Thermodynamic Properties of Ethylene from the Freezing Line to 450 K at Pressures to 260 MPa Majid Jahangiti, Richard T Jacobsen, and Richard B. Stewart (Contr for Applied Thermadonamic Studies. Cllee of Ensineria. University of Idaho, Mescow, Idaho 83643 and Robert D. McCarty Chemical Engineering Science Division, Notional Engineering Laboratory, National Bureau of Standards, Boulder, Colorado 80303 ‘Annew fundamental equation explicit in Helmholtz energy for thermodynamic prop- erties of ethylene from the freezing lin to 450 K at pressures to 260 MPa is presented. Independent equations for the vapor pressure forthe saturated liquid and vapor densities 1s functions of temperature, and for the ideal gas heat capacity are also included. The fundamental equation was selected from a comprehensive function of 100 terms on the basis ofa statistical analysis ofthe quality ofthe fit. The coefcients of the fundamental ‘equation were detcsusued Uy a weighted Ieaatnquaiea ts scested Pp-T* data, saturated liquid, and saturated vapor density data to define the phase equilibrium criteria for coexis- ‘tence, C, data, velocity of sound dats, and second virial coefficient data. The fundamental ‘cauation and the derivative functions for calculating internal energy, enthalpy, entropy, isochoric heat capacity (C,), isobaric heat capacity (C, ), and velocity of sound are included. Tables of thermodynamic properties of ethylene are given for liquid and vapor states within the range of validity ofthe fundamental equation. The fundamental equation teported here may generally bused to calculate pressures and densities with an uncertain ty of 40.1%, heat capacities within ++ 3% and velocity of sound values within + 1%. ‘Comparisons of calculated properties to experimental data are included to verify the accuracy of the formulation ‘Key words: density enthalpy and entropy equation of state ethylene; heat capacity; property table; ‘thermodynsmic properties velocity of sound Contents 1. Introduction... 596 Density 608 1.1. Prior Correlations of Ethylene Properties .. 596 3.4, The Melting Pressure Equation 610 12. The Fundamental Equation for Ethylene .. 397 4, Ideal Gas Heat Capacity. 610 2. Experimental Daa for the inglePBase Region 596 4.1. Experimental Dat ou PpT Data.. 598 42. Calculation of C; from Velocity of Sound - 611 tennant Teare Ho Capac) $88 EY. he Equation fo thn Ma Cae Hen Vals of Sound Date st Capacity nnn Viral Cofiiens. 600 5, TheDeterminaton of the Fundamental Equation 600 for Etylne on ow Si Sepmas” ‘Lew Squares "Tec wita Toenthlpivand isothermal Sule-Thomson Search Procedure ou Cocticints 60052. Preparation of Expesimenial Property Dat a8 oneal Pont fn Exlitglneteticinthe Ceara 6b 29, Tape Point GO 53, The Fundamental Equation ois 3. Ligid-Vapor and’ Solid-Ligud”Cocrscnse 5A, Derived Themodyuanic Proper woes 616 Proper, i 620 6. Compan ofthe Fndanentl Egon J The Vapor Pressure Eauation oo” Da ew 32. The Equation for the Satuatd” Vapor 1. Comparisons of the Fundamental Equation Density . ee orp? Data. «0 3.3, The Equation for the Seturted tiga GL Ligeia gion on (© 1986y the US, Serene of Commerce on bebalfof the United States ota cae omar an 4 ‘Teenie ened te Ancien Inte Pee te 613. Fluid ‘Region for Temperatures AOE SERS, cri Late kote ‘Above the Catia Tempersture +625 0047-2690706/020503-142/818.00 599 Phys. Chem. Ret. Data, Vol 16, No.2, 1086504, 6.14, Isotherms Temperature 6.2, Heat Capacity 62.1. Isochoric Heat Capacity 62.2. Isobaric Heat Capacity 63. Velocity of Sound 64. The Second Virial Coeficient Maxwell Criterion 1 Enthalpy /- nthalpy of Vapontzation. Joule-Thomson Coeficients ‘The Critical Region. Properties 7. Acknowledgments 8. References... Appendix Near the Critical oF Calenlatnd List of Tables 1. Prior cocrelations for ethyl Summary of Pp-T data for ethylene 3. Summary of experimental isochoric and ‘isobaric heat capacity for ethvlene nr 4. Summary of velocity of sound measurements for ethylene 5. Summary of vital coefficients for ethylene. Summary ofeapetaucutal data fo endaspy OF ethylene. 7. Summary ofexperimental data forthe enthalpy of vaporization ... 8. Summary of experimental isenthalpic and isothermal Joule-Thomson coeficients 9. Summary of reported critieal-point properties for ethylene 10. Summary of experimental values for the tiple point of ethylene... 11, Summary of vapor pressure data for ethylene 12 Summary of saturated vapor density data 13. Summary of saturated liquid density data 14, Coeflcients for coexistence property equations For eee 15, Summary of experimental values for melting pressure of ethylene. 16, Ideal gas neat capacity values for ethylene 17. Vibrational wave numbers for ethylene 18. Ideal gas heat capacity, enthalpy, and entropy from Eq. (4.3) with coeficients from Shiman- uchi (Ref 93) sn 19, Parameters considered in the determination of the equation of state for ethylene nw 20. Functions for fitting the fundamental equations of state to various data forms on. 21. Second virial coefciens used in the determin- ation of the equation of state 22, Gyctlicuts 1 the fundaucntal cation (Ea (5.9)] for ethylene (coefiients not listed are zer0) = 23, Summary comparisons to Pp-T” data not ine ‘cluded in Figs. 15 and 16 : 4 Phys Chom, Re. Data, Vo. 16, No.2, 1086, os 2s 023 os 626 635 6S 5 637 638 638 oa 644 085 397 398 a0 eu ot él as ois als 616 20 m4, 26. 2. 1B. 4 15. 16. 1 JAHANGIRI ET AL. Second viral coefficients for ethylene. ‘Comparisons of calculated values of enthalpy fn the saturation curve using Eg. (9.7) with data of Douslin and Harrison (Ref. 23) CCriticel-point properties of ethylene ‘Thermodlynamic properties f eatrated ethyl- ‘Thermodynamic properties of ethylene List of Figures Ethylene Pp-T data Eulilone P-7 data the ‘Ethylene heat capacity data Ethylene velocity of sound data Comparisons of vapor pressure values calclat- ‘ed from Eq, (3.1) to data for temperatures above 150K ‘Comparisons of vapor pressure values calulat- ed from Fg. (3.1) te data for temperatures be- low 150K, ‘Comparisons of saturation temperatures caleu- lated from Fa. (3.1) to data Comparisons of (dP/dT), values calculated from Eq. (3.1) todata of Douslin and Harrison (Ref. 23) ‘Comparisons of sauraued vapor Getty values calculated from Eq. (3.2) to data... ‘Comparisons of saturated lguid density values calculated from Eq, (3.3) 10 488 on ‘Comparisons of ideal gas heat capacity values ‘to alculated values from Eq. (4.3) with vibra- tional assignments of Shimanouchi (Ref. 93) Fit 30 W300 Kenan Bihylene Pp-T data used in the determination of the fundamental equation ... Ethylene isochoric heat capacity data of Weber (Ref. 36) used in the determination ofthe fun- damental equation. Ethylene velocity of sound data used inthe de- ‘eriination 0 Uke Qala equations ‘Comparisons of calculated values of density to data for the liquid below the critical tempera- tre a ‘Comparisons of calculated values of density to data for the vapor below the critical tempera- ture ‘Comparnons of calculated values of density to ‘data for fui states above the critical tempera- 11 vane ‘Comparisons of calculated values of density to data near the critical temperature (T,, = 282.3452 K, p, = 7.6340 mol/dm’.. Comparisons of clelated values of isochoric Wea Capaety, Cy WW MAE son Comparisons of calculated values of heat ca- pacity, C,, to data from Weber (Ref. 36) Comparisons of calculated values of isobaric ‘eat capacity, C,, to data from Vashchenko et ical vi 635 er 638 646 656 599 ol 602 or 7 on 617 61s ar 0622 2B, 25, 26, 2. 28 ‘THERMODYNAMIC PROPERTIES OF ETHYLENE al. (Ref. 92) 630 porizaton from Eq, (5.7) to data Comparisons of calculated values of ‘soberic 28. Comparisons of Pp-T dats for ethylene inthe heat capacity, Cy, to data 630 critical region Comparisons of calculated values of velocity of 30. Comparisons ofcalculted values of pressure to oN 10 dal. 6 data in the critical region ‘Comparisons of calculated values ofthe veloc: 41. Pressure deviations of equation of sate and P- {ty ofsound at seturation to data os pT data irom the revised and extended sealing ‘Comparisons of calculated second virial coe. ‘equation inthe critical region. (The 2ero devi- cients with values from other soures (valves of ation ines the formulation of Levelt Sengerset ‘Thomas and Truppenire sock were culelated ft. at 1) by Level Sengers and Hastings (Ref 47) from 32, Density deviations of equation of state and Pp- data given in Refs. 7 and 26 respectively 634 TT data from the revised and extended scaling ‘Comparisons of selected coexistence property ‘equation inthe critical region. [The zero devi- dataand values calculated from Eq. (5.7) using ation lines the formulation of Levelt Sengerset the Maxwell criterion (equal area principle) al, (Ref. 12)] with calculated values from Eqs. (3.0, 3.2, 33. Comparisons of calculated derived properties nd (3.9) 06 from thi work (isothermal Hse) t0 valoee ‘Comparisons of calculated values of enthalpy from in sae formulations (Ret. 12) (oe to data of Dawe and Snowdon (Ref. 56) or line of plots) Comparisons of calculated values of heat of va Nomenciature Symbol Physical quantity Unit T Temperature K P Pressure Mea ° Density smol/dmm* » ‘Molar volume m*/mol z Comproosbility aston, Z— P/pRT uv Internal energy Jol 4 Helmholtz enerey Ymol 6 Gibbs energy mol H Enthalpy 4/mol s Entropy 3/(m01K) G Isobar heat capacity I/(mol K) & Toshorie heat oupacity Tmo) oa ‘Two-phase heat capacity Jmol K) r Heat capacity ratio w Velocity of sound m/s B Second virial coefcient ém"/mol c ‘Third virial coefficient (€m*/mol)? D Fourth virilcoeficient (ém"/mol)* (@P/ap) Totherm derivative a MPa/mol Pian), sochore derivative MPa/K R Gas constant (8.314 34) Imo K) u ‘Molecular weight of ethylene (28.054) a Planck's constant (6.626 196% 10) Is € ‘Speed of light in vacuum (2.997 925 0% 10") ms k Boltzmann's constant (1,380 622% 10-®) VK x ‘Acoustic virial am'/mol # IsenthalpicJoule-Thomson coefcient K/MPs 4 Isothermal Joule-Thomson coefficient I/(snol MPa) @ Reduced Helmholtz energy, a = A/RT 78 Reduced temperature, r= 7./T 6 Reduced density, = p/p. Superscript deal gas property es a0 oat on J.Phys. Chem. Ref. Data, Vol. 15, No.2, 1986,596 JAHANGIRI ET AL. Subscripts o Reference state property e CCritiea-point property o Property at saturation Triple point property ean Calenlated neing an nation ‘ata Experimental value bp ‘Normal boiling point sv Saturated vapor oe Saturated lid tp ‘Triple point (vapor) tpl Triple point (liquid) ‘Aduitional abbrevia K kelvins MPa ‘megapascals (10 pascals) kPa Keilopacsals (10° pascal) exp Exponential function a Difference Fixed Points for Ethylene Quantity Value Citic temperature 282.3452 K, Critical pressure 5.0401 MPa. Crtical density 7.634 mol/dm" ‘Triple point temperature 103.986 K 1.225% 10-* MPa 1428 45%10~* mol/dm? ‘Triple point pressure ‘Triple point density (enpor) 1. Introduction Ethylene is produced commercially in large-scale plants ands frequently distributed through pipelines. Accu- rate tables of thermodynamic and transport properties of caiylene ure esental for technological calculations in equip- ‘ment design, effective process control, sa storage, and equi table custody transfer. Although in 1977 the U.S. produc- tion of ethylene ranked fifth in all chemicals and fist in petrochemicals, its thermodynamic properties have not been known with high accuracy until recently. ‘Throughout this manuseript the word “data” is used to sefer w eapesivenal ieasutenients. The cers “formule tion’ refers to the equation or equations necessary to caleu- late fluid properties from a correlation. The term “funda- ‘mental equation” is used to describe the equation of state ‘used in this work. The ideal gas heat capacity representation js an integral part ofthe fundamental equation, while with, some other equation of state forms a separate equation for ideal yas heat capacity is required. Ancillary equations for the vapor pressure, saturated liquid density, and saturated ‘vapor density are used to calculate values to define liguid~ vapor coexistence states in the development of the funds ‘mental equation. These ancillary equations are also useful as, ‘4. Phys.Chem. Ret. Dat, Vol. 15, No.2, 1805 ‘Triple point density (liquid) 23.348 mol/dm? ‘Normal boiling point temperature 169.35 K ‘Normal boiling point density (vapor) 0.074 40 mol/am? ‘Normal bouimg point density (iguid) 20.247 mol/dmm* Reference temperature 298.18 K Reference enthalpy at Ty 29 6103/mol Reference entropy at Ty 219.295 1/(mol K) ‘stimating functions for defining saturated states using the Maxwell erterion for phase equilibrium. 1.1. Prior Correlations of Ethylene Properties ‘A comprehensive correlation and evaluation of ethy!- ene data was reported by Angus ea in 1972, This correla- tion did much to demonstrate that new measurements ofthe thermodynamic properties of ethylene were needed. Indus- trial needs for critically evaluated P.p-7' data for ethylene ‘were asessed at a symposium in 1972.* Following this sym- posium, a joint industry-government ethylene project was freatea under the aaministration or the Umice oF Stanaara Reference Data of the National Bureau of Standards (NBS) to respond to the industrial and scientific needs that had ‘heen identified. Tn subsequent years. new penperty measre- ments were made including measurements inthe critical re- gion, and several thermodynamic models (equations of state) representing these data were published. Most ofthese ‘equations of state Were restricted to a par of the thermody- namic surface. ‘Angus eal? and Vashchenko eral discussed several correlations published prior to 1972. Although these corre- lations are of historical interest, they are not discussed in‘THERMODYNAMIC PROPERTIES OF ETHYLENE ‘hee 597 Sip prercre in oases acest saeate-se cath (oes) detail here. The correlations summarized in Table include those which represent ony a portion ofthe surface of state for ethylene in adition to those based on wide-range eq tions of state. These earlier correlations, especialy that of Angus otal,” provided interim properties of ethylene for use in commerce, and perhaps more significantly, created an awarencs ofthe ned for more accurate experimental prop- ety measurements. Both Angus et land Vashchenko et a*extende the ranges of validity in temperature and pres sue ofthe prior cortelatons for ethylene. In 1981, MoCarty and Jacobsen* published a 32-erm pressure explicit equation of state for ethylene with a range ‘oF validity to 40 MP in pressure for temperatures from the triple point temperature (103.986 K) to 423 K, Compari- sons of ealculated properties tothe experimental Pp-T and other property data were included. The possibilities of using ferent forms ofthe equation of state and new modeling techniques for improving the representation ofthe thermo- dynamic ourface of atte wore ditewioed. In prtivular the ‘need for improvements in the accuracy of the equation of state were needed forthe citicl region and the low-tem- erature lgid and vapor region near the vapor resure ‘were identi 4.2, The Fundamental Equation for Ethylene The fundamental equation used in his work i expici in reduced Helmbota energy, and other thermodynamic properties are derived from iby dferentiaton The coefi- ets ofthe fundameual equa were detetsoel esi teat squaresegresion procedure’ Torslection on op Simm grovp of terms fom an ntl bak of 100 propoed terms, Dat elected for determing the coficient ofthe fundamental equation are denied in Seo 3The range of validity ofthe fundamental equation for ethylene is from the freezing line to 430 K at pressures to 260 MPa. With a few ‘exceptions, the equation presented here represents the se- lected experimental Pp-T' data to within the estimated ac- coracie of theve data, ‘Throughout this paper, comparisons of calculated Droperties to experimental data are used asthe bass for va- lidity and estimated accuracy ofthe correlation In all com- parisons given, percentage deviations are defined as [en —Aoe)/Kae)] 100, aay where X isthe property compared. Detailed comparisons of calculated thermodynamic properties to experimental data are given in Sec 6 In addition to the fundamental equation, ancillary ‘unclons tnciuaing a vapor pressure equation, equations tor the density of the saturated liquid and saturated vapor, and ‘an equation forthe ideal gas heat capacity are given. Sum= rmaries ofthe available data for these properties of ethylene are given, and the ranges ofthese data are tabulated. ‘The fundamental equation may be used forthe calcula tion of accurate tables of thermodynamic properties of ethyl- lene within ts range of applicability. 