kg de agua, volumen constante de 1.00 L, de 20.0 °C a 30.0 °C enuna tetera. la misma cantidad de calor, ;cudntos kilogramos de aire a 20.0 °C odrian calentar a 30.0 °C? {Qué volumen (en litros) ocuparia ese 20.0 °C y 1.00 atm de presién? Suponga, para simplificar, que ae Inner nt C, =20.16 I/mol-K, le & 20,76 Jimol-K W 28,014.10" kgimol (b) To warm the water, Q=me, AT =(1.00 kg)(4190 Smol:K)(10.0 K)=4.19x10° J. Forair, pote HI OD gag pi 15.65 bg. Sl -K 293K) cy AP (141 Whg-K)(100K) 8 Tp RROTERIO” ginlfL 13x10 Pa) Fvariate: sie omallor fie Non lace heat ie needed for | boat No than far 10 ko af water QCA GEL 4170 UC aS HIUICCULLS CS TNCHUL Que a) LIU TIS, m/s; c) 500 mys? Use la tabla 182, La masa molar del N) De Bud EXECUTE: (a) cy = 1D hg: K. “+2565; ¢, is over five time larger. & fer 7" SETUP: For N,, M=280x10" kgmol, v/v,, =1.60. Vigg = So the temperature is ac UD = (4385x107 Ks’, HU.60)'R —3(1,60)'(8.3145 Jimol-K) (a) T= (4385.10 K-s/m’)(1500 ms)! =987 K (b) 7 =(4385x10"K 5/n'}(1000 ms)’ =438.Ka) {Qué presidn externa minima p, debe aplicarsele para observ: i riba la sucesién de transicion fase que se da si la presién aplicada p es tal que p < p,. b) Por; de cierta presién maxima p,, no se observa tansicién de ebull Determine esta presién. Describa la sucesién de transiciones di wniFY: Refer to the phase diagram in Figure 18.24 in the texibook, Up: For water the triple-point pressure is 610 Pa and the critical-point pressure is 2.212% 10" Pa , CUTE: (a) To observe a solid to liquid (melting) phase transition the pressure must be greater than the triple- { pressure, so p, =610 Pa. For p< p, the solid to vapor (sublimation) phase transition is observed. No liquid % vapor (boiling) phase transition is observed if the pressure is greater than the critical-point pressure. . a purillada. Inicialmente, ¢! tanque se lena hasta que la presién métrica es de 1.30 X 10° Pa y la temperatura .0 °C. La te: tura del gas se mantiene constante mientras el tanque fay mente hasta que la presién manométrica es de 2.50 X 10° Pa. ¢ la maca de nronana ane ce ensts pressures in the two states, Apply Eq,(18.4) to the initial state to calculate m,, SerUr: pl’ =aRP can be written pl’ =(m/M)RT 7, V.M, Rare all constant, so p/m=RT/MV =constant, So p,/mni =p, /m,, where m is the mass of the gas in the tank, Execure: _p,=1.30x10° Pa+1.01x10° Pa =140x10° Pa P2=250x10° Pa+1,01x10° Pa =3.51x10° Pa am, = pM RT: V =hA = har’ =(1.00 m).(0.060 m)* = 0.01131 m’ __(1.40>10° Pa)(0.01131 m’)(44.1% 10" kgimal) m = 0.2845 ky (8.3145 Jimol -K)((22.0+ 273.15) K) cal Ble 3.51x10" Pa) Then m, = of ‘ |xoms 4 a ae =00713 kg, ‘m, is the mass that remains in the tank. The mass that has been used is m, =n, = 0.2848 kg ~0.0713 kg =0.213 kgnly Ctl CUKTpO AIG UI CSUMUUNE Ue TIC Ue OY Ng. ONSITE! cuerpo humano es en su mayor parte agua (M = 18,0 g/mol) DENTIFY and SEC UPS. Apply £182) nd and then use Avogadro's number ota! te number ot okecules, 'NECUTE: Calculate the number of water molecules N, ath } 718x10" mol 18010” kana Vat, =QM8x1 ia x0" lel) 1,710" moles ‘ch water molecule has the aon, she number of alos is (710°) 28.1010" ams lander foes 12" =