1s equation may also ‘be used readily for systems analysis where iterative solutions are required to solve the equation for known variable pairs other than density and temperature. The fundamental equse tion was developed to conform to the Maxwell criterion for Tiquid-vapor phase equilibrium The fundamental equation given here is accurate in the critical region to within 0.1% in pressure. However, for accurate property determination in ‘the critical region, the revised and extended sealing formula- tion of Levelt Sengers eta.” should be used. ‘The thermodynamic property correlation for ethylene reported here represents specific improvements over that of 4. Phys. Chem. ef. Data, Vol 15, No.2, 1986500 “MoCarty and Jacobsen! a follows: (1) The range ofthe correlation has been extended to include al ofthe availabe data (2) The accuracy of the ideal gas heat capacity equa- tion has ben improved. (G) Saturated igui and vapor densities consistent with ‘thebest single-phase data in adjacent egions have been used in the development ofthe formulation. The eitical region Iehavinr af ealeated extvestion donsitiog es heer tme proved to agre with that of ther of Levelt Sengers etal? 2, Experimental Data for the Single-Phase Region ‘The available experimental data for ethylene are dis- ‘cussed below. These data were the bass forthe development of the new thermodynamic property formulation for ethyl- ene reported here. Some of the data in the selected data sets ‘were not sed in determining the equation of state. Howeves, all available data were compared to values calculated with ‘the formulation. Sources for experimental property data ‘with temperature, pressure and density ranges. uncertain- tie, and sample purities are tabulated. 241. Pip-T Data ‘Theexperimental P-p-T data for ethylene are summar~ ized in Table 2. The distribution of these data is shown in YANIANOIRI ET AL. Fig. 1, For clavty of illustration, Pp-T' data for ethylene in thecritcal region ae shown separately in Fig 2. The data of Calado eta.” and Roper" at low pressure, and the data of Ku and Dodge! and of Sass eta.” inthe vapor region are not included in Fig 1. Further discussion of the data used in this work is gtven by Jahangir. * ‘The unpublished low-density experimental Pyp-T data cof Waxman”™ from the National Bureau of Standards in Workington, TWO, which were aktsined for the Aatwrrinas ton of the second virial coeficients reported by Waxman and Davis" in 1976, were not used inthe development ofthe fundamental equation ofthis work. 2.2. Isochoric and Isobaric Heat Capacity ‘The reported measurements ofthe isochoric and iso- brie neat capacity for emylene are summarized in Table >. Figure 3 shows most ofthe recent experimental heat capac- ity data for ethylene on P-T coordinates. The 12 values of saturated liquid heat capacity of Weber" below 0.1 MPa are also included in Fig, 3.A preliminary formulation was used to calculate pressure for heat capacity data for which the experimental pressure was not reported by the author. 2.3, Velocity of Sound Data ‘There are extensive measurements of velocity of sound for ethylene, especially in the vapor region. The sources of these data are summarized in Table 4, and Fig. 4 shows the Insver of teste Tageratare omasty MST AY OT tepersture ar oroats oe te) tse nai .2069,06 14 0.06 wo? 28 “namo on sone urns se nent ante wn sae! Mem soe) mate 5 ese, sates tts rd These ats ve Ber prscnd 5 ows of Tanne oa 4: ye: Ohne Baty Yo 18H 8 1900‘THERMODYNAMIC PROPERTIES OF ETHYLENE 599 PRESSURE (ldPa) TEMPERATURE (K) ic Bayle Pp da, PRESSURE (MPa) DENSITY (mol/dm*) i Ryne pe al ep 4. Phys. Chem. Rt, Dat, Vo. 18,No.2, 1986600 distribution ofthese data on P-T coordinates. In Fig. 4, five Jow-presure dat pints of Gammon on thesaturation line sxe not shown. Figure shows that the avaliable daa forthe velocity of sound of ethylene cover most ofthe vapor surface above 0.02 MPa in pressure, and that only the data of Dregulyas and Stavizv are available in the iid region. Other sources for reported values of velocity of sound for ethylene which were not included here are discussed by Vashchenko etal 2.4, Virial Coefficients ‘There are many reported values for the second virial cvefficients of etiylene for temperatures frou 200 (0448 K. ‘The most recent data are those of Douslin and Harrison,” Levelt Sengers and Hastings,” and Waxman and Davis.” Discrepancies ofthe data from other sources with the select- ced data (see Sec. 5.3) may be attributed to the associated experimental procedures and to considerations of impurities and absorption. Table S summarizes the sources forthe viral coemetents or exnylene. Usually, accurate second virial coeficients are derived from experimental low-density compressibility data ob- tained hy the Rinenett method or hy other methods. hut val ues can also be calculated from other experimental proper- ties such as velocity of sound data.*** Values ofthe second virial coefcient determined from refractive index, reported by Ashton and Halberstadt,” are consistently higher than the other available data. Evaluation of virial coeficients from Joule-Thomson coeficients and heat capacity was dis- etc by Charnley eral and Vashchenka etal,“ such values were not used in this work. 2.5. Enthalpy Data ‘The four sources of enthalpy data considered in this work are summarized in Table 6. These values have been ineed only for comparison to caletated vals, 2.6. Heat of Vaporization Data ‘There are few reported experimental values of the heat ‘of vaporization (latent hea) for ethylene. The experimental ata for heat of vaporization are summarized in Table 6. 2.7. Isenthalpic and Isothermal Joule~Thomson Coefficients: ‘Table 8 is a summary of reported experimental values {for adiabatic and isothermal Joule-Thomson coefficients. Experimental values of isenthalpic Joule-Thomson coefi- cient, = (OT /OP)y, were not used in this Work. Values of (AT/AP)y from an experiment in which a gus is expanded through an orifice to atmospheric pressure (reported as the temperature difference of the eas at hath sides ofthe orifice) are reported as integral isenthalpic Joule~-Thomson coefi- cients **** Values ofthe isothermal Joule-Thomson coefi- cients § = (@H /4P) for ethylene ae reported by Hejmadi and Powers,”* Fan,"“and Charnley etal.” 4 Phys. Chem. Ref. Data Vol. 15, No.2 1988 JAHANGIRI ET AL. 2.8. Critical Point “The diiculties of experimental determination of the rtcal parameter are the cave of consderahle differences among the reslts obtained bythe various investigators. A detailed analysis ofthe methods and results of investigations ofthe critical parameters of ethylene given by Moldover.* The eriticl density cannot be defined accurately by exper- rent because of the infinite compressibility atthe critical point and the associated dificult of reaching thermody- ‘namic equilibrium. Therefore, reported values fr the eri cal density are caleulated ether by extrapolation of rectlin- ar diameters ulizing measured saturation densities, or by correlating single-phase data close to the critical point. Re- ‘ent reported temperature and pressure measurements for the critical point of ethylene are listed in Table 9. The selec ed criticakpoint parameters are 7, = 282.3452 K, Ty ~ 2.0401 Mio, ale 7-094 eal” “Hastings era, atthe National Bureau of Standards in Washinaton, DC, calculated the critical parameters from their Pp-T data inthe erica region using a revised and extended scaling equation. These values are in good agree- ‘ment with those of Douslin and Harrison®* and of Mol- dover," uid were use the devekoptet of the func tal equation inthis work 2.9. Triple Point ‘The triple point temperature for ethylene hasbeen mea- sured extensively, but the pressure of the triple point was reported only by Bigeleisen eral and by Clusius and Wei- gand." Sources of triple point data are liste in Table 10. ‘The elected temperature and pressure forthe triple point in this workare 103.986 4 0.003 K from Straty¥ and 0.000 12, MPa from Bigeleisen etal, respectively 3, Liquid-Vapor and Solid-Liquid Coexistence Properties Paceot emphasis on the inclosion of cxtical cepion properties in a wide range formulation for ethylene has Prompted the development ofthe vapor pressure equation snd equations for the density ofthe saturated liquid and the Saturated vapor as functions of temperature which include {he critical region data. New equations for coexistence prop- cetis, consistent with the revised and extended scaling for tuulation of Levele Senger oa in he ortel region, are {given below and are compared todata, The functional forms forthe ancillary equations reported here are similar to those reported by Wagner and Ewers® and by Pentermann and Wagner.” 2.1. The Vapor Pressure Equation “The functional form for the vapor pressure equation is m(P/P, (IDE NA-T/T 7, GAY‘THERMODYNAMIC PROPERTIES OF ETHYLENE 60 sauce or citer "tege™ "Yaege™ "Rta, wo sett eee suate Tae eat Camel Th te ak ancl FW antl ee Te) nen mg om rr 2.001 at ce wagt a mum ea ste veer weg O47 ma sens eer aaa ea ug? @ koe com an ym krmaroh gm Ges nse ae ene? meg 9538 eB vse 30. : — e S w © 5 3 wo « & aio 20 «260 ad0 a0 alo ae = TEMPERATURE (K) ‘ie 3. yen eat copay at, 4 Phys. Chem, Ret Data, Vol. 15, No.2, 1986,602 JAHANGIRI ET AL, fmter of romere Tomoratare potty CSTR CATION BCS caperstare Mt oe ee ee eee ee ere SOL oe vom nak eat tent eee me ‘toa ao ees 10. Seren wt . 7 . aril | i] 1 fe {: { z - i: ea 2 Apps tT : é Hg ace oa wt ee et age g ae g : g : # : z 5 oo : not TEMPERATURE (K) ee 4 Phys. Chem. Ret. Data, Vol. 16, No.2, 1906‘THERMODYNAMIC PROPERTIES OF ETHYLENE 603 ee = oe ae om & os ron rome? thas mma ns eg eC . a Cuisine nen 4: Phys. Chom. Re. Data, Vt 15, No.2, 1905604 JAHANGIRI ET AL. Tavle 65 sumary of experimental cata for entnaloy of ethylene amer oF Teaperature Pressure reertatety saree rae rains tae ge see etenaey i (oes) ime ave & stowon® we ae ons 1 sos Deuslin b aretsen?? 976 » naan 3.997 egmaat 4 Pvers?® an ma mene nates 3.98 “e plgronied tn gresure for 12 Teotharna based un experinental SruerThoneencaefftetentes source veer Tenge sn agers etme wo teres) clasts a romereas™ ne . ea 2 apt ouelin tarrteo®® gee nae cos x nase 58 9.307 joel 8 rovar® m9 2 aoe tr1s86 9 Tita tee cried bw store ran Beir Pac RRR ‘able 6. Simary of experimental Isenhalpte an 1sothema JutesTnnson coefficients 7 re ‘essere CTmgeratore rity of w tree) cooteney lsethalpiedovle- Tomson cost fitent etn? an ws.m mate wrs.68 ee it mse ans is.68 va Charney et 2.5 1986 ee wea as rs.t6 es ret 1see a pease 4.88.8 rs. 3.9 Salues vere poral grapticatiy. alate mere reports as polynental function of pressure for sich other. 4 Phys. Chem, Ret Data, Vol. 15, No.2, 18‘THERMODYNAMIC PROPERTIES OF ETHYLENE 605 a i orig ‘ai oto) perce) enue we ranean rence wr ross ma repeaters ot 12 ee wos 8 toot? wm soe a sings at 108 ate? nne528.0n7 5.010.002 7.6000.0009 9.998 2 nee tt mre ae rks (Fe SOL 4 fron a rte mtn.) hasan & Megat? 18k cat (te agen? wns tanaese.1 x geteean et alt? a7 csi 8) ne surat rstoe 13. 5050.008 wise so sige yn ad fg” lyin esse of Speen et a, mary of veer reser ate for eye = a — ‘oereent} on ca 10 » wae 0.085 ‘3012 508 bassin A artson a ® ore 0m uote: wis nn Soro we = kane 8 attest ts strat 2” mae oon as tse v.90 rat ‘ mea 008 mre 9.309 Fass eae a, ‘4. Phys. Chem, Ret Dats, Vl. 15, No.2, 1906606 where P, and T, are the critical pressure and the ertical temperature respectively. This functional form was used t0 represent selected vapor pressure data for ethylene by appli- cation ofa least-squares selection algorithm published by de Reuck and Armstrong." The algorithm selected an opt sum repeetentation from among the IT terme of Eq. (3.1) ‘based upon a statistical analysis of the quality of the correla- tion. No critical-point constraints were used. Arbitrary ‘weights were assigned to individual data points a required todevelop the best it of the equation to the selected data Table 11 is a summary of the vapor pressure data for ‘thylene. Estimates of the uncertainty of each data set as reported by the author(s) are included where available. ‘These data cover the temperature range from the triple point (Ty, = 103.986K) tothecritical point (7, = 282.3452 K). Gammon" isthe only source of data that covers the entire range from the triple point to the critical point. Additional sources for experimental vapor pressure data for ethylene are discussed by Angus eal and Vashchenko et alt ‘The data selected for devalopment of this equation for temperatures above 230 K were those of Hastings eral.” from 231 to 279.15 K. Since the experimental values of ve- locity of sound of Gammon" were used for determination of the coefficients ofthe fundamental equation, the vapor pres- ‘ure values of Gammon‘? were selected for this correlation in the range of temperatures from 133 to 238 K. For tem= ee JAHANGIRI ET AL. peratures below 225 K, the reported values of Gammon'* differ considerably from those of Bigeleisen et a. (about 259 in pressure at the triple point). Although the experi- ‘mental values for vapor pressure by Bigeleisen eral’ in- clude more significant figures at low temperatures then those of Gammon, the relationship of the temperate scale ofthese data to IPTS-68 was not known, The triple point at 103.986 K and 0,000 12 MPa was included in the correlation. Coeficents for Eq, (3.1) are given in Table 14, ‘Comparisons ofthis equation fo the vapor pressure data for ethylene and to the vapor pressure equation of McCarty and Jacobsen* are given in Figs. 5, 6, nd 7. Figure 6 illus- trates the vapor pressure differences between data and values calculated from Eq, (3.1) for temperatures below 150 K. Figure 7 illustrates deviations of saturation temperatures calculated iteratively from Eq. (3.1). The differences ‘between calculated values and data below 200 K, including those of Tickner and Lossing'* and Lossing™ are large, even ‘though the differences are within the estimated experimental uncertaintios of the data. Dowslin and Harrison? reported experimental values fr the slope ofthe vapor pressure (dP / 447)... Comparisons of these values with slopes from Eq, (3.1) (the zero line of the graph) are shown in Fig. 8. Slopes of the vapor pressure Eq. (3.1) are in agreement with the values from Douslin and Harrison* within + 0.08% for ‘temperatures below 279 K. For temperatures near the criti- ; 2 oe a : orcas mt : mee 58 ie aio ats ate as Sor 2 0.20 © 0.00 » ecg me +i — wet 0.149 $d 278 9 280 281 TEMPERATURE (K) ic 5, Comparisons of vapor pressure values clelted from Eq, (3.1) to data for terpeatres above 10K. 4: Phys. Chem. Ret. Data, Vol. 15. No. 2.1996 262 283THERMODYNAMIC PROPERTIES OF ETHYLENE or Foe e § £0.20 0.20 cee cop LE eS ds teats ido" sds isa ‘TEMPERATURE (K) is, 6 Comparisons of vapor pest values clelted from Bq, (.1) te dt for tempeatres blow 150K. Taata oan. 6 1% oe 28 20 2 ‘be TEMPERATURE (K) io 7. Comparisons of stration temperatures caleulted from Eg (3.1) to dt, J. Pha. Cham 8 Data, VoL. 15, No. 2, 1988,3 JAHANGIRI ET AL. z 0.20 = ° 20 BE os Es <& 0.10 o' ae ° @ , aos ° me ° Cast) O=0 Bie 0.004 ua OG -0.05 cl T TEMPFRATURF (K) Fic § Comparisons of (4P 47), vale alealated fom Eq. (31) t data of Desi and Haris (Ref. 23) cal temperature, the deviations are a large as 0.2%. In Fig, 26, caleulated vapor pressures from Eq. (3.1) are compared te values valvulated wing Une Cendant suation [De (0). 8.2. The Equation for the Saturated Vapor Density ‘The functional form of the equation for the saturated vapor density is Inipev/p. where 1=(T, ~7)/T, @ dim, he ertca density. “The saturated vapor density data for ethylene consid- cred inthis work are summarized in Table 12. Other sources for reported saturated vapor density are discussed by Vash- chenko et a Saturated vapor density values for tempera tures from the triple point to 192 K were calculated by inter- secting the vapor pressure from Eq, (3.1) with an equation Of state reportea By McCarty," Which is alia Yor tne Vapor Aeosites up to 2.0 mol/dm’. The values from the equation of state by McCarty" for temperatures below 192 K, the data fT evel Sengrrs at forthe ramon 770 0364 K Conch ing one data value at 231 K), and values calculated from the revised and extended scaling equation published by Levelt Sengers ef a.™ between 281.4 and 282.345 K were used to Getcrmine the costicients tor Bq. (5.2) which are gwen in ‘Teble 14. The deviations of values calculated using this equa- tion from data are illustrated in Fig. 9. The overall agree- ment ofthis equation with the data selected for determining the coefficients of Eq. (3.2) is within + 0.2% in density. Values reported by Douslin and Harrison” were not included in the data selected for usein the correlation inthis region, There ae deviations of as much as — 0.3% in den- sity of these data from calculated values! at temperatures near the critical temperature. Calculated values from Eq. (3.2) were sed in the data set for determining couficionts of the fundamental equation. (32) $ venom, 7.634 mol/ Tes and 4 Phys. Chem. Ret: Data, Vol 15, No.2, 1886, 3.3. The Equation for the Saturated Liquid Density ‘The functional form of the equation for the saturated liquid density is ale)—1= FE Magu Ot F New? +N ln + Nay, (33) wherer = (1. ~ 1)/Tand8 = 7/T.-Thsfunctinal form includes one term similar to those of the revised and ex- tended scaling equation." This functional form is incorrect at the eitical point, ie, at T= T.s pa, #2 ‘The recent values of saturated liquid density data for ethylene thar were considered inthis work are summarized in Table 13. The data used to determine the coefficients for Eq, (3.3) were those of Haynes”? and values calculated from the revised and extended scaling equation" between, 280.8 and 282.3451 K. The coeficients for Ea. (3.3) are Bivenin Table 14 The overall scatter of the reported experi- ‘mental dataisabout + 0.3% in density from the triple point { the entucal point, as lustratea in ig 1U. Ene values Of Menes etal are in agreement with those of Haynes” to ‘within 0.19 in density for temperatures below 200K. Also, shuns af Daan and Harrison® exhibited 0.1% deviation in density from those of Haynes Comparisons of density values calculating using Eq, (3.3) with the selected data in- dicate agreement within 0.04% in density. Smoothed satu- rated liquid density values trom Eq, (5.5) were used with saturated vapor density values from Eq, (3.2) inthe deta set for determining the coeficients of the fundamental equa- cen we me ne w7 ° ° Eon a © 6 5 = -02 2 : s 9 eat tr tn ° a us x alent fan NON ae a £ aun wr pee st 93) hoo" ias' 180 tts * 200" as’ 280" as 300 eo 0.2 ao Be o.¢f i ey & -o.1 0.2 0.9 ° ae 260 abi ate TEMPERATURE (K) 1B, Samury of saturates Tut density ata source var "poate vie waite eae ene ea. 1s » os come ae 98 tows tnurrise®® 076 « nome 0.005 koe vis68 v0 Cotovtts & temaret™ ar » 105-0 astige Leet Seger 1900 , meee 008 x om ota? 8 9.908 J: Phys. Chem. Ret Data, Vol. 15, No.2 1086ere wear ti se ee nares * he iaaraat wer encanta GL fe estan = ese he sts ‘aires aie teal eae Gy JAHANGIRI ET AL. 3.4. The Melting Pressure Equation Sources forthe experimental value ofthe melting pres- sure or ethylene are listed in Table 15. The data of Reeves et al.” exhibit deviations as large as 159 from the experimen- tal values of Straty” and from those of Clusius and Kon- nertz? In 1980, Steaty” published a Simon equation for ethylene, P= Po ta[(T/T)— 1], Ga) where Py = 0.000 12 MPa, d= 357.928 Ma, € = 2.008, and Tyy = 103.986 +. 0.003 K. This equation predicts the ata of Straty™ within + 0.2% in melting pressure 4, Ideal Gas Heat Capacity In the calculation of thermodynamic properties ofeth- yilene, an equation for the ideal gas heat capacity C; is used inthe calcultion of eal @uid enthalpy, entropy, cai capac- ties, and velocity of sound. Dip et 02 Fee ae etd PERCENT DEVIATICN IN SATURATED LIQUID DENSITY a.) a3 ° no. ° oe a oot? ergy ae 20 air 22 29 ‘Fic 10. Comparisons of saturated lui dees values uzlated frm Eq (3) to data 4. Phys: Chom, Ret. Dats, Vol 16, No.2, 1986‘THERMODYNAMIC PROPERTIES OF ETHYLENE eu Table 15, Sumary of exerinental values for melting pressure of ethylene umber of Tenperature Pressure temperature varity of Source Year points." range ‘ange scale sample Ww (ia) (percent) Solig-Itquia Clustus & Weigand’? 1940 B 103-105 09.6 Reeves et at.79 19688 103-223 -1000 49.001 Straty*# 1980 6 104-109 TPTS-68 99,999 do.008 S01 id-vapor, Bigeletsen et at.® 1977 8 92-103.9 054.0.9 99.999 20.05, (om 9) 3 the experinental data are also epresented by a Sinon equation (3.4). 4.1. Experimental Data ‘The ideal gas heat capacity data for ethylene presented in various references are either experimental measurements of heat capacity at low pressure or calculations based on. spectroscopic data. Above 273 K, the spectroscopic date are ‘considered more reliable. For temperatures below 273 K, the ‘only sources of deal gas heat capacity of ethylene are values ‘derived from measurements of heat capacity or velocity of sound at low pressures, The accuracy of such data is less ‘than that of comparable values calculated from spectzoscop- jc data. The data for ideal eas heat capacity for ethylene ‘considered here are summarized in Table 16. The vibrational ‘wave numbers from spectroscopic data from Herzberg and, ‘Shimanouchi™ listed in Table 17 may be used in conjunction, ‘with the theoretical model described in Sec. 4.8 for thecaleu- lation of C;. The wave numbers forthe 12 vibrational modes ‘of ethylene from Shimanovchi” and Herzberg are given in, ‘Table 17 wet a a wm ee, 4.2 Caleulation of C; trom Velocity of Sound “Mei and Moldover" obtained the C, values for ehyl- neby iting to polynomial funtion of pressure thet low- pressure velocity of sound data. published by Mebl and Mol- dover foreach of five temperatures ranging from 273 t0 373 K. The function i w tO P 4 0PPb, any where ay = 7oRT/M. ‘The values of 7 calculate from ay were used to obtain C3/R=7/0~D. (42) ‘These data, reported by Mel and Moldoves* are in close agreement with C} values calculated from spectro- scopic wave numbers given by Herzberg" using a sum of tos er sah ost 4. Phys. Chom, Re. Data, Vol 15, No.2, 1088612 4.3. The Equation for the ideal Gas Heal Capacity The sbarc hea capacity C; ithe sm of conti sons trom several era) frts Wilding te tele movement of the mola, that frm rotons rom “aru vibrational mes, the pr contbutedbyeletonc {xcitation consbution rom interaction een oaion and vibration, and the lo-tempeatre rotational comp nen. The various modes of exttion may be defined a terms of idealized models sucha: he rid rotator and ha ton testo. “The eqation ised forthe del ga heat capacity is ie ce 1P whereu, = (0,/7)8, = hea / his Planes constant, cs {hepeedolight in vacium, ithe vibrational wave num. terand kis Bltomann'sconstan. The value fe wed a thinworkis 1436852 Sem K, The vals of werecale Inted using Eq. (4.3) with the vibrational wave numbers ftom Shimanouch™ given in Tobe 17. ompaisons of Cs ‘aloes up 10 00 Kate given in ip. 1 “The enthalpy and entropy ofthe el es ecved from (63) reece by EAA) and (3), rep tively Gas § R aan a.eh Site trou Pp PERCENT DEVIATION IN C° we eae ee ‘se JAHANGIRI ET AL, WD =WS app gg BPH HOH ery e oc an +e ET. ae Srp) —s5 @ janine en 3 HY ier pee esac lt IMP), «as where J" — 29 610 (3/mol) is the ideal gas reference enth- alpy at T, = 298.15 K, and $” = 219.225 (J/mol K) is the ideal gas entropy ofthe reference state at Ty = 298.15 K and P= 0.101 325 MPa (1 atm), Calculated values forthe ideal gas heat capacity, enth- alpy, and entropy from Eqs. (43), (4.4), and (4.5) with vibrational assignments from Shimanouchi” are given in Table 1, The Determination of the Fundamental Equation for Ethylene ‘This work isa more accurate representation of the ther- ‘modynamic property data for ethylene than the prior formu lation by MeCarty and Jacobsen,” for states inthe ertial ais senses TEMPERATURE (K) Fic 11. Comparisons fie as et capaci ae toca values fom E(4.) with ibatinal asignnents of Skimanovshi (Ret 83) from 010 4. Phys Chem, Rt. Dats, Vo. 15, No.2, 1986‘THERMODYNAMIC PROPERTIES OF ETHYLENE 613 woe 18. Tesperature ( 60.0 Teal as neat capacity, enthalpy and entropy, fron ge (fea) with coefficients tron Shiasnoucht?# (ime) (a/e01) 2 (3/01-«) 9320.58 65:0 7020 75:0 2500 30:0 95.0 10070 10870 iola us:o 12010 10l0 135.0, 33.28737 33128740 33125749, 33125772 33136023, 33125923, 3326128 33. 26481, 3327003 330218 331290 33.307 33330 331399 Ta3sel295 Taie8!007 Zeo2i:719 Tyaag. 136 Tis22!a3s risers 27130! 186 Thogsteie 26957!306 766902908 Tes242312 Tets0-693 5023-581 Tsas6.202 Ts688. 498 Ts182: $013,128 Th671. 699 Tav991736 743261869, Thi52/994 Tpaot las, 236241483 23495702 732681580 [3083-920 [2900605 Titis aoa 235251205, T2150. 8s, Tisse laa 21764321 Tis6a:173 Ti3697960 cites tals =967.097 762.366 Tha6! 108 71341512 791437 324459 Fsleeo 9591266 11852335, 18442520 1678457 21141503 2353-068 3spariea 2e37 746 3oa7/e71 33321519 3303-00, 3ast.a74 033/573, 43520281 ae1.488 Te5.768 253.107 2s01642 Thala? persert reais Teaizas Thol4as lhelne 2351607 Tyna 232! 709, 2Jo.038 fait Ta7ls60 Toel3a3 Teita Zaaloss Z22!020 Bilas Toca? Tislea Theloes Tinie 2151367 Telia Tialeas riaital ities S33 Tiolaia 31307 o11330 rings Telaes 415333 az 4. Phys. Chem. Ret, Dat, Vol. 15, No.2, 1988,614 JAHANGIRI ET AL. Tale 18. (continues) lees! gas heat capacity, entnelpy and entrony fran Egy (8:3) with cacttictents fran Shieanouent?? Temperature oa wy (/moi-x) 400.0 52.969 405.0, 53.485 4100 531979 ai5.0 saan i250 551447 430.0, 551932 slo Sead aol0 Tas3 a0 So 450.0, ace 435.0 Si ° 782 3 08 3 16? ° 622 20 74 Soo 1323 495.0, [583 500.0, ca region and in the low-density vapor region. The range of applicability of the fundamental equation hat also been in- eased to higher pressures In the development of the new formulation, a new form of equation of state and new tech- niques for correlation have been developed which result in Improvements in the representation ofthe thermodynamic surface. Thenew form of the equation ofstate includes terms suggested by Schmidt and Wagner 5.1. Stepwise Least-Squares Technique with Search Procedure “The correlation presented in thie work was developed using stepwise least-squares technique with search proce- -0. ‘The values of i,j, and /are arbitrary. However, / and j are generally expected to be greater than zero, and / is an integer ereater than or eaual to z2r0. The selection of values {or ethylene was based upon preliminary fis to selected data using different integers for i and /, and real values for j. The ‘bank of terms used for ethylene is given in Table 19, “Fhe reduced Nt vatiabies uae i Use siultaueons Bi ting of multiple data forms are given in Table 20, These func- tions were used to represent the selected data for liquid and vapor phases by simultaneous east squares fitting of various property data. ‘Data used in iting the fundamental equation for ethyl ene were selected to avoid redundancy in various regions of the surface, The selecied experimental Py-T* data included Regen af state fo vartour ante forms REE | ren store Bb) = Beh EE dntase amet ettertn apc B1 NUM) = WHEN = Wb 65) yy = By, Yelecey of Sone eth ech, a] eee Co fe616 JAHANGIAIET AL. Table 21, Second vietal coeFfictents ured fn the eterntnatien of Uh equation of stave Temperature oO) i) (oreo) suthor 20.18 0.24917 Levelt. Songer tnd tastings emus 0.20078 0.18088 0.16753 Bas 0.1882 amas 2.08961 sma. 0.08461 292.17 0.07211 waar 0.06138 0.08219 those ofStraty* below 270 Kin the liguid region, and those ‘of Trappeniers eral, except inthe ange of 273 t0283 K at 5.5t08.5 mol/ém in theertcal region. The data of Golovs- Ki et al were not used in the liquid region. The new ‘measurements of Calad eal” above 50 MPa (except iso- therm at 110, 130, 170, 190, 200, nd 259 K) wore al included in the dataset In the vapor region, the data of Levelt Sengers and Hastings” and Trappeners et a™ were ‘sed inthe correlation. Also, smoothed values ofthe two- Phase equilibrium properties calnlated ftom Eqs. (3.1) (G.2),and (3.3) were inchudedin the Pp-T dataset. Caleu lated P.p-T values from the revised and extended scaling ssquation, reported by Levelt Sangre otal! i th ertoal repion were used at temperatures between 280 and 289 K at densities from 6 to 10 mol/dm®. Velocity of sound values between 282 and 300 K at densities between 6 and 10 mol/ di calculated from the revised and extended scaling equa- tion"? were also used inthe fit. Calculated values from the Jow-deasity vapor equation, reported by McCarty," for temperatures from 350 to 450 IC ot denstia between 0.05 and 1.6 mol/dm? were alo included. Selected values ofthe second virial coeficient from Waxman" and from Levelt Sengers and Hastings” arlisted in Table 21. Figure 12ilus- trates the Pp-T" data selected for this work. The selected experimental values for isochoric heat capacity and velocity of sound data are also shown in Figs. 13 and 14, respectively Ts woncvnte of Ey (2.9) gives in Table 22 were dtr smined by a least-squares fit to 2088 selected data points. 4 Phys. Chom. Re. Data, Vol. 16,No 2, 1985 5.4. Derived Thermodynamic Properties The functions used for calculating internal energy, enthalpy, entropy, isochori heat capacity, isobaric heat ca: pacity, Gibbs energy, and the velocity of sound from Eq. (5.7) are given as Eqs. (5.10)-(5.18) These functions ‘were used in calculating the table of thermodynamic prop- erties of ethylene given in the Appendis. (5.10) ay (5.12) (5.13) 1) ou) 5.16) (11) (5.18) ‘Saturation entries for isobar tables were calculated using temperatures determined from the vapor pressure equation. ‘The densities for the saturated liguid and saturated vapor were calculated iteratively from the equation of state using ‘the Maxwell criterion for phase equilibrium. The derived ‘Properties for saruration states were calculatea as runctions ‘of temperature and density using standard thermodynamic relations. Table entries for the liquid-rapor saturation table ‘were calenlated using the vane precanrs equation tn deter ‘mine, atthe table value of [,. Densities and derived prop- erties were calculated using the methods described above for saturation entries in the isobar tables. Tati epreion or derived propentie (Bs, (5.1)-(5.18] the eb ‘Scop ir the popes bla cena rng erento ae ted rch‘THERMODYNAMIC PROPERTIES OF ETHYLENE. 617 { 150 i ws woo 38 er t . 300 ees a0 a En 3 +. -0.3 a os beo-ate & aie os eet evans x 7 ote pti vee 8 “0.8 ate 23% O38 303 K Pi TT) fetter sl -os 224 0.3 300-906 K laweinplitgarreust.. | 0 “0.3 = 0.3 290-310 tae ° OSS TS ee DENSITY (mol/dm*) © ontie & arrson®* 2 pastings et a. a DENSITY (mol/dm?) 1 Gatoetts 1.2 1 serty2® “+ Tresoenters ot 91.26 % enn ‘ie 17. Conan if cleat alan of ey at frit hilo ‘4. Phys: Chom. Ret. Data, Vol. 15, No.2 1888628 JAHANGIRI ET AL. i prea 03 359K 0 pt Se ° 0.9 -osl a 318-320 K oa 373K 0 Lg] fewest “0.3 0.3 921-329 K 373K 0.3 0.3 > E G 2 a a Z oa 325 el 398 K Z 08 oe : Z 0 tm | Q = 03 “0.3 2 220-227 308K 5 08 0.3 wo —_ 9 eterna ————} ph te or Gan 330-353 Ag 423 o Zo 0 | meant & a -03 “0.3 ae 348 a 425 “0.3 -0.3 a ok 03 we 0 femeterreeriemnt—) 0 “0.3, -0.3 beeper TTT EE ea DENSITY (mol/dm®) (© postin & terion? 2B stray OSS TE ea DENSITY (mol/dms) 1S Getoahis et a1? © Thon & Zander? Fo 17.Compacuon of cls aloes of es todta frida above the eicaltemperatare—contnit 4. Phys. Chem. Ref. Data, Vol 15, No.2, 1986‘THERMODYNAMIC PROPERTIES OF ETHYLENE. 620 7 ot oe 8 “2.0 “ -2.0 I = fee 156 E —— a — fa é e 283.15-283.17 z & z : & Seta 7 mane 2 S “Tyolets off scale™ ° points qo off scale? & 2 ° o B oleae sol eee £ 20 oe oe a aa Bee gT22.02 X39 220 1 ROSES is ea OSE TE ea DENSITY (mol/dm*) DENSITY (mol/dm’) Fi. 18, Comparisons of cbulated values of denity to data near the eal tempertre (7, 2202482 Kp, = 7630 mol). 4. Phys. Chom, Rt. Data, Vo. 15, No.2, 1988630 JAHANGIRI ET AL, g Prema te ; giles Ll g Zee me ty 2 a ; 3. Epes | 2. fe aa a 8 & PRESSURE (Pa) i § ie eae ae he ie ae TEMPERATURE (K) TEMPERATURE (K) Fic 19 Comparisons of caculate ales ofscherc heat capacity, C10 ts e.o FILLING DENSITY 5.88 mol/dm* HPL point off scale ° PRESSURE (MPa) 'e.21. Comparisons of cleltd ae of sobre heat capacity, C10 aa rom Vashceako era. (Ret 9), 5.0 ? 2 ‘ecard 8 z z 2 | =) = Zz : gl. a —_ Fee EEE acs tan thes Eek. _ 2c Tewenereneno 2 ne tt8 maven? ge ay : ms ae & -s0 [eee sea Boo ist mavens e nr Oo ° ik go Feta a ion ieo 20020300 TEMPERATURE (K) io.20Comprionfcalulsed values ofheacpacty,C,,t0daafrom ‘Weber (Ret 36) 4 Phys. Chom. Ref. Data, Vl. 15, No.2, 1986 ‘TEMPERATURE (K) Fo, 22. Comparisons ofcllted values of tbarc het agai, C10‘THERMODYNAMIC PROPERTIES OF ETHYLENE. 631 — 149-183 a0 253K o ° — | 2 Z -3.0 wht 3.0 " 2 20 189 ao 259-258 K do ° sone W -2.0 wt 3.0 Lest ein i out ss0-ea9 1 3.0 e20 809 ze ° Boo 2.0 © 20 ie 3.0 a £, Ho ° — 2 -3.0 wtrsennd 9.0 Leen netssm ese Zao 220-229 K ao 2K 3 0 me o ae S -s.0Lesmt—renint—rsnint—essid —-2.0 rset rss —rssdrsi ae Saovaas 8 St 73 a? oun ° iy a -20 eri —evvond —~9.0 Less esses =n 249K ao 275-278 K Zz go ° og SD 3.0 Less tevin] 2.0 Leones rn © ao 247-248 K = 279-282 K o* oan [6 points off scale*® -2.9 “3.9 Bt tt, La RT PRESSURE (MPa) + Drogulyas & Stavtzey"™ 1D Went & Holdover “6 10.23. Comparizons false vals of velocity of sound to dt. PRESSURE (MPa) % Ganmon"* (© Soldatenko & Dregulyas"® 4: Phys, Chem, Ret. Data, Vol. 15, No.2, 1986632 JAHANGIRI ET AL. a 202k aa 293 7 points off seale™ ° ° 3.0 Lesemiesominerinterind —-2.0 3.0 282 K 3.0 3 points off scale*> o ° -3.0 tabs asa 3.0 i ™e9 a o 0 14 points off scale®! 3.0 Lestat sen -2.0 Se 807 — apes carer]? ° ° -3.0 Lest +n—eevt 2.0 3.0 284 K 3.0 5 points off scale’? NT DEVIATION IN VELOCITY OF SOUND 3.0 208K oa 09 0 esol ° «xj —| -3.0 Lesemttsind ester 2.0 Lear stirs °° aims aT sale a = o at o Gi 5.0 Lent sent eee -3.0 Lasse eccni essed o so 293K a0 323K fies 22,points off scale” } o 3.0 ve 3.0 vat wt vm Sor dl, Oca Tt tl, PRESSURE (MPa) PRESSURE (MPa) + Dregulyas & Stavtzev** Ganmon*® A Herget*? O Mehl & Moldover"® © Soldatenko 6 Dreguiyas*# © Terres et ati? ie 23. Compares of acl values of elo of sound to te—contied |. Phys. Chem. Ret. Dat, Vol. 1, No.2, 1988‘THERMODYNAMIC PROPERTIES OF ETHYLENE 633 3.0 au 3.0 407 K ao nom one ° | ZZ =3.0 Leen eesti eit tit 3.0 Le eesti tet et 2 ue 423 k B 20 3.0 Do oe 0 * a ee so “t + vt 3.0 a vt oa o x0 Ld 20 42a K ~ . oe i 3 so O30 Leresnnhresinintmtersenibmereti 23.0 Ltt eet tte tind 0 a 383 a we k Bo | —Aaege atte —| oy Lp 9 tg $f 8.0 Levees -9.0 Lenten rev 23) ss k cs we z 5 = 0 com] gE tan ne te ze tag 0 acy Ln aa Saat a tl, Go 2 oo. PRESSURE (MPa) 9 3.0 Lett testo tote eet oS my 0 ++ ea 3.0 pg mes Barth te, PRESSURE (MPa) 1D Mehl & Moldover*® © Soldatenko & Dregulyas*® © Terres et al.4? Fra. 23, Comparzons of ck vals of voy of sound to ats—sontinoe, 4: Phys. Chem. Re. Data, VoL 1, No.2, 1986634 JAHANGIRI ET AL. 1.0 0.5 n “ OST aman"® (saturated Tiavid) PERCENT DEVIATION IN VELOCITY OF SOUND AT SATURATION ° b -1,0 A Soldatenko & Dregulyas*? (saturated vapor) 100 150 200 TEMPERATURE (Kk) Fic. 24 Comparons of eaculate ales ofthe lost founda stration fo ata 250 300 5 an “ ouslin &parrison®® a © Lsengers & Hastings"? BZ 2.0 “ 1 nienets & ectdergane!? 2 a . Y atasen & ateerten®? = a ‘Tronas & Zander? B 10fP o . tease at bad ° Waxwan®? & 0.0 0 a pete v8 4 eo” TEx SOW > 3 a 8 3 x % -1.0 y 8 a a fo 3 a -2.0 e -3 ‘TEMPERATURE (K) +0 220 2u0 260 260 300 320 340 360 360 400 420 uYO 46O "ic. 28. Comparisons of acid second viral cocci with ales rom other sources [values of Thomas and Teappesiseach were SENS; elec ge tgs 7) fa Goren Rts 7nd 2 egey 4. Phys. Chom, Ret Data, Vol. 15, No.2, 1986,‘THERMODYNAMIC PROPERTIES OF ETHYLENE. eas, and saturated vapor velocity of sound data. The data of Dre- agulyas and Stavizev,"* Gammon,** and Mehl and Mol- dover" are in agreement wit velocity of sound values ealeu- Jated from the fundamental equation within -+ 19%, except in the critical region. Calculated values from Eg. (5.7) are aencrally in agreement within 19 in velocity of sound ‘with the data of Terreseral-* and other available data above 300K. Figure 2 illustrates agreement ofthe saturated liquid velocity of sound of Gammon" and calculated values from, Eq, (5.7) within + 1% in velocity of sound. The deviations ofthe saturated liquid values calculated from Eq. (5.7) n= rease as temperature approaches both the critical tempera ture and the triple point temperature. ‘Comparisons ofthe velocity of sound at saturation from Soldatenko and Dregulyas illustrated in Fig. 24 indicate agreement of + 0.079% with values from Eq. (5.7). This is within the estimated uncertainty ofthe data, 6.4. The Second Virial Coctficiont Figure 25 illustrates comparisons between calculated values of the second virial coeficient from Eg. (5.7) and selected data from 200 a 460 K. The values calculated from, the data of Thomas and Zander’ and Trappeniers et al.** shown in Fig. 25 were reported by Levelt Sengers and Has- tings” The values of Levelt Sengers and Hastings® and ‘Waxman and Davis” used inthe determination of the coef cients of Eq. (5.7) are predicted within + 0.5 cm?/mol at temperatures from 270 o 350 K. The deviations are as large ‘as2em"/mol at temperatures from 360 10450 K. Calculated values of second virial coefficients of Gammon inthe range (of 150-220 K are not generally in agreement with values calculated from Eq. (5.7) and are not included in Fig. 25 “Yaple 24 lists Valves ote secona Vira coemetent tor etny- 6.5. Maxwell Criterion Figure 26 illustrates comparisons of values of vapor pressure, saturated liquid density, and saturated vapor den- sity with values calculated from Fas. (3.1), (3.2),and (3.3), respectively. In addition, Fig. 26 includes comparisons t6 saturation properties calculated from Eq. (5.7) using the Maxwell criterion. The values calculated from Eq, (5.7) us- jing the Maxwell csitucion atin gal agresteit (iin 0.01%) with values calculated from Eqs. (3.1), (32), ‘and (3.3), and with selected data from the triple point to270 K, For temperatures between 270 K and the critical tem- perature (282.3482 K), values calculated from Eg. (5.7) ‘deviate from values calculated using Eqs. (3.2) and (3.3) by ‘as much as 1% in density. 6.6.Enthalpy Enthalpy values from Ba, (5.7) are compared below ‘with the available enthalpy data including experimental enthalpy differences on isotherms and isobars and enthalpy values on the saturation curve. The comparisons of data with esloulated values of enthalpy from Eq, (5.7) givan in thi section indicate that Eq. (5.7) may be used to predict values sable 24. second virial Getictens for eee Se TI CORFICIEN, 8, (ena) ey cqatten (5.1) samen? Levete sengers®? saanae?> ‘of enthalpy accurately except th critical repion, No claim for accuracy inthe eritical region is made. ‘The enthalpy data of Dawe and Snowdon®® were con- ‘verted to the enthalpy datum ofthis work (13 =29 6101/ mol at Zy ~ 208.15 K). Figure 37 illustrates the compari sons of values of enthalpy calculated from Eq. (5.7) to the ata of Dawe and Snowdon. * The average value of enthalpy in the range of the data from Dawe and Snowdon’ is about, 20000 J/mol. These vapor data exhibit good agreement ( 40.1%) with enthalpy values calculated from Eq (5.7) ‘The enthalpy dilference values of Fan'® and Hejmadi ‘and Pomero! om inothormo and igre have been compared, with caleulated values from Eq. (5.7). These comparisons are given by Jahangiei and are not repeated here. The large deviations of the ealculated enthalpy values suggest that there may be large uncertainties in the enthalpy values of Fan'® and Hejmadi and Powers." Some of the data from Fan®® and Hejmadi and Powers are in the critical region and Bq. (5.7) in not reliable for the calolation of ealorime tte values inthe critical region. 4 Phys. Chom. Ret. Data, Vol. 15 No.2 196628 YAHANGIRI ETAL. WO pt w a cama i g a 1B vastings et a1! i B 0.20 A + calculated from equation of state a (5:1) using the Moov ertterton £ atte natal iit pe eaea te ea eg te Te lel peste aera $ 4 & -0.20 : =O. 0 tt 100 125° ~«180~«17S~=C«ODSSaSO ATS «300 TEMPERATURE (Kk) Zz O.2 + 2, ol oo ®t i Be BO Po vam ot IT teresa Be oeaG * i So -( tarrtson®? + Beg OSL Somm ero Ti ered wm ntiny wor wea | c - stings et ‘and vapor pressure equation (3.; fete eepe| Cceeer etal eet tect cere ca e Bae -08F ° sealing equation of state!® Ww > t ‘+ Calculated fron equation of state (5.7) 9 0.8 6 iain ieee ae 0 | & “1.0 fi I a 100 125 150 175 200 225 300 TEMPERATURE (K) BO pee > 0.8 © oust & arrton?? . at i 1 taynes?”.78 2g 0.64 Y Calculated tram revised and extended 4g EB gui scanog equation" * § ' + cateuated from equation of sate (6.7) 53 cel ong the Mel) ertaron a i +t 3 0.0 eal a 9 -0.2 $$ et 1 és 180 «175 200 225 290 e75 900 TEMPERATURE (K) ia 26 Comparions of else coexnence property dt nd vibes calcul fom Eq. (7) ung the Maxwell iron (ol area pipe) with ‘leit values fom Eae (31), (2) tnd (3), 4. Ps. Chem. Ret Data, Vol. 15, Mo. 2, 1966,‘THERMODYNAMIC PROPERTIES OF ETHYLENE — = 637 15, copatens of aetaad wn of why 0 aetna Baste oI} te oF el ara ee diy Bh ay Sram oe ae og : a] oe eae PRESSURE (MPa) ° penne PRESSURE (MPa) Fra, Compritons of clases vale fata todas of Dawe and ‘Seomdon (et 5) ‘Comparisons of calculated values of enthalpy ofthe sat- urated liquid and saturated vapor from Eq. (5.7) with the data of Douslin and Harrison” are listed in Table 25. Values of saturated liquid and vapor densities were calculated from 15g. (3.1) atthe pressure given oy the vapor pressure equa- tion, Eq, (3.1), and were used with the data temperatures for calculation of enthalpies. Table 25 shows theres good agree- ‘ment between the calculated values from Eq, (5.7) and the data of Douslin and Harrison.” Although the deviations of ‘both liquid enthalpies and vapor enthalpies are small (about 0.02%), the deviations for the saturated vapor states are ‘Benerally smauier than those for the saturatea iguia states. ‘As the temperature increases toward the critical tempera- ture, the deviations for both saturated liquid and vapor in- rene te ahost -1122h in anthalny 6.7. Enthalpy of Vaporization Figure 28 illustrates comparisons with data of values of the enthalpy of vaporization calculated from Eq, (5.7) using saturation densities calculated from Eq. (5.7) by applying the Maxwell criterion at the data temperature. The devia- tone of ealeulaed nd experimental valves are generally within + 4%. The values of Clusius and Konnertz,” Koz {ov and Tully and Edmister are notin aereement with the calculated values from Eq, (5.7). The single data points of Egan and Kemp” and Fan are within + 0.03% of val- ‘ues calculated from Eq. (5.7). The values of Douslin and ‘narrson™ are consistent with the enthalpies at saturated Tiguid and vapor states discussed in Sec. 6.6, and arein good. ‘agreement with calculated values from Eq. (5.7). Devia- tions of calculated values ofthe enthalpy of vaporization at states near the critical point are as large as 0.8%. The two values of Hejmadi and Powers™ near 280 K are within 1% of predicted values from Eq, (5.7). 6.8, Joule-Thomson Coetficients Comparicons of calculated values of the icenthalpio JouleThomson coeficient and isothermal Joule-Thomson ‘coefficient from Bq. (5.7) with data are given by Jahangir. ‘Values of the isenthalpic Joule-Thomson coeflcient caleu- lated from Eq, (5.7) are within 1% of the data values of ‘Dawe and Snowdon.”*Some isothermal Joule-Thomson co- efficient data from Fan‘® and Hejmadi and Powers* exhibit deviations ae lrge ae 254 from values caloulated wsing Eq: (6. 4: Phys. Chem. Ret Date, Vol. 15, No.2, 1988,JAHANGIRI ETAL, Ze 300 “ ss + o% ree) oe ze 5 225 Bes 100 b aca 2 & fsa} ‘i Bow! -100 a A zo 2 a D clustes & konnerte®? GS. 8-200 © oustin barren! a3 eet ‘ 4 00 a ter 400 + tre ~ 28. Comparisons of alte values oF heat of vapor 6.9. The Critical Region ‘The critical region for the equation of state for ethylene {is defined to include states at temperatures between 279 and 303 K at densities from 5.75 to 10.5 mol/dm’. The revised land extended scaling model of Levelt Sengers ea." is con- sidered to be the most accurate representation of available ata for ethylene in this region. The fundaental equation ‘was determined by least-squares fitting of selected data with- ‘out constraints atthe critica point. The riticl point ofthe fundamental equation was determined as that point where (GP /ép)x and (0°P /6p*)z are both zero. The ertical point parameters ofthe fundamental equation are compared ‘ovalues from Levelt Sengers eral." in Table 26, This agree- ‘ment ofthe eritieal point of the cquation of state with the accepted values is the result ofthe inclusion of calculated properties from the revised and extended model of Levelt Sengers etal in the data base for determining the coefi- cients ofthe equation of state. ‘Comparisons of calculated and measured density val ues in the critical region are included in Fig. 18. Additional ‘comparisons of ip" data in the critical rgion are given in Froperty Le gers Tmyeratre (6) 28 resate 8) 10. 4 Phys. Chem. Ret, Data, Vol. 15, No.2, 1986 TEMPERATURE (k) vation fom Ea (5.72 a. Figs. 29-32. Figures 31 and 32ilustrate comparisons of val- ‘es of pressure and density calculated from Ea, (5.7) with values from the revised and extended scaling equation of Levelt Sengers et al The range of valiaity of the models ‘between 5.75 and 10.5 mol/dm®. The P-p-T graphs ofthis, section extend beyond this range of validity to illustrate agreement with data outside the rtical region (i.e. the data (of Trappeniers etal"). The 2er0 deviation line ofthese plots {isthe formulation of Levelt Sengers ea.” The percent de- Viations illustrated in these figures are given by peroent deviation = [(X"°— Xue )/X"]X100, (63) Where Xp fepresents calculated values from the formula- ‘ion presented here and X 1 represents values from the cal- ‘ng equation of Levelt Sengers ef a" Significant discrepancies in calculated density values ‘are apparent in Fig 32. The agreement of this formulation with the data of Trappeniers tal (which extends beyond ‘the range ofthese plots) is apparent in Figs. 31 and 32. ‘The anomalous behavior of calorimetric properties at ‘the critical point cannot be properly modeled by an analyti- cal equation of stale. Lnis Is Contrmen i rig. 33 wich illustrates comparisons of calculated derived properties to values calculated from the revised and extended scaling ‘model of Levelt Senges era." 6.10. Estimated Accuracy of Calculated Properties ‘The estimated uovurncy of density values calculated with the formulation presented hereis + 0.1% forthe range of validity to 450 K at pressures to 260 MPa except in the ‘near ctitical reaion (between 5-5 and 10.5 mol/dny at tem- peratures between 279 and 303 K). Extrapolation of ealeu-‘THERMODYNAMIC PROPERTIES OF ETHYLENE. PRESSURE (IMPa) LE 7D. douslin & Harrison?? A Hastings et at.!° © Trpenters etal. gaat ertterton values ateataed fran equation (6.7) — aterm ales exteloed from equation (5.7). +0 8.0 7.0 8.0 9.0 DENSITY (mol/dm?) 1,29. Comparisons of Pp-T data for tyne inthe exe region 10.0 11.0 4. Phys. Chem. Ref. Data, Vl. 18, No.2, 1086,640 JAHANGIRI ET AL. zoussk gy 209.15 9 points off scale’? 2 of 0 pect goo o| 208.15 - a @ 7 8 8 wi w Bo [ap 2 c0gp0 oe = DENSITY (moisam®) Qo eos 202.85 K Zoo 2 2089; 2 © Doustin & Harrison?? 3-1 X Hastings et a1? E ot 289-15 k D Trappenters et a1.°* eae = Boa 5 er 265.65 G “(pees & 3 Dos oe 298.65 K 0° feet “a. 209015 & os ya, ° pal “on se 7 8 8 10 mt DENSITY (mol/dm3) 50. Comparisons of calcul values of presurto data in thecal pion ‘Phys. Chem. ef, Data Vl. 15, No.2, 1‘THERMODYNAMIC PROPERTIES OF ETHYLENE. eat ‘ERCENT DEVIATION IN PRESSURE a 0.3 aa{ 298-18K pc} 29815 K oil * a. ovo Latest 2 a oo : on 0. PERZENT DEVIATION IN DENSITY een een ion 284-287K 0.1 *t ed-gark gst Oe eps py agaeerned Tints wart Deusen & Marrison?? NT DEVIATION N PRESSURE Erna errant Soe ea ae 270-284K 278-284K ot 10 § ou. 8 0.0 a “ “01S ie a! poe ats aad ee 0.2. -20 PERCENT DEVIATION IN DENSITY Se te Oe. WW) AL DENSITY (mol/dm*) Fic. 31 Preturedevitions of eguatin of tat and Pip at fom the ‘eve sad extend scaling equation nthe etc region. [The {ave devin lint the fortnstion Une omg oa (Ra a eee tr oar aloneT DENSITY (mol/dm*) ‘Po. 32. Density deviations of equton of state and Pyp-T dat om the ‘eve and extended sling equation inthe eed repon [The ‘se decaton asthe formation of Leet Songer (Raf a) “J Phys. Chem. Ret Dats, Vol. 15, No.2, 1966oa Ursa Usgn (5.1) Hts2q Mean ¢5.19 S{52] ~ Sem c6.1) (J/mol) (J/mol) ° 0.05 0.00 (J/mol-K) 0.05 -0.10 YAHANGIRI ET AL. 6 7 8 g 10 % 28.5, ais 298.15 K. nt 6 7 8 8 10 1 we = mee 5 6 7 8 3 10 i DENSITY (mol/dm®*) ic 58, Comparizns of clei derive proper fem this work (Sothermal nes) to vals rom the seal hata) enw ne spon)‘THERMODYNAMIC PROPERTIES OF ETHYLENE 643 20 283.18 & aS. 10 ae eae > = —! 3} 0 293.15 « 208.18 K 293.18 238.15 & ss PERCENT DEVIATION IN ' VELCCITY OF SOUND 5 6 im 8 9 10 it DENSITY (mol/dm?) ic. 38, Comparison of eluted derived proper from his work (isotherm formalatons (Rel 12) (baseline of pls) continued. 4. Phys. Chem. Rt. Data, Vol. 16, No.2, 188664g JAHANGIRI ET AL. ed properties beyond the range defined by data are not advised. The formulation given here may be expected to give pressures in the critical region with an estimated accuracy of ‘+0.1%. Although this fundamental equation is more accu- rate than the wide range equation of state of McCarty and ‘Jacobsen’ for ethylene forthe calculation of pressures in the sritial region, clowlated densities may be in ceror by 02 ‘much as 19 near the critical point, The formulation of Le- veltSengerseral should be used for ritcal-egion proper- ties instead ofthat presented here. ‘The calculated values of heat capacity (C, and C,) are ‘estimated to be accurate to within + 3%. Although the ‘comparisons of Sec. 6.2 indicate some deviations of caleulat- cedisochoric het capacity (C,) values larger than = 5% at ‘densities below 7 mol/dim, the overall accuracy is estimated ‘on the bass of comparisons tothe data considered most reli- able by the authors (those of Weber" above 11 mol/dm’). Based on comparisons to the measured values of Watan- abe,” the estimated accuracy of calculated values of C, for ‘the vapor is + 2%, Calculated values of velocity of sound scentinaied w be wecurave w wibln 4-196, except at tem= peratures between 279 and 310 K at densities between 5.5 and 10.5 mol/dm*. The accuracies of other caleulated de- ‘ved properties may be inferred from those discussed in this section, 7. Acknowledgments This work was supported by the National Bureau of Standards Office of Standard Reference Data (NBS- ‘OSRD) under Grant No. NB8INADA20SI. The efforts of Dr. Howard J. White, Jr. of NBS-OSRD in managing the national program to improve the thermodynamic property| formulations and tables fr ethylene ae recognized and ap- ‘precited. The contributions of Dr. J. M. H. Levelt Senger, Dr. J.8. Gallagher, and Dr. L. Haar atthe National Bureau ‘of Standards in Washington, DC and of Dr. J. V. Sengers at, ‘the University of Maryland in reviewing preliminary results ‘and in providing suggestions throughout this work are grate- fully acknowledged. 8. References "RH. Harn an D.R. Doula, J Chem. Eng. Data 22,24 (197). "S-Angus Hy Armaltong and K-AL de Keto, Ftemational FR ‘ami Table he Fl Stats, Elen, International Union of Pues ‘Apnied Chantry (Butervrts,Loodon, 1972), ° Symp, nda Nea fr Ciel valuatd PVT Daa of Et Ist Warreatoe, VA, Numerical Dats Advisory Board, NRC. and Of of Sundard Reference Data Natl Bur Stand (US), 1972 *D.M.Vasiceako Ye. Vonoy, BV Volga EK. Dregs A. Ya ‘Kolm §D. Labo A.A Morozo,L A. Neda ¥-. Provera, ‘YULA soldi, Strashenko and Va Romar, ia Thormody amie and Transport Proper of Eplne and Proper, aslo by Nal Bur Std (US), OBceo tandaré Reference Dat, 1972 2 Bender, yogis 1, 67 (197), “RD Gowawin, private communicate, 197. 2W. Thomas and M, Zander lt. Thermophys 1, 383 (1980), "RD. 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Chem 36, 2127 (1982). 6, Hecser, Bln Spc ofPljamie Mole (Vaa Nostrand, New Yet, 196). Kiri and KS Paes Na A346, “DLR Shall and FD. Mayel nd. Ea. Chem. 35,69 (194). DR Sl and H, Prop, Proje Divan, JANAF Thermocheal Tables 20, Off Standard Reference Dat NSRDS (Publication [No ii, US Deparment of Commerce, Wasungion, DC 1971). 8}. Thompson, Tran Faraday So. 37,344 (941). ‘RSet and W. Wagner Fld Phase Eats 19,175 (198), ‘TB. Doel, J Re Na Bur Stand (US) Sect A 73,481 (186) SMELL Hap) Row Na Bae: Stand (US) Saat ©7209 (1968). RT faeces, PRD. dseratin (Watingion State Univers, Pull span, WA, 197) "PD. Mz. Vashheno, private communication, 191 "PT Shimanooc Nat Stand. Reé Data Ser No. Bar Stand. (US. No 39,1972, Vol I A.D. Kealo, private communication, 1979, or Stand. 08.) 37.168 ‘Appendix. Thermodynamic Properties of Ethylene Saturation enteiee for isobar tablee are enloulatod woing, temperatures determined by the vapor pressure Eq, (3.1) ‘The densities for the saturated liquid and vapor are calculat- edusing Eq, (5.7). Tableentres for the liquid-vaporsatura- tion table are calculated using the vapor pressure equation to determine P, at the table value of 7, Densities and derived properties are calculated using the same methods as th for the saturation trio in the inber tables 4 Phys. Chem. Ret. Data, Vol 18,No. 2, 1986646, JAHANGIRI ET AL. Table 27. Thermodynamic properties of saturated ethylene Temperature Pressure Density Enthalpy Entropy ©, c, Velocity of Sound K Mea mol/dn?— J/mol_-—-J/mol K J/mol K J/mol K — a/s. FAUs.9¥ U.UUULZ 45.508 OIL. HHS SELL ABLE 0.00014 22552. 237179 24.97 33.29, 203 104 0.00012 23.347 6613.6 84.32 39.00 61.67 1822, 0.00014 © 22552. 237158 24197 33.29, 203, 105 0.00015 23.302 6676.1 84.92 40.86 63.76 1801 0.00017 22585. 236.44 © 26.98 33.30 204 108 0.00017 23.257 6740.8 85.53 42.38 65.50 «1784 0.00020 22619. 235.32 24.98 33.30, 205 107 0.00021 23.212 6807.0 86.15 43.62 66.96 1768, 0.00023 22652. 234123 24.98 «33.31 206 108 0.00024 92.266 £07K.€ © 8.7862 68d, 0.00027 22685. 233.17 24.99 33.32 207 109 0.00029 23.121 6943.2 87.41 45.40 69.06 1743 0.00031 22718. 232113 24.99 33.32 207 110 0,033 23.075 7012.6 «88.05 46.01 69.81 1732 0.00037 22751. 231.12 25.00 33.33, 208 LIL 0.00039 23.030 7082.7 88.68 46.45 70.60 1722 0.00042 22784. 230.13 25.00 33.34 209, 112 0.00083 22.986 7133.4 89.32 46.77 70.84 = A733 0.00049 22817. 229117 25.01 93.35 210 113 0.00053 22.938 7224.6 89.95 46.97 72.15 1704 Vudu zed. zzelzs 3 luL 53133, zd 1s 0.00061 22.892 7295.7 90.57 47.07 71.37 1696 0.00064 22883. 227.31 25.02 33.36 212 150,070 22.847 7367.1 91.20 47.09 71.49 1688 0.00074 22916. 226.41 25.03 33.37 213 116 0,081 22.801 7438.6 91.82 «47.08 71.54 1680 0.00084 22949, 225.53 25.04 33.39. 214 117 0,093 22.755 7510.2 92.43 46.96 71.53 1673, 0-00083 22882. 224167 2504 «33/40 215. 118 0.00106 22.709 7581.7 93.06 46.79 71.47 1666. 0.00108 © 23018. 223.83 «25.05 33.41 216 119 0.00121 22.663 7653.1 93.64 46.60 71.37 1659. 0.00123 23048. 223.01 «25.06 33.43, 217 120 0.00138 22.617 7724.4 94.24 46.38 71.23 1652 0.00138 © 23081, 222.21 25.07 33.44 218 “4. Phys. Chem, Ret. Data, Vol. 15, No.2, 1986‘THERMODYNAMIC PROPERTIES OF ETHYLENE 647 Table 27. Thermodynamic properties of saturated ethylene-Continued Temperature Pressure Density Enthalpy Entropy Cy, ©, Velocity of Sound K MPa mol /dn?—J/mol. Jmol K J/mol K J/nol K m/s 121 0.00157 22.571 7795.6 94.83 46.13 71.07 1646 0.00156 23114. 221.43 25.08 33.46 218 122 0.00177 22.524 7866.6 95.41 45.87 70.89 1639 0.00175 23147. 220.66 25.09 33.47 219 123° -0,00201 22.478 «7937.4 95.99 45.59 70.69 1633, vevulys — z5180.2ays91 233.89 220 124 0.00226 22.432 8008.0 96.56 45.30 70.48 «= 1627 0.00220 23212, 219.18 25.12, 33.51 221 125 0.00255 22.386 8078.3 97.13 45.00 70.26 +1620 0.00245 23245. 218.46 25.13 33153, 222 126 0.00286 22.339 8148.5 97.69 44.70 70.04 += 1614 0.00274 © 23278. 217.76 «25.14 33.55. 223 127 0.00320 22.293 8218.6 98.26 44.40 69.82 1608 0.00304 © 23310. 217.07 «25.16 33.58 224 128 (0.00358 22.246 8288.2 98.79 44.10 69.60 1602 0.00338 © 23343. 216.40 25.18 33.60 226 129 0.00400 22.200 8357.7 99.33 43.80 69.38 1595 0.00374 23375. 215.74 25.19 33.63 225 130 -0,00645 22.153 8426.9 99.86 43.51 69.16 1589 0.00813 23408. 215.10 25.21 33.65 226 331 0.00495 22.107 8496.0 100.39 43.22 68.95 1583. 0.00856 23440, 214.47 25.23 33.68 227 132 0.00550 22.060 8564.9 100.92 42.94 68.75 «1577 0.00509 20472, 21910325182 99.71 220 133 0.00609 22.013 8633.6 101.43 42.67 68.56 1570 0.00553 23504. 213.25 25.27 33.74 228 134 0.00674 21.966 8702.0 101.95 42.40 68.37 1564 0.00607 23537. 21265 25.29 33.78 229 iso U.UU/ae ALLY 81.9 102.4942 OBLLU 398 0.00666 23569. 212.07 25.31 33.81 230 136 0.00820 21.873 8838.5 102.96 41.89 68.03.1551 0.00729 23601. 211.50 25.33 33.85, 231 137 0,00902 21.825 8906.5 103.45 41.65 67.87 1545 0.00796 23633. 210.94 25.35 33.89 232 138 0.00991 -21.778 8974.3 103.95 41.42 67.72 1538 0.00869 23664, 210.40 25.38 33.93 232 4 Phys. Chom. Ret. Data, Vol. 18, No.2, 1986648 JAHANGIRI ET AL. Table 27. Thermodynamic properties of saturated ethylene—Continued ‘Temperature Pressure Density Enthalpy Entropy , G Velocity 3 ¥ P of Sound K Mpa mol /dm?—J/mol. © J/mol K J/mol K J/molK —a/s 199 U.U1UB/ 21.731 YOHZ.0 106.44 1.19 67.58 1532 0.00947 23696. 209.86 25.40 33.97 233 140 0,01191 21.684 9109.5 104.92 40.98 67.46 1525 0.01030 © 23728. 209134 251433401 236 141 (0.01303 21.636 9176.9 105.40 40.77 67.34 1518 0.01119 23759. 20RD -75.4R 34, 298, 142 0.01423 21.589 9264.3 105.87 40.57 67.23.1512 0.01215 23791. 208132 -25.49 34.10 235 163 (0.01552 21.541 9311.5 106.35 40.39 67.13 «1505 0.01316 23822. 207.82 25.52 34.15 236 Ath 0.01690 1.494 9378.6 106.81 40.92 67.0% 1490 0.01425 23853. 207.33 25.55 34.21 237 145 0.01839 21.446 9445.7 107.28 40.03 66.96 1491 0.01540 23885. 206.86 25.50 34.26, 230 146 0.01998 21.398 9512.6 107.74 39.87 66.88 1485 0.01662 23916. 20639-25161 34.32 238 1467 0.02167 21.350 9579.5 108.19 39.71 66.82 1478 0.01792 23947. 205.93 25.65 34.38, 239 148 0.02348 21.302 9646.4 108.65 39-56 68.77 1471, 0.01930 23977. 205.48 25.68 34.44 240 149 0,02542 21.254 9713.2 109.09 39.42 66.72 1464 u.02077 24008. 20510325172 34150, 240 150 0.02748 21.206 9779.9 109.54 39.29 66.68 1457 0.02231 24039. 204.60 25.76 34.56 241 151 0.02967 21.157 9846.7 109.98 39.16 66.65 1449 0.02395 24069, 204.17 25.80 34.63, 242 152 0.03199 21.109 9913.4 110.42 39.04 66.62 1442 0.02568 © 24100. 203.75 25.86 34.70 262 153 0.03447 21.060 9980.1 110.86 38.92 66.61 1495 0.02751 24130. 203134 25188 34.78 243 154 0.03709 «2.011 10047, 111.29 38.81 66.60 1428 9.02943 © 24160. 207193 75.9244 AS 2b 15S 0.03987 20.963 10113. 111.72 38.71 66.59 1421 0.03146 24190. 202.54 25.97 34.93 he, 156 0.04282 20.914 10180. 112.15 38.61 $6.60 1413, 0.03360 © 24219. 202.15 26.01 35.01, 245; 4 Phys. Chem. Ret. Dat, Vol. 16, No.2, 1996‘THERMODYNAMIC PROPERTIES OF ETHYLENE Table 27. Thermodynamic properties of saturated ethylene-Continued Temperatura Prassura Density Enthalpy Entropy ¢, cy Velocity 7 P of Sound K Mea nol/dn®>— J/mol. © J/mol K J/nol K J/mol K n/s 157 0.04593 20.865 10247. 112.58 38.52 66.60 1406 0.03585 24249, 201.76 «26.06 35.0826 158 0,04923 20.815 10314. 113.00 38.43 66.62 1399 0.03822 24279. 201.38 26:11 35.18 246 189 .05770 99.768 ~—«TNAAM.. 119.47 3R.AS HHT 0.04070 24308: 201101 26.16 35.27 247 160 0.05637 20.716 10447. 113.84 38.27 66.67.1388 ooiaay 24387) 0016S 2k 2A KR 2 161 0.06026 20.667 10514. 114.25 38.19 66.70 1377 0.06606 24366. 200.29 26.26 35.46 248 162 0.06431 20.617 «10581. 114.66 38.12 66.73.1369 0.06891 24395. 199196 26132 38.55 249 163 0.06860 20.567 10648. 115.07, 38.05 66.77.1962 0.05191 24423. «1991592613735. 243 164 0.07311 20.517 10714. 115.48 37.99 66.82 «1354 0.05505 24452). 199125 26143, «33.76 250, 165 0.07785 20.467 «10781. 115.89 37.93 66.87 1347 0.05833 24480. 198.91 26.49 38.87 250 166 0.08283 20.416 10848. 116.29 37.87 66.92 1339 0.06176 24508. 198.58 26155 35.98 251 167 0.08803. 20.366 10916. 116.69 37.82 66.98. 1331 0.06535 24536. 198.25. 26.61 36.09 «251 168 0,09352 20.315 10983. 117.09. 37.77. 67.05 1326 008803 24566. 19919326167 «36121252 169 0,09926 20.264 11050. 117.49. 37.72 67-11-1316 007300 24591. 197.62 26.73 36193282 170 0.10526 20.213 11217. 37.68 67.19 1308 0.07707 24619. 26.80 36.45 253 171 0,11155 20.162, 11285. 37.63 67.26 1301 0.08132 24646 26187 3658 253, 172 o.atsi2 20.11. 11252. 37.59 67.9% 1298 0.08574 24673 26.94 36.71 254 173 0,12498 20.059 11320. 37.56 67.42 1285 0.03038 24699. 2700 36le4 254 174 0.13215 20.008. 11387. 37.52 67.51 1278 0.09513. 24726. 27:08 36.98 = 255 649 “Phe. Chem. Rf. Data. Vol 15.No. 2.1986650 JAHANGIRI ET AL, Table 27, Thermodynamic properties of saturated ethylene-Continued Temperature Pressure Density Enthalpy Entropy G, _ Velocity of Sou K Mpa mol/dm?—J/nol_-J/mol K J/mol K J/mol K m/s 17S 0.13964 19.956 11455. 119.83 37.49 67.60 1270 0.10010 24752. «195.82 «27.15 37.12 255 176 0.14744 19.906 11523. 120. 0.10528 24778. 195. 2 «37.48 «67.69 1262 3271223727 255 177—(0.15558 19.851 11591. 120.60 37.43 «67.79 «1254 pings aRne” 1898 97 an TAD 38K 178 (0.16405 19.799 11659. 120.98 37.40 67.89 1246 0.11623 © 24829. 194.97 27.38 37.57 256 179 0,17288 = 19.746 «11727. 121.36 37.37 67.99 1239 0.12203 © 24855. 194.70 27.46 37.73 257 oo 0.40206 19.69% 1179. 122.7% 97.95 Gosden 0.12806 = 24880. 194.43 27.54 37.89 257 181 0.19162 19.641 11864. 122.12 37.32 1223 0.13627 24908. 194117 27.62 257 182 0.20154 19.587 11932. 122.49 37.30 ais 0.14073 24929. 193.90 27.70 258 183 -0,21186 19.534 12001. 122.86 37.28, 1207 0.14742 24954. 193/64 27.79 258 184 0.22257 19.480 «12070. 123.24 37.26 1199 0.15436 24978. 193.39 27.87 258 185 0.23369 19.426 12139, 123.61 37.25, - 1191 0.16153 25002: 193114 27196 38.76 259 186 0.24522 19.372 «12208. 123.98 37.23 68.81 1183 n16R8 95095" 197789 20S 38.95, 259 187 (0,25718 19.318 12277. 126.34 37.22 68.95 1175 0.17665 25068. 192.64 28.14 259 188 0.26957 19.263 12346. 126,71 37.20 1167 0.18460 25071. 192.40 28.23 260 40> 0.20241 19.209 © gea6. 125.07 37.19 69.22 150 0.19281 25096. 192.16 28.33 39.54 260 190 0.29570 19.154 12485. 125.4 37.18 © 69.36 1151 0.20131 25117. 191192 28.42 39.75 260 191 0.30946 19.098 0.21008 125.80 37.17 69.51 1143, 191169 28.52 39.96 260 192 0,32369 19.043 0.21915, 126.16 37.16 69.66 1135 191-45 28.62 40.17 261 J.Phys. hem. Ret Dats, Vol. 15, No. 2,18‘THERMODYNAMIC PROPERTIES OF ETHYLENE. 651 Table 27. Thermodynamle properties of saturated ethylene-Continued Temperature Pressure Density Enthalpy Entropy Cy C, Velocity of Sound K Mpa mol /dn?—S/mol.—J/mol K -J/mol K 3/mol K m/s 193 0,33840 18.987 12695. 126.52 37-15 69.81 1127 0.22851 25182. 191.22 28.72 40.40 261 194 0.89881 18.931 12785. 128.88 37.15 69.979 0.23817 25204. 191.00 28.82 40.63 261 195 0.36933 18-875 12836. 127.24 37-14 70-13. 0.26814 © 25225. 19017728192 40:86 261 196 0.38556 18.818 12906. 127.59 37.14 70.30 1103 0.25843 25245. 190.55 29.03 41.10, 261 197 -0,40232 18.761 12977, 127.95 37.13 70.47 095. 0.26904 25266. 190.33 29.13 41.34 261 198 0.41961 18.706 13068. 128.30 37.13 70.65 1086 0.27998 25286. 190-11 29.24 4160, 262 199 0.49745 18646 19719. 17K.66 37.13 TORR 1078. 0.29126 25305. 189.90 29.35 41.85, 262 200 © 0.45585 18.589 13190. 129.01. 37.13 72.01 1070 0.30289 25325. 180.68 20.462 12 262 201 «0.47481, 18.531 | 13262. 129.36 97-13 71.20 1062 0.31487 25344. 189.47 29.58 42.39 262 202 0.49435 18.472 13333. 129.71 37.13. 7.40 1054, 0.32721 25363. 189.26 29.69 42.67 262 2030-51440 18.419 19405. 130.06. 37.19 71.60. 1045, 0.33993 25381. 189.06 29.81 42.95 262 204 0.53521 18.354 13477. 130.41 71.81 1037 0.95302 25399. 18803 a3 lee 202 205 0.55655 18.295 13550. 130.76 37.14 72.02 1029 0.36651 25417. 188.65 30.06 43.56 262 206 © 0.57851 182235 13622. 131.10 72.24 1020 0.38039 25434. 188.44 43.85 262 207 0.60110 18.175 13695. 131.45 37.15 72.46 1012, 0.39668 25451. 188.24 30.28 44.16 262 208 0.62433 18.115 13768. 131.80 37.16 72.69 1004 0.40938 25467. 188105 30.41 is 49 262 209 0.64821 18.054 13841. 132.14 37.16 72.93 995 0.62451 25483. 187,85 30.53.82 262 210 0.67276. 17.993 13914. 132.48 37.17 73.17 987 0.44008 25499. 187.65 30.66 45.16 262 ‘4. Phys. Chem. Ret. Dat, Vol 15,No. 2, 1988652 Table 27 JAHANGIRI ET AL. Thermodynamic propertice of saturated ethylene-Continued Temperature Pressure Density Enthalpy Entropy ©, c, Velocity of Sound K Mpa mol/dm?—J/nol.-S/mol K J/nol K J/mol K m/s 211 0.69798 «17.931 13988. 132.83 37.18 73.42 979 0.45609 25514. 187.46 30.79 45.51, 262 212 0.72389 17.869 14062, 133.17 97-19 73.68 970 0.47256 25529. 187.26 30.92 45.87 262 213 0.75069 17.806 «14136. 133.51 37.21 73.96 962 -88950 23300. 19710731103 408.28 202 216 0.77780 17.744 «= «14211, 133.85 37.22 74.22 953. 0.50692 25558. 186.88 31.19 46.62 262 215 0.80582 17.680 14285. 134.19 37.23 74.50 945 0.52484 © 25572. 186.69 31.32 47.01 262 216 0.83658 17.617 «14360. 134.53 37.25 74.79 936 0.54325 25585. 186.50 31.46 47.41 262 217 0.86408 17.552 14435. 134.87 37.26 75.09 927 0.56219 25597. 186.31 31.60 47.82 262 218 0.89633 «17.488 «14511. 135.21 37.28 75.40 919 0.58165 25610. 186.13 31.76 «48.25 262 219 0.92534 -17.422«14587, 135.55 37.30 75.72 910 0.60166 25622. 185.94 31.88 48.68 262 220 0.95713 17.357 14663. 135.89 37.32 76.08 902 0.62223 25633. 185.76 32.03 49.13, 261 221 0.98070 37.900 14790. 1K 22 AT RHR a3 0.64337 25644. 185.57 32.17 49.60 261 222 1.0231 17.224 «14816. 136.57 37.36 76.73 886 0.66510 25654. 185.39 32.32 50.08 261 223° «1.0572 17.156 14893, 196.90 37.38 77.09 875 0.68743 25664. 185.21 32.47 50.57 261 226 1.0922 17.088 14971. 137.26 37.41 77.47 867 0.71038 25673. 185.02 32.62 51.08 261 223° 1.201 17.020 15088. 197.50 97.49 77.05 ese 0.73397 25682. 184.86 32.78 51.61 260 226 «1.1647 16,951 15127, 137.92 37.46 78.25 849 0.75822 «25690. 184.66 32.93 52.15 260 227 1.2023 16.881 «15205. 138.25 37.49 78.67 840 0.78314 25698. 184.48 33.09 52.71 260 228 1.2607 16.811 15284, 198.59 37.52 79.09 831 0.80875 25705. 184.30 33.25 $3.29 259 Phys. Chem. Ret. Data, Vol. 16, Ho. 2, 1886,‘THERMODYNAMIC PROPERTIES OF ETHYLENE Table 27, Thermodynamic properties of saturated ethylene-Continued ‘Temperature Pressure Density Enthalpy Entropy Cy «, Velocity Po of Sound x MPa mol/dm?—J/mol_ © J/mol K J/mol K J/mol K — a/s 229° -1,2799 16.740 «15363. 138.93 37.55 79.54 822 0.83508 © 25711. 184.12 33.42 53.90, 259 230 «1.4701 16.66R 15443. 139.26 97.58 80.00 a13 0.86214 25717. 183.94 33.58 54.52 259 231 «11,3612 16.596 15523. 139.60 37.61 80.47 804 o.ee006 © 25702. 183,76 i 55.17 250 232 -1.4032 16.523 15603. 139.94 80.97 795 0.91856 © 25727. 183157 55.84 258 233° (1.4661 16.449 15684. 140,27 81.48 786 0.94797 25731. 183.39 56.54 258 228 1.099 16.974 3780. 190.02, ez.01 mm 0.97821 25734. 183.21 57.26 257 235 «1.5347 16.299 15847. 140.95, 82.57 768 1.0093 25737. 183.03 38.0n 2 236 © -1,5805 16.223 15930. 141.28, 83.15 759 1.0613 25738. 182/85 58.80 257 237° -1,6272 16.146 16013. 141.62. 83.75 750 1.0762 25739. 182167 59.62 256 238 1.6749 16.068 16096. 141.96 84.37 7a. 1.1081 25740. 182/48 60.47 256 239° «1.7237 15.989 16180. 142.30 85.02 731 1.1429 25739. 182/30 61.36 255 240 «1.7734 15.909 16264. 142.64 85.70 722 vtvaR | 9873R" R919 62.20 255, 241 «1.8242 15.828 16349. 142.98, 86.41 m3 1.2157 25736. 181.93, 63.26 254 242 -1,8760 15.746 16435. 143.32 87.16 703 1.2537 25733. 181.74 64.28 256 243 «1.9289 45.669 6521. 149.66 20.19 07.99 634 1.2928 25729. 181.56 35.96 65.35, 253 26h 1.9829 15.579 16607. 144.00 38.19 88.75 684 1,9392 25724. 161.97 36.16 66.47 252 245 2.0379 15.494 16695. 144.35 38.24 89.60 675 1.3748 25718. 181.18 36.37 «67.65, 252 246 2.0940 15.407 16783. 144.69 38.30 90.50 665 1.4176 25711. 180.99 36.58 68.89, 251 653 4. Phys. Chem. Ret. Dat, Vol 18, No.2, 1986654 JAHANGIRI ET AL, Table 27, Thermodynamic properties of saturated ethylene-Continued Temperature Pressure Density Enthalpy Entropy G, Cy Velocity of Sound K MPa mol/dn?—J/mol_--J/mol K J/nol K J/mol K m/s 207 -2.1513 15.920 16872, 145.08 38.37 91.43 836 1.4618 25703. 180.79 36-80 70.20 251 248 2.2096 15.281 16961, 145.38 38.43 92.46 646 1.5074 25694. 180.60 37.02 71.59 250 269 2.2692 15.140 17052. 145.73 38.50 93.49 636 1.5565 25684. 180.40 37.25 73.08 © 248, 250 2.3298 15.048 «17143, 146.08 38.57 94.60 627 1.6031 25673. 180.20 37.47 74.61 249 251 «2.3917 14,955 17285. 186.43 38.66" 95.771 1.6534 25660. 180.00 37.71 76.26 «248 252 2.4847 tego 17927, 16.78 8.727.026 1.7053 25646. 179.79 37.95 78.02 247 253° 2.5189 14.763 17421. «147.13 38.79 98.34 597 1.7590 25631. «179153 38:19 79.89 an 254 2.5844 14.666 17516. «147.49 38.87 9.75587 1.8146 25615. 179.38 38.44 81.90 246 255 2.6511 14.566 17611, «147.85 38.96 101.3577 1.8721 25596. 17916 38.70 84.04 245 256 2.7190 14,462 17708, 148.21 39.08 102.9367 1.9518 25577. «178.95 38.96 86.35 2a 257 2.7882 14.987 «17806, 148.57 39.14 106.6 «557 aise) 25595) 873 391z3 8883S 203 258 2.8587 14.251 17905. 148.94 39.23 106.5547 2.0578 25532. 178.50 39.51 91.51 242 259 2.9305 14.161 18005. 149.30 39.33 108.5536 2.1246 25507. 178.27 39.79 94,42 DAL 260 3.0036 14.030 38107, 149.68 39.44 110.7526 2.1940 25480. 178.04 40.08 97.58 240 et VOTAL aR aS ATID. ASN.OS 99.55.15 2.2662, 25451. 177.79 40.38 «101.0240 262 «3.1540 13.798 18324. 150.43 39.66 115.7506 23iie 2519) 17718840170 1d 288 263 «3.2312 13.677 «18421. 150.81 39.79 118.6 49% 2.4202 25385. 177.30 41.02 109.0238 264 «3.3098 13.553 18529. 151.20 39.92 121.7483 2.5025 © 25369. 177.06 41.35 «113.6 237 4: Phys, Chem. Rt. Dats, Vol. 15, No.2, 1988‘THERMODYNAMIC PROPERTIES OF ETHYLENE Table 27. Thermodynamic properties of saturated ethylene-Continued Temperature Pressure Density Enthalpy Entropy C, ©, Velocity of Sound K MPa nol/dn?—-J/mol.~—-S/mol K J/mol K J/mol K m/s 265 3.3899 13.425 18639. 151.60 40.06 125.3 ana 2.5886 25309. «176.77 41.69 118.8 235, 266 © «3.4714 13.293 18751. 152.99 40.21 129.3460 2.6790 25267. 176.49 42.05 126.5 234 267 «3.5544 13.156 18865. 152.40 40.37 133.7 448 2.7740 25221. 176.21 42.42 131.0 233 ace 2.6280 t2.0ah ene? ase ung Tak 236 2.8742 25171. 175.91 «42.81 138.4 232 269° «3.7250 12.866 19102. 153.24 40.73 144.7 426 p.peo)agiz8) 498160132 4Kes8 31 270 © -3,8126 12.712 «19226. 153.67 40.94 151.4 412 3.0923 25060. 175.28 43.65 156.7 230 271 -3,9018 12.550 19352. 154.11 41.18 159.4 399 3.2118 24996. 174.96 «44.10 168.3 229 272 9.9920 12.979 19609, 198.97 428s 188.9 206 3.3395 24927. 174.58 44.57 (182.0 227 273° -4,0850 12.199 19619. 155.04 41.76 180.3. 372 sale; 24092. yalz0 a3 lua 9018 220 276 4.1792 12.007 19760. 155.53 42.09 194.5, 358 3.6251 24768. 173.80 45.63 219.1 225 275 4.2751 14.801 29908. 156.03 42.50 212.3 36m 3.7668 24676. 173.37 «46.21.2451 223, 276 «4.3729 11,577 20064. 156.57 42.98 235.5 329 3.9649 24572. «172.90 46.85 279.2 222 277,472 12,333 20230. 157-16 43.57 267.0 313 41372454) 172139 «47135 52519 220 278 4.5739 —11.062 20409. 157.75 44.28 311.9, 297 4.3897 -24317.«171.81 «48.35 393.9 218 279 4.6774 10.754 20605. 158.42 45.19 382.0 280 4.6541 24155. 17114 «49.26 502.3 216 280 «4.7830 «10.392 20827. 159.18 46.36 $08.6 262 4.9781 23953. 170.34 $0.35 703.2 214 281 4.8908 9.9208 22006. 160.10 48.00 819.9 ana 51431-23678. 169.29 51.75 1205.8, 212 282 © 5.0012. 9.1517 21520. 161.57 50.96 218 6.1974 «23178. 167.ke 53.94 208 + 282.35 5.0401 7.6340 22313. 164.36 F triple paler ** Critical point 655 4. Phys. Chem, Ret ata, Vo. 15, No. 2, 1986656 JAHANGIRI ET AL. Table 28. Thermodynamic properties of ethylene ‘Temperature Density Internal snthalpy Entropy Cy Gy Velocity 3 ‘Energy of Sound K mol/én? J/nol —S/mol.-S/mol K J/nol K J/mol KK a/s 0.01 MPa Isobar % 103.99 23.348 6612-5 6612.9 84.31 38.98 61.64 1822 105, 23.302 6676.0 6676.4 84.92 40.86 63.76 1801 aio 29.073 7012-5 70190-88103 4g01 9181732 1s. 22.867 7367.0 7367-4 91.20 47.09 71.49 1688 120 22.617 7724.3 7724.7 94.24 46.38 71.23 1652 12s. 22.986 6078.1 6078.6 97-13 45.00 70.26 1620 130 22.153 8426.7 8427.1 99.86 43.51 69.16 1589 335 21.920 877010 8770.4 102-45 42.14 68.20 1558 * 138.10 21.774 8980.3 8980.7 10319941139 67.71 1538. wrsely U,0u8/z25z8. 23887. 210135 2513833193 232 140 0.00864 22575. 23732. 210.81 25.39 33.93 234 145, 0.00834 22702. 23902. 212-00 25.43 33.94 238 150 0.00805 22830. 24071. 213115 25149 33.97 242 155 0.00779 22958. 24241. 214127 25156 34.03 246 160 0.00755 23086. 24412. 215135 25.66 © 34.11 250 165 0.00731 23215. 24583. 216.40 25.77 34.21 254 170 0.00710 23345. 24754. 217.42 25.91 34.33 258 475 0.00689 23475. 24926. 218.42 26.05 34.47 261 180 0.00670 23606. 25099. 219139 26.22 34.63 265 185 0.00652 23738. 25272. 220.34 26.41 34.80 268 190 0.00634 23870. 25447. 221.27 «26.61 35.00 272 395, fa’nneie anna’ 95499" 99910 RRA 3899 255 200 0.00602 24139. 25799. 223.08 27.07 35.45 278 202, 0.00597 24193. 25870. 223.43 27:17 35.35 279 204 0.00591 24248. 25941. 223.79 27.28 35.65 281 206 0.00585 24303. 26012. 224.13 27.38 35.75 282 208 0100579 24358. 26084. 224.48 «27149 35.86 283 210 0.00574 24413. 26156. 224.82 27.60 35.97 284 212 0.00568 © 2unea. 26228. «225-16 27.72 36.08 286 216 000563 24524. 26300. 225.50 36.20 287 216 0.00558 24579. 26373. 225.84 27.95 36.31 288 B10 000329 24ae. —Beaaa) © BEG110 © «20107-90149 209 220 0.00547 24692, 26518. 226.51 28.20 36.56 290 222 0100543 24748. 26592. 226.84 28.32 36.68 292 22% 000538 24805. 26665. 227.17 «28.45 36.81 293 226 0.00533 24862. 26739. 227.50 28.58 36.94 294 228 0.00528 24920. 26813. 227.82 © 28.71 37.07 295 230 0.00524 24977, 26887. 228.15 28.85 37.21 296 Be viuusiy Z5u33!Zeyez! 22614) el¥y 5734 zi 234 0.00515 25093. 27037. 228.79 «29.13 37.48 298 4. Phys. Chem, Ret. Data, Vol. 15, No.2, 1986‘THERMODYNAMIC PROPERTIES OF ETHYLENE 687 Table 28. Thermodynamic properties of echylene-continued ‘Temperature Density Internal Enthalpy Entropy C, c, Velocity Energy of Sound K nol/dn? J/nol —J/mol_-S/mol K J/mol K J/mol K — a/s 236 9.00510 25152. 27112. 229.11 29.27 37.62 299 238 0.00506 25210. 27187. 229.43 29.41 37.77 301 240 0.00502 25269. 27263. 229.75 29.56 37.91 302 242 0.00498 25329. 27339. 230.08 29-71 38.08 303 2h 0.00493 25388. 27415. 230.38 29.86 38.21 304 266 0.00489 25448. 27492. 230.69 30.01. 38.36 305 208 Olo0u8s 25508. 27568. 231.00 3011738131 306 250 0.00482 25569. 27646. © 231.31 30.32 38.67 307 252 0.00478 25630. 27723. 231.62 30.48 38.83 308 256 0.00674 25691. 27801. 231.93 30.66 38.99, 309 256 0.00470 25752. 27879. 232.23 30.80 39.15, 310 258 0.00467 25814. 27957. 232.54 30.97 39.31 aL 260 0.00463 25876. 28036. 232.84 31.13.3947 312 262 0200459 25939. 28115. 23311331130 396m. 313, 264 0.00456 26002. 28195. 233.45 31.47 39.81 31k 266 0.00453 26065. 28275. 233.75 31.64 39.98 us 268, 0.00449 26128. 28355. 234.05 31.81 40.15 316 270 0.00466 26192, 28435. 234.35 31198 40.32, 317 272 0.00463 26256. 28516. 234.65 32115 40.49 318 27% olnnex9 2821. 28597. 234.94 321334067 319, 276 0.00436 26386. 28679. 235.26 32.51 40.84 320 278 0.00433 26451. 28761! 235.54 32.68 4102 321 280 0.00430 26516. 28843. 235.83 32186 4120 322 282 0.00427 26582. 28925. 236.12 33104 41.38 323, 284 0.00424 26649. 29008. 236.42 3312341156 324, 286 0.00421 26715. 29092. 236.71 99.41 41.75 923 288 O.00618 26782. 29175. 237.00 33.59 41.93, 326 290 0100615 26850. 29259. 237.29 78 42111 327, 292 0.00412 26917. 29344. 237.58 96 42.30 328 204 e003 26900. z9029. 237.87 Ts aglay 39 296 0.00607 27054. 29514. 238.16 34.36 42.67 330 298 0.00604 27123. 29599. 238.45 34.53 42.86 331 300 Oooo, zie, Zea! 258175 SHl/Z 4305 332 305 0.00395 27367, 29902. 239.45 35.20 43.53 334 310 0.00388 27544. 30120, 240.16 35.68 44.01 336 31> U.vussz 27724. 30342, 240.87 36.17 44.50 339 320 0.00376 27906. 30565. 241.57 36.66 44.99 341 325 0.00370 28091. 30792. 242.28 37.15 45.48 343 330 0.00365 28278. 31020. 242.97 37.65 45.98 345 335 0.00359 28467, 31251. 243.67 38.115 46.48 348 340 0.00354 28659. 31485. 244.36 38.65 46.98 350 345, 0.00349 28854. 31721. 245.05 391547148 352 350 0.00344 29051. 31960. 245.74 39654798 354 355 0.00339 29250. 32201. 246.42 40116 48.48 356 360 0.00334 29452, 32445. 247.10 40.66 48.99. 358. Phys. Chem. Ret. Dats, Vol. 15, No.2, 1986658, JAHANGIRI ET AL, Table 28. Thermodynamic properties of ethylene-Continued Temperature Density Internal Enthalpy Entropy ©, c, Velocity Energy of Sound K mol/dn? J/mol —J/nol_««J/nol K J/mol K J/mol K m/s 365 0.00330 29657. 32691. 247.78 41.17 49.49 361 370 0100325 29864. 32940. 248-46 41.67 50.00 363 375 9.00321 30074. 33191. 249.13 42.17 50.50 365 380 0.00317 30286. 33445. 249.81 42-68 © 51.00 367 385 0:00312 30501. 33701. 250.48 «43.18 $1.50 369 390 0.00308 30718. 33960. 251.14 43.68 52.00 371 sas, plooaos 30827) © Bhaan. 283.81 R&D SO aa 400 0.00301 31160. 34485. 252.47 44.68 © 53.00 375, 405 0.00297 31384. 34751. 253.13 45.17 53.50 377 410 0.00293 31611. 35020. 253.78 45.67 53.99 379 415 0.00290 31841. 35291. 254.45 6.16 54.48 381 420 0.00286 32073. 35364. 255.11 46.65 54.97 383, 425 000283 32307. 35840. 255.76 «47-13 55.46 385, 430 0100200 32344. e113. 2aGl41 47 lc2 3394 bor 435 0.00277 32784. 36400. 257.06 48.10 56.42 389 440 0.00273 33025. 36683. 257.71 48.58 56.90 391 445 9100270 33269. 36969. 258.35 «4906 37.38 393 450 0.00267 33516. 37257. 259.00 49.53 $7.85 395, * 103.99 105) 310 4s. 120 125 130 18 140 145 155 * 158.23 * 158.23 68 165 170 175. 180 185 190 195 23.348, 231303, 23.076 22.848, 221618, 22.387 221156 51"a90, 21.685 21.447 21.206 20.963, 20.804 0.03877 olo3eaa 0.03708 0.03594 0.03486 0.03385, 0.03290 0.03200 0.03116 6612 6675. 7012. 7366. 7123 8077. 8426 8760 9108 9444 101i. 10326. 22996. 29049 23175. 23308. 25460. 23574 23708. 23562. 23978 4: Phys. Chem. Ret. Data, Vo. 15, No.2, 1988, 0.05 HPa Isobar 6616 6677, 7018; 7368. 7726. 8079 8428. A771 9110. Sake. e780 10114, 10329. 24285. 24523. 24699. 24075. 25051. 25227. 23408, 25582. 84, Bu. 88. 91 94. 97 99. 309 104 107. aos ql. 13. 201. 202. 203 204 205 206 207 208. 31 51 04 19 24 2 86 45 92 27 su 72 10 30 7 82 are 83 80 ™ 67 99 86 00 51 14 98 03 17 22m, 38 48 63 81 27 00 61.65 63.76 69.81 71.49 71.23 70.26 69.16 68.19 67.45 66.95 66.59 66.62 35.20 38.37 35.13 35.13, 35:18 35.25, 35.36 25.50 35.67 1822 1801 3732 1688 1653, 1620 1589 1558 1525 1492. 1421 1397 246 ane 252 256 259 263, 267 270 273‘THERMODYNAMIC PROPERTIES OF ETHYLENE. 659 Table 28. Thermodynamic properties of ethylene-Continued Temperature Density Internal Enthalpy Entropy C, C, Velocity nergy of Sound K mol/én? J/mol — J/mol_-«-J/mol K J/mol K J/mol K /s 200 0.03036 24114. 25761. 209.57 27.22 35.86 277 202, 9.03005 24169. 25833. 209.93 27.32 35.94 278 204 0.02974 24226. «25905. 210.29 27.41 36.03 279 206 olo2aes 24279. 28077° 714A 77.51 36.12 2a 208 0.02926 24335. 26049. 210.99 27.62 36.21, 282 210 ° 24390. 26122. 27.72 36.31 283 Feed : baaee, 26298: 271e3 Bela ae 216 0 24502. 26268. 27194 36.51 286 216 0. 24558. 26341. 28.05 36.62 287 218 0 24615. 26616. 28.17 36.73 288 220 0. 20671. 26488. 28.29 36.86 289 222 0. 24728. 26561 28.41 36.96 291 226 0. 24786. 26635 28.54 37.08 292 220 on 2003) 20720 2016737120 295, 228 0. 24901. 26784 28.80 37.32 298 230 0. 26959. 26859. 28.93 37.45 295, 232 9. 25017. 26934. 29108 37158 296 234. 0. 25075. 27009. 29:20 37.71 298, 236 0. 25134. 27085. 29:34 37.86 299 238 0. 25193. 27161 29.48 37.98 300 240 0. 25252. 27237. 29.62 38.12 301 242 o. 25312. 27313. 29.77 38.26 302 24m 0. 25372. 27390. 29192 38.41 303 246 0. 25432. 27467 30:07 38.55 304 248, 0: 25492. 27544. 30.22 38.70 305 250 ° 25553. 27622. 30.38 38.85 306 252 0 25614. 27699. 30.53 39.00 307 254 0. 25675. 27778. 30.69 39.16 308 256 ° 25737. 27856. 30.85 39.32 310 258 0 25799. 27935 aior 39.47 an 260 0. 25862. 28014. 31.18 39.63 312 262 0. 25924. 28093. 31.36 39.80 313 36 A dear) bai7a ayer 2a'an aie 266 0. 26050. 28253. 31.68 40.13 315 268. F 261i. 28334. 3185 40.29 316 270 ° nerve. ganas 22.02 10.n6 37 272 °. 26242, 28496. 32:19 40.63 318 27% 0 26307, 28577. 32136 40.80 319 276 °. 26372, 28659. 32.54 40.98 320 278 ° 26438. 28741. 32.72 41.15 32a 280 0.02155 26503. 28823. 32.90 41.33 322 282 0.02140 26569. 28906. 33.08 41.50 323 204 0.02124 26636. 20909. 39:26 41.68 324, 286 0.02109 26703. 29073. 33.44 41186 325 288 0.02095 26770. 29157. 33162 42.06 326 4. Phys. Chem. Ref. Data, Vol 15, No 2, 1986660 JAHANGIRI ET AL. Table 28. Thermodynamic properties of ethylene-Continued Temperature Deneity Internal Enthalpy Entropy Cy, cp Velontty Energy of Sound K mol/én? 3/mol— J/mol_ © J/mol K J/mol K J/mol K —/s 280 0.02080 26837. 29241. 223.87 93.81 42.23, 327 292 0.02066 26905. 29326. 224.16 «33.99 42.44 328 294 0.02052 26974. 29411. 224145 34.18 42.59, 329 296 0.02038 27042: 29496. 224:74 34136 42.78 330 298 0.02024 27111. 29582. 225.03 34.55 42.97 330 300 0.02010 27181. 29668. 225.31 34.74 43.15 331 305 0101977 27356. 29885. 226103 «35122 43103334 310 9101945 27533. 30104. 226.75 35.70 44.10 336 315 0.01916 27713. 30326. 227.45 36.19 44.59 338 320 Olo1aaL © 27896. «30850. 228.16 © 36.68 «45.07 aL 325 0.01854 28080. 30777. 228.86 37.17 45.56 343 330 0.01826 28268. 31006. 229.56 37.66 46.05 345 aa nini7aa Rus?) 419A?” Dan'oR AR GR RS, au 340 0.01772 28650. 31471. 230.95 38.66 47.05 350 35, 0:01746 28844. «31708. 231.64 © 39.16 47.55, 352 355 0.01697 29241. 32188. 233.02 40.17 48.55, 356 360 0.01673 29444. 32432. 233.70 40.67 49.05, 358. 365 0.01650 29648. 32679. 234.38 «41118 49.55 360 370 oloisae 20056. 32028. 23s 0s © n1 168 S008, 262 375 0.01606 30065. 33179. 235.73 42.18 50.55 364 380 0.01585 30278. 33433. 236.40 42.69 $1.05 367 38s o01s6% 30493. 33690. 237107 43-19 51.55. 369 390, 0101544 30710. «33949. 237.74 43.69 52.05 an 395, 0101524 30930. «34210. 238.41 4411952155 373, 400 0.01505 31152. 34474, 239.07 hu.68 $3.05 375 405, 0.01486 31377. 34741. 239.73 4511853154 877 410 0.01468 31604. 35010. 240.39 45.67 54.03, 379 415. 0.01450 31834. 35281. 241.05 46.16 54.52 381 420 0.01433 32066. 35555. 241.71 46.65 55.02 383 425 0.01616 32300. 35832. 242.36 47.14 «55.50 385 430 0.01400 32538. 36110. 243.01 47.63 55.98, 387 435 101904 32777! 369911243166 © 40:11 56.46. 389 440 0.01368 33019. 36674. 244.31 48.59 36.94 382 445 0.01352 33263. «36960. 244196 49.06 57-41 393, 430 0.01337 99920. 37249, 249.60 49.54 57.09 393 # 104.00 23.349 6612.5 6616.8 84.31 39.00 61.67 1822 105 23.304 6675.2 6679.5 84.91 40.85 63.76 1801 no 231077 ott? ose! Bue elu ylok 1738 us. 22.848 7366.1 7370.4 «91.19 47.09 71.49 (1688 4. Phys, Chem, Re Dats, Vol 18,No 2, 1986‘THERMODYNAMIC PROPERTIES OF ETHYLENE. 661 ‘Table 28, Thermodynamic properties of ethyleneContiniad ‘Temperature Density Internal Enthalpy Entropy 6, ©, Velocity Energy of Sound K nol/dn? J/mol — J/mol_~—«J/mol K J/mol K J/nol K m/s 120 22.619 7723.3 7727.7-94.23 46.38 71.23 1653, 125 22:388 © 8077-1 8081.6 97-12 45-01 70.26 1621 130 22.155 8425.6 8430.1 99.85 43.51 69116 1590, 135 21922 A76AR | OATT3|3 1074S? 14 RID. ISSR 140 21.686 9107.7 9112.3 104.91 40.98 67.45 «1526 14s 21.468 9443.6 40.06 66.95 1492 150 Bils0e 9777.5 2ola9eele71us? 155 20.964 10110. 38.71 66.59 1421 160 20.718 10443. 38.27 66.66 1384, 165 20.468 © 10777. 37193 66.87 1347 169.13 20.258 11054. 37.72 67.12 1315 %* 169.13 0.07351 23234. 26.74 36.3% 252 170 0.07309 23258. 26.74 36.31 253, 373 0.07079 23393! 2617736133 237 180 0.06864 23532. 26.83 36.16 261 185 0.06663 23668. 26.94 36.16 265 190 0.06473 23608. 2707 36.19 268 195 0.06298 23943. 27.26 36.28 272 200 0.06131 24082, 27.43 36.41 215 202 0.06066 24137. 27.51 36.47 276 204 0.06004 24193. 27.60 278 206 0.05962 24248. 27.69 279 208 0.05882 24305. 27:78 280 210 0.05823 24361. 27.88 282 212 0.05765 24418. 27.98 283, 214 0.05709 24474, 28.08 286 216 0.05654 24531. 28.19 286 218 0.05599 24588. 28.30 287 220 0.05546 24645. 28.42 288 292 Olnsase 94703 oR sa ora 224 0.05643 24760. 26598. 207.83 28.65 290 226 0.05393 24818. 26673. 208.16 28.77 292 298 ons, 94876” 24748. 908.40 28.00 203, 230 0.05295 24935. 26823. 208.82 29.03 29% 232 0.05248 24993. 26899. 209.15 29.16 295 94 0.05202 as0s2. 26078. 209.47 29.29 296 236 0105156 25111. 27051. 209.80 29.43 298 238 0.05111 25171. 27127. 210.12, 29.57 299 240 0.05067 25230. 27204. 210.44 29.71 300 242 0105024 25200. 27281. 210.76 29.05 301 24 0.04981 25351. 27358. 211.08 29.99 302 246 0.04960 25411 30.14 303 248 o.o4a98 25472. 30.29 304 250 0.04858 25533. 27591. z 30.46 305 252 0.04818 25594. 27670. 212.33 30.60 307 ‘Phys. Chem. Ref. Data, Vol 15, No 2, 1906.JAHANGIRL ET AL. Table 28. Thermodynamic properties of ethylene-ontinued ‘Temperature Density Internal Enthalpy Entropy ©, ©, Velocity Energy of Sound K nol/an? J/mel —3/mol_- J/mol K J/mol K J/mol K m/s 254 0.0479 25656. 27748. 212.64 30.75 39.38, 308, 256 0.04741 25718. 27827. 212.95 30.91 39.53, 309 258 0.04703 28780. 27906. 213.26 31.07 39.68. 310 260 0.04666 23863. 27986. 213.57 31123 39.84, 311 262 0.04630 25906. 28066. 213.87 31.39 40.00, 312 264 0.04594 25969. 28146. 214.18 31.56 40.15, 313 286 0.04358 28033. 28226. 214.48 5417340131 314 268 0.04523 26096. 28307. 214.79 31189 40.48. 315 270 0104489 26161. 28388. 215.09 32.06 40.64 316 272 0.06455 26225. 28470. 215.39 32.26 40.81 317 27, 0.04422 26290. 215.69 32.41 318 276 0:04389 26355. 215.99 32.58 319 278 0.04357 26421, 216.28 32.76 320 280 004325 26487! 216/58 32.84 321 282 0.04294 26553: 216.88 33.11 322 284 0.04263 26620. 217.17 33.29 323, 286 0:04233 2e687: 21746 33.48 324. 288 0.04203 26754. 217.76 33.66 325, 290 0.04173 26822 218.05 33.84 326 292 0.04144 26890. 218.34 34.02 327 296 0.06115 26958. 218.63 34.21 328 296 0.04087 27027. 218.92 34.40 329 298, 0.94058 27096. 219.21 34.58 330, 300 0.04032 27166 219/50 3477 331 305 0.03964 27341 220122 35.25 333, 310 0.03899 27519. 30084. 220.94 35.73 44.22 236 315 0.03837 27700. 30308. 221165 36.21 4.70 338. 320, 0.03776 27882. 30531. 222136 «36.70 45.18. 340 325 0.03717 28067, 30758. 223.06 «37.19 45.66 302 330 Gloa4s0 A955. «NMRA! «93.76 ATR GATS aus, 335 0.03604 28445, 31219. 224.46 38.18 46.64 347 340 (010355128638. 31454. 225115 38.68 «47.14 349 as 010340928833. 31691. 225185 39184763 351 350 0.03448 29030. 31930. 226.53 38.68 48.13 353, 355 0103399 29230, 32172. 227.22 40.18 48.63, 356 260 0.02951 29422, 22627, ae7.90 40.69 49.48 ase 365, 0103305 29638. «32663. 228.59 41119-4962. 360 370 0.03260 29845. 32913. 229.26 41.69 $0.12, 362, 375 0.03216 30055. 33165. 229.94 42.20 50.62 36 385, 0.03132 30483. 33676. 231.29 43.20 $1.62 368 390 0.03091 33935. 231.95 43.70 52.11, 370 400 0.03013 34461. 233.29 44169 53.10 375 405 0.02976 34728. 233.95 45.19 53.60 377 4. Phys. Chem, Re. Data, Vol. 18, No.2, 1986‘THERMODYNAMIC PROPERTIES OF ETHYLENE 663 Table 28, Thermodynamic properties of ethylene-continued Temperature Density Internal Enthalpy Entropy Cy ¢, Velocity Energy of Sound k mol/dn? J/nol J/mol.-— J/mol K J/nol K J/mol K m/s 410 0.02939 31595. 34997. 234.61 45.68 54.09 379 435. 0102906 31825. 35269. 235.27 46.17 54.57 381 420 0.02869 32057. 35543. 235.92 46.66 55.06 383 425, 0102835 32292. 35819. 296.58 47-15 55.55 385, 430 0.02802 32529. 36098. 237.23 «47.63 56.03, 387 435 0.02769 32769. 36380. 237.88 «48.11 56.51, 389 440 0102/38 33010! S005! 258153 olay 30-90, 330 445 0.02707 33255. 36950. 239.18 49.07 57.46 392, 450 0.02676 33502, 37238. © 239.82 49.54 57.93, 396 0.101325 MPa Isobar % 104.00 23.349 6612.5 6616.8 84.31 39.00 61-67 1822, 105, 23.304 6675.2 6679.6 84.91 40.85 63.76 «1801 110 231077 7011.7 7016.0 88.04 46.01 69.81 1732 us. 221868 7366.0 7370.5 91.19 47-09 71.49 «(1688 120 221619 772313 «772718 © 94.23 «46.38 71.23 (1653, 125 22.388 8077.1 8081.6 97.12 45.01 70.26 = 1621 130 221155 8425.5 8430.1 99.85 43.51 69.16 1590 135 211922 876818 8773.4 102.45 42.14 681191558 140 21.686 9107.7 9112.4 104.91 40.98 67.45 1526 145 21.448 9443.5 9448.3 107.27 40.04 : 1492, 150 21,208 9777.5 9782.2 109.53 39.29 66.67 «1457 355 201964 10110. 10115. «112.72 38-71 66.59 1421 160 20.718 10443. 10448. 113.83 38.27 66.66 ©1384 165, 20.468 10777. «10782. «115.89 «3703 66.87 1347 * 169.35 20.247 11069. 11074. 117.63 37.71 67.14 = «1313, * 169.35 0.07441 23239. 24601. 197.51 26.76 36.37 252 170 olo7eo9 ao87] aenk! © 197 16s 6.76 36195, 253 175 0.07175 23396. 24806. 198.70 26.78 36.22 257 180 0.06958 23531. 24987, 199.72 26.84 36.17 261 185 0.06754 23667, 25168. 200.71 26.95 36.17 264 190 0.06563 23805. 25349. 201.67 27.08 36.21 268 195 0.06383 23942, 25530. 202.61 27.24 36.30 272 200 0:06214 26081. 25712. 203.53 27.43 36.43, 275 zuz vlueras 26137. 25703. 20313027131 30.40 270 206 0.06085 24192. 25858. 204.26 27.60 36.55, 278 206 0.06022 24248. 25931. 27.69 36.62 279 208 05861 24304. -2eUDs. 21s 38.09 280 210 0.05902 24361. 26078. 27.88 7 282 212 0.05843 24417. 26151. 27.98 36.85 283 214 0.05786 © 24474. 26225. 28.09 36.9% 284, 216 0.05730 24530. 26299. 28.19 37,03 286 4. Phys. Chem. Ref. Data, Vol 15,No. 2, 1986664 Table 28. Thermodynamic properties of ethylene—Continued JAHANGIRI ET AL, Temperature Density Internal Enthalpy Entropy 6, cy Velocity energy P of Sound K mol/dn? —J/mol —J/mol_-J/nol K J/mol K J/mol K 8/8 218 0.05675 20587. 26573. 206.70 28.31 37.19 287 220 0108621 24645. 26447. «207106 28.42 57.23 288 222 (0.05568 24702. 26522. «207.38 28.54 37.33 289 3a4 —blossis 24760. 26807. 207.71 RAR 37480 226 0.05465 24818. 26672. 208.05 28.78 37.54 292 228 0.05415 24876. 26747. 208.38 28.90 37.66 «293 350 closace anae. Reade. ©0071 2910837197 20k 232 0.05318 24993. 26898. 209.03 29.16 37.89 295, 254 0.05271 25052. 26974. 209.36 29.29 38.01 296 236 0.05225. 25111. 27050. 209.68 «29.43 38.14 298 238 0.05180 25170. 27126. 210.01 29.57 38.27 299 240 0.05135 25230. 27203. 210.33 «29.71 38.40 300 242 0.05091 25290. 27280. 210.65 29.85 38.53 301 Pos 203008 25590! Zisyr Ziv.ye—Suru0 38173 246 (0108006 25411. 27435. 211128 30.14 «38.81 303, 248 0.04964 25471. 27512. 211.60 30.29 38.95 308, 250 © 0.0ng23. 25532. 27591. 21181 30143 3¥.uy 303 252 010488325594. 27669. 21222 30.60 39.24 306 254 0.04863 25655. 27747. 212.53 30.75 39.39 308, 256 © 0.04804 25717. 27826. 212.84 30.91 39.54 309 258 0.04766 25780. 27906. 213.15 31.07 39.69 310 260 010472925842. -27985. 213.46 31.23 39.84 311 362 0.04691 25005. 28065. 213.76 31.80 40.00 512 262 0.04655 25868. 28145. 731188 Mote 313 266 0.04619 26032. 28226. 214.37 31.73 40.32 314 268 0.04584 26096. 28306. 214.67 31.90 40.48 315 270 0.04349 26160. 28388. 214198 32:07 40.65 318, 272 oL0usis 26225. 28469. 215.28 32.26 40.81 317 274 0104481 26290. 28551. «21558 32.41 40.98 318, are Glomus «ease. gaena’ 30k AP RR aT TS 38 0.0415 26620. 28715. 216.17 32.76 41.32 320 0104383 26486. 28798. 216.47 32.94 41.49 32 rosasa essa: agen elas nue? a2 0106320 26619. 28965. 217.08 33.30 41.84 = 323 0704269 26686. 29049. 217135 33.48 42.02 324 200 0.04239 26754, a9199. s17.05 99.66 © Ha.30 sas 390 0104229 26021. 29218. 217.94 33.84 42.37 326, 292 0.04199 26890. 29302. 218.23 34.03 42.55 327 294 0104170 26958. 29388. 218.52 34.21 42.74 328 296 © oLoai1 27027. «29473. 218.81 34.40 42.92 309 298 «0.04113. 27096. 29559. 219.10 34.58 43.10 330 300 0.04085 27166. 29646. 219.39 34.77 43.29 332, 303 Uluauly Zysut. 29803. 22011 35125 43.73 333, 310 0.03641 27519. 30083. 220.83 35.73 44.22 336, 3150103888 27699. 30306. 221156 36.21 44.70 338, 4: Phys. Chem. Ref, Data, Vol. 16, No.2 1888‘THERMODYNAMIC PROPERTIES OF ETHYLENE. Table 26. Thermoynawic properties of ethylene-Continued ee ‘Temperature Density Internal Enthalpy Entropy G, ¢, Velocity Energy of Sound K nol/dn? J/nol —-S/nol_-J/mol K J/mol K J/mol K m/s 320 0.03826 27882. 30530. 22.25 36.70 45.18 340 325 0.03766 28067. 30757. 222.95 37.19 45.67 342 330 0.03708 28255. 30987, 223.65 «37.68 © 46.15 345, 335, 003652 26443. 91219. 224.5 38.18 46.64 347 340 0.03598 28637. 31453. 225.04 38.68 «47.14 349 345, 0.03545 28832. 31690. 225.74 39.18 47.63. 351 350, Olu3ey4 —Z¥UZU.—S19sU! zzz © 39108 40.12 333, 355 0.03444 29230. 32172. 227.11 40.18 48.63 356 360 003396 29432. «32416. © 227.79 «40.69 49.13 358 365, 0.03349 29637. 32663. 228.47 41.19 49.63 360 370 0.03303 29845. 32912, 229.15 41.69 50.12 362 375 0.03259 30035. 33164. 229.83 42.20 50.62 364 380 0.03215 30267. 33419. 230.50 Siig 366 385 003173 30482, 33675. 231.17 51.62 368, 390 0.03132 30700. 33935. 231.84 52.12 370, 395, 0.03092 30920. 34397. 232.52 52.61 312 400 003053 31142: 34461. 233-18 53:10 37% 405 003015 31367. 34728. 233.84 45.19 $3.60 377 410 0102978 31595. 34997. 234.50 45.68 54.09 379 ans n’noqu? 31898. A8PHR. 79518 «46.1785 3a 420 0.02907 32057. 35543. 235.81 46.66 55.06 383 425 0.02872 32292 35819. 236.47 «47.15 $5.55 385 430 oloze39 32529. 34098. 997.1774 «56.03 387 435 0.02806 32768. 36379. 237.77 «48.11 56.51 389 440 002774 33010. 36663. 238.42 48.59 56.98 390 aes. 0.02742 23256. 96040. 290.07 19.07 £7.46 202 450 0.02712 33501. 37238. 239.71 «49.54 57.93 394 * 104.00 105 10 45 120 125 130 135 140 45. 150 155 160 23.349 231305, 23.078 22.849 22.620 22.389 22.157 21.923 21.687 21.450 20/966 20.719 6612. 6674 7011 7365. 7722: 8076 8424, 8768 9107. 9402. 976. 10116 10643. 9783.7 10117. 10450. 1822 1802 1733 1688 1653 1621 3590 1558 1326 1492 1457 1422 1385 4. Phys. Chom. Ret Data, Vol. 15, No.2, 1886,JAHANGIRI ET AL, Table 28. Thermodynamic properties of ethylene-Continued Temperature Density Internal Enthalpy Entropy C, Cy Velocity 3 Enerey P of Sound i mol/én? J/mol J/mol_S/mol K J/mol K J/mol K a/s 165 20.469 «10776. «10784. 115.88 37.93 66.86 1347 170 20.215 «111.119 117.88 37.68 67-18 1308 175 19.956 11448. «11455. 119.83 37.49 67-60 «1270 176.32 191887 11537. «11545. 120.34 37.45 67.72 1260 * 176132 010697 23384. ahFa6. «195144 271255751256 180 0.10447 23487, 24923. 196.21 27.24 37.16 258 aes lamas a2eag) © asioe| Sey 22 37128 370a 348 390 0.09830 23768. 25294. 198.21 27.37 36.96 266 195 0.09551 23908. 25478. 199.17 27.49 36.96 270 200 0.09289 24049. 25663. 200.11 27.65 37.01 273 202 0.09189 26405. 25737. 200.48 27.72 37.04 275 205 0.09091 24162. 25812. 200.84 27.79 37.08 «276 206 0.08995 24218. 25886. 201.21 27.87 37:13 278 200 «0.00902 24275. © as9Go. 201.36 271965712079 210 0.08810 24332. 26034. «201.82 28.05 37.24 «280 212 0,08721 24389. 26109. 202.27 28.14 37.30 282 214 0108633 24s4e! 26184. 202.62 -28.24 37137283 216 0.08547 24504. 26259. 202197 28.34 37.65 284 218 «0.08463 24561. 26333. 203-32 28.44 «37.53 285 220 0.08381 24619. 26409. 203.66 28.55 37.61 287 222 0,08301 24677. 26484. 204.00 28.66 37.70 288 226 0.08222 24735. 26559. 206.36 28.77 37.79 289. 226 0.08145 24793. 26635. 204.68 28.89 37.89 290 228 © 00806524852. 26711. 208.01 29.01 37:99 292 230 0.07994 24911. 26787. 205.34 29.13 38.09 293 232 0.07922 24970. 26863. 205.67 29.26 38.20 294 23h 010785025028. 24040. 206-00 29139 «38.32 295, 236 0.07780 25089. «27017. 206.33 28.52 38.43 «296 238 0.07711 25148. «27094. 206.65 29.65 38.55 298 dun ndakk «98708-99171 DNK_BR 98179 3RL|? 299 242 0.07577 25269. 27248. 207.30 29.93 38.80 300 2h 0.07512 25329. 27326. 207-62 30.07 38.93 301 Bie oLoznka 28990. Arnon. 20792 30122 3Aaw a? 268 «0.07385 25451. «27482. © 208.25 30.36 39.19 303 250 0.07323 25513. «27561. 208-57 30.51 39.33 304 252 «0.07260 «85574. 87640. 208.08 30.66 29-47 306 256 0.07203 25636. «27719. © 209-19 30.82 39.61 307 256 0.07144 25698. 27798. 209.51 30.97 39.75 308 258 0.07087 25761. 27878. 209.82 31:13 39.90 309, 260 010703025824. 27958. 210.12 31.29 40.05 310 262 0,06974 25887. 28038. 210.43 31.45 40.20 312 266 0.06919 25951. 28118. 210.74 31.61 40.35 312 Ze U.0885 28014. 28199. 211104 ors1 33 268 0.05812 26079. 28280. 211.35, so.67 318 270 0.06760 26143. 28362. 211.65, 0183315, 4. Phys. Chem. Ref, Data, Vol. 15, No.2, 1986‘THERMODYNAMIC PROPERTIES OF ETHYLENE Table 28, Thexmodynumie properties of ethyLene-continued Temperature Density Internal Enthalpy Entropy ©, Velocity Energy of Sound k nol/én? J/mol — J/mol_--J/mol K J/mol K J/mol K m/s 272 0.06709 26208. 28444. 211.95 32.28 40.99 516 274 0.06658 26273. 28526. 212.25 32.45 4115317 276 0.06608 26338. 28608. 212.55 32.63 41.32 318 278 0106559 26406. © 28691. 212.85 32.80 1.4a 319 260 «0.06511 26470. 28774. 213-15 32.98 41.65 320 262 0.06463 26537. 28858. 213.45 33.15 41.8232 Zee UiUbwle Zeoue, —Zayaz. Zsie 33133 MLlyy 3c 286 © 0.06370 26671. 29026. 214.06 33.51 42.17 323 288 010632426738. 29110. 214.33 33.69 42.36 324 290 010627926806. 29195. 214.63 33.88 42.52 325, 292 0.06235 26875. 29280. 214.92 34.06 42.69 326 294 0.06182 26943. 29366. 215.21 34.24 42.87 327 296 0.06149 27012. 29452. 215.50 34.43 43.05 328 238 010610627082: 29538218178 Bale2 23123308 500 0.06064 27151. 29625. 216.08 34.80 43.41 330, 305 0.05962 27327. 29843. 216.80 35.27 43.87 333 310010886 27505: 30063. 217.52 35.75 4134385, 315 0.05769 27686. 30286. 218.23 36.23 44.81 337, 320 0.05677 27869. «30512. 218.98 36.72 45.29 340 525 0.05587 28055. 30738. 219165 37.21 «45.77 «Baz 330 0.05501 28242. 30969. 220.35 37.70 46.25 344 3350105417 28433. 31202. 221.05 38.20 46.74 346 3400108336 28626. 31437. 221175 387047123349 345 0.05257 28821. 31674. 222.4% 4772351 350 0.05181 29019. 31916. 223.13, 4e.21 353, 358 0.08107 2719 a71sK 293.87 berg 360 0.05035 29422, 32401. 224.50 49.20 357 365 0.04965 29627. 32648. 225.18, 49:70 360 370 0.04857 29834. 32898. 225.86, 50.19 362 3750104830 30045. 35150. 226.54, 50.69 368 380 0.04766 30257. 33405, 227.22 51.19 366 385 0.04703 30473. 33662. 227.89, 5168368, 350 0462 30690. 33922. 228.56 Seis 370, 395 0104583 30910. 34184. 229.23 52.67 372 oo 00452531133. 34uu8. 229.89 53.16 374 403.4860 91950. 94733. 290.05 goer one 430 010441331586. 34985. 231.22 Sule 378 415 010635931816. 35257. 231.88 54163380, 420 0.04307 32048. 35531. 232.53 S511 382 425° 0.04256 32283. 35808. 233.19 55.59 384 430 04206 32520. 36087. 233.84 56.07 386 435 104157 32760. 36368. 234.49 56.55 388 sao beloy 33002) 3eb32! 239.44 Bi03 S30 445 "04063 33247. 36939. 235.79 57150382 430 Too1? 33493. 37227, 236.43, 57197396 687 4 Phys. Chem. Re. Data, Vol 15, No.2, 1986Table 28. Thermodynamic properties of ethylene-Continued Temperature Density Internal Enthalpy Entropy ©, ©, Velocity Energy of Sound el mol/dn? J/mol —«J/mol_—-S/nol K J/mol K J/mol K m/s JAHANGIRI ET AL, * 104.01 105, 110 115 120 125 130 135, 1a 145, 150 155, 160 165, 170 as 180 * 181.85 * 161,85, 185 190 195, 200 202 204 206 208 210 212 zie 216 218 220 222 226 226 228 230 232 234 23.350 23.305, 23.079, 22/850 22.621, 22.390 22.158 21.924 31 6Ra 21.451 21.211 20.987 20.721 20.471 20.217 19.958 191694 191595 0.13973, 0.13691, 0.13272 0112862, 0.12516 0.12376 0.12240, 0.12107 0.11978 0.11851 0131727 0.11607 0.11489, 211373 0.31260, 0.11149, 211041 0.10935, 0.10831, 910730, 0.10630 0.10532 6612 6674. 7010. 7365. 22. 8075. 3424. 8767 e1n6 9442 9775.9 10108 10442 10775. iit10 11447. Lives. 11912. 23494) 23585. 23728 23871. 24016: 24072. 24129. 24187. 24264 24302. 26359. 2eua7 20475) 20534 24592. 24650 24709 24768 24827 auese 24946. 25006. “4 Phye Chem. Ra Data, Vol 15, No.2, 1986 0.20 MPa Isobar 6621.1 6682.9 7019.4 7373.8 TL 808. 8433. 8776. ans 9451. 9785. ao1a 10451. 10785. 11120. 11457. 11796. 11922" 24926. 25066. 25235. 25426, 25612. 23688 23763. 25838. 25914. 25989. 26065 26140 26216 26292 26368. 26444, 26520. 26597. 26674 26750 26827. 26904. 84.31 84.90 88:03, 91.18 94.22 o7.aa 99.8% 102.44 you'an 107.26 109.52 aunl7a 113.82 31587 17) 119.83 121.74 122.43 393.94 19460 195.61 196.58 197.54 197/92, 198.29, 198.66 199102 199.38 398°74 200.10 200.45 200:80 201: 201.49 201.83 202.17 202151 2028 203.18 203/51 39.03 40.85 46:01, 47.10 46.38 45.01 43.52 42.15 40.98 40.08 39.29 38.72 38.27 37:93, 37.68 37.49 37:35 37.31 27169 27.67 27.69 27.77 27.89 27.94 28101 28.07 28.15 28.23, 28:31 28.40 28.49 28:59 28.69 28.79 28.90 29.01 29.12 90/74. 29.36 29.49 61.69 63.75 6980 71.48 71:22 70.25 69.15 68.18 67.46 66.94 66.66 66.57 66.64 66.85 67.17 67.59 68.10 68.31 38.20 38.02 37.82 37:70 37.66 37.66 37.68 37.69 37.72 37.76 37:80 37.85 37.90 37196 38.03, 38.10 38.18 38.26 38.35, Rk 38.56 38.64 1822 1689 1653, 1621 1590, 1559 1526 1493 1458 3492 1385 1348, 1309 1270 1231 iis 258 260 264 268 272 273, 275 276 277 279 280 281 283 284 285, 287 288 289 290 292 293, 294‘THERMODYNAMIC PROPERTIES OF ETHYLENE. 669 Table 28, Thermodyunnie properties of echylene-Continued Temperature Density Internal Enthalpy Entropy Cy C, Velocity Energy of Sound K mol/dn> J/mol — S/mol Jmol K J/mol K J/mol K m/s 236 0.10636 25065. 26982, 203.84 29.62 38.74 295 238 0.10342 25126. 27059. 204.16 29.75 38.85 297 240 0.10250 25186. 27137, 149 29.88 38.96 298 242 o.10160 252467. 27215. Te1 30.01 39:08, 299 26h 010071 25308. 27294. 205.14 © 30.15 39.20 300, 266 0.09984 25369. 27372. 205.46 30.29 39.32 301 248 viuysys Zul 2/451 23178 Slaw lad Buz 250 0.09814 25492. 27530. 206.09 30.58 39.58 306 252 0.09731 25554. 27609. 206.41 30.73 39.71 305 254 0109650 25616. 27689. 206.72 30.88 39.84 306 256 0.09571 25679. 27769. 04 31.08 39.98 307 258 0.09492 25742, 27849. 13531119 40.12 308 260 0.09415 25805. 27929 6 31135 40.26 309 262 0209360 25868: 28010: 207/97 311314041 310 264 0.09265 25932. 28091. 208.28 31.67 40.56 Este 266 0.09192 25996. 28172. 208.58 31.83 40.71 312 268 0.09120 26061. 28254. 208.89 32:00 40.86 313 270 0109089 26125. 28335. 209.19 32.16 41.02 314 272 0.08979 26190. 28418. 209.50 32.33. 1.17 316 278 0108911 26256. 28500. -209.80-32.50 143 a7 276 0.08863 26321. 28583. 210.10 32.67 41.49 318 278 0.08777 26387. 28666. 210.40 32.84 41.65 319 a0 o'na711 26454’ 28780’ 21017033102 41182 320 282 0.08647 26520. 28833. 211.00 33.19 41.98 321 284 0.08584 26587, 28917. «211.29 33.37 42115 322 286 0.08521 26655. 29002. 211.59 33.55 42.32, 323 288 0.08460 26723. 29087. 211.89 33.73 42.49 326 290 0.08399 26791. 29172. 212.18 © 33.91 42.66 325, 292 0.08339 26859. 29257. 212.47 34.09 42.84 326 bos e.00z00 26980. 9549, 177 «4120 43.02, 327 296 0.08222 26997. 29429. 213.06 34.46 43.19 328 298 0.08165 27067. 29516. 213.35 34.65 43.37 329 300 0.00103 27136. 29403. 213104 341834333, 330 305 0.07971 27313. 29822, 214.36 35.30 44.00 332 310 0.07839. 27491. 30043. 21508 35.78 46 334 ous V.uriy z7rz. — suz00. 213.80 30.Z0 a. ¥ 337 320 0.07586 27856. 30492. 216.51 36.74 45.40 339 325 0.07466 28042. 30720. 217.22 «37.23 «45.87 341 330 0.07350 28230. 30951. 217.92 37.72 46.35 34d 335 0.07237 28420. 31184. 218.62 38.22 46.83 346 340 0.07128 28613. 31419. 219.32 38.72 47.32 348 345 0.07022 28809. 31657. 220.01 39.21 47.80 381 350 0.06920 29007. 31897. 220:77 39:71 43.29 353 355 0.06820 29207. 32140. 221.39 40.21 48.79 355 360 0.06723 29410. 32385. 22208 © 40.72 49.28 387 “Phys. Chem. Ref, Dat, Vol. 16, No.2, 1986670 SAHANGIRI ET aL. Table 28. Thermodynamic properties of ethylene-Continued ‘Temperature Densicy Internal Enthalpy Entropy Gy Gy Velocity 5 meray of Sound x mol/dn? J/mol —J/mol._--S/mol K J/mol K J/mol K —a/s 365 0.06629 29616. 32633, 222.76 41.22 49.77 359 370 0.06538 29826. 32883. 223.44 © 41.72 50.26 361 375 0.06449 22hi2 42.22 50.76 364 380 0.06363 226180 4217251125 366 385 0.06279 225.47 43.22 51.74 368 230 0.06197 30680. 33908. 226.18 49.72 92.24 210 395 0.06117 30901. 226.81 6.22 52.73, 372 400 0.06039 31124. 227148 = 471 53.22 374 405 0.05964 31349. 228.16 45.21 53.71 376 410 0105890 31377 228180 45.70 54.19 378 415 0.05818 229.46 46.19 54.68 380 420 0.05748, 230112 46.68 35.16 382 825 0.05679 20178 T1635 164 384 430 0.05612 231.43 47.65 56.12 386 435 0.05547 232108 48.13. 56.60 388 440 0.05483, 232.73 48.61 $7.07 390 445 0.05421, 233.38 © 49.08 57.54 392 450 0.05360 234102 49.56 58.01 394 0.25 MPa Isobar * 104.02 23.350 23.306 23.080, 23/881 22.622, 22.391 22/159 211925 21.690 21.452 21.212 20.969, 20.723, 201479 20.219 19.960 191696 191427 19.350 0.17204 0.16808 0.16293, 6612.5 6623.2 6673.9 6684.6 7010.3 7021.1 gens 7998's 721.7 7732.7 8075.4 8086.5 2423.7 8435.0 8766.8 8778.2 9105.6 9117.1 946113 9453.0 9775.1 9786.8 10108. 10120. 10441: 10453. yorys! 10786. uilos, 11121, 1ig46. 11458. a17e5; 11797. 12126. 12139. 12223. 12236. 23581, 25035. 23687. 25174. 23833. 25368. 4. Phys. Chem. Ret. Data, Vol. 15, No. 2, 1986 84. 34. 88. 56. 97. 99. 102 104. 107. 109 un. 13. a3) uy. 19 12. 123. 124 192 193. 19% 31 50 03 22 n 84 43 90 25 52 70 31 87 82 3 60 2 9 53 33 39 40, 46. 46. 45 42 40 40 39 38 38. 37 37 37 37 37 28 28. 28. 04 85 01 19 39 01 a3. 52 15 299 206 30 [72 127 68 249 133 125 23 208 06 107 61. 63. 6. a. 70. 6. 68 6 66. 66 66 66. 6 67. 68 68. 68. 39 38 38 10 75 80 22 25 5 18 43 93 65 57 66 n6 58 08 68 37 102 17 132 1822 1802 1733 1654 1622 1590 1559 3527 3493 1458 1422 1385 1310 a7. asa 1191 1180 259 262 266Table 26 ‘THERMODYNAMIC PROPERTIES OF ETHYLENE ‘Thermodynamic propertice of ethylene—Continued ee ‘Temperature Density Internal Enthalpy Entropy G Velocity * > Boerey of i P of Sound a nolan? J/nol —J/nol.~— J/mol K J/mok K J/mol K 9/8 200 0.15815 23979. 25560. 195.51 28.14 38.38 270 202 0115633 24037, 25637. «195.89 28.19 38.34 271 20% 0.15455 20096. 25713. 196.27 28.23 38.32 273 206 01ig2e2 24154. «25790. 196.64 28.2938 30, 27% 208 0.15114 26212. 25866. 197-01 28.35 38.30 276 210 0.14949 26271. 25943. 197.38 28.42 38.31 277 zz o.1709 24929. 2020. «197.74 «0.49 38.33, 279 214 0.14632 24388. 26096. «198.10 28.57 38.35 280 216 0114480 24447. 26173. «198.46 28.65 38.38 281 218 0.14330 24505. 26250. 198.81 28.74 38.42 283, 220 0.14185 24564. 26327. «199.16 28.83 38.47 286 222 0.16042 24623. 26404. 199.51 28.93 38.53, 285 226 0.13903 24683. 26481. 199.86 29.03 38.59, 287 226 0113766 2esaz! — Zoo>s. Zu Lzu 2913 30.03, 200 228 013633 26802. 26636. 200.54 29.24 38.73, 289 230 0.13502 26861. 26713. 200.88 «29.36 38.80 290 232 0113374 24921. 26791. 201.22 29.47 38.BY ayz 234 0113249 24982. 26869. 201.55 29.59 38.97 293 236 0.13126 25042. 26947. 201-88 29.71 39.07 29% 238 0.13005 25103. 27025. 202.21 «29.84 39.16 295 240 0.12887 25163. 27103. 202.54 29.97 39.27 297 202 0.12772 25224. 27182. 202-87 30.10 39.37 298 2b 0112658 25286. 27261. 203-19 30.24 39.48 299 246 012547 25347. 27340. 203.51 39.60 300 248, 0112438 25409. 27419. 203.83 39.71 301 250 0.17330 75471. 27499. 204.15 39.83 303, 252 0.12225 25534. 27579. 204.47 39:96 304 254 0.12122 25596. 27639. 204.79 40.09 305, 256 0.12020 25659. 27739. 205.10 40.22 306 258 olii20 | 35722. «7810. © 208-42 40135 307 260 0.11822 25786. 27900. 205.73 40.49 308 262 0111726 © 25849. 27981. 206.04 40:63, 309 Boe, olile91 25919. 3e063: 206.35 : no.77 bio 266 0111538 25978. 28144. 206.66 © 31.89 40.91 312 268 0111467 26062. 28226. 206.96 32.05 41.06, 313 270 0.12937 26107. 20909. 207.27 2-21 42.22 ou 272 0.11268 26173. 28391. 207.57 32.38 41.36 315, 27% 0.11281 26238. 28474. 207.88 «32.55 41.51 316 276 0.11095 26304. 28557. 208.18 32.72 41.67, 317 278 Ol11011 26370. 28641. 208.48 «32.89 41.89 Esty 280 0.10928 26637. 28725. 208.78 33.06 41.99 319 282 0110846 26504. 28809. 20908 «= 33.24 42.15, 320 28% 010766 Zest. zeuys. 20938 33-41 42.91 321 286 0.10687 26639. 28978. 209.68 33.59 42.48 322 288 0110609 26707. 29063. 209.97 33.77 42.65, 323 ent 4. Phys, Chem. Ret, Dat, Vol 15, No.2, 1906