1. The fugacity coefficient of a certain gas at 290 K and 2.1 MPa is 0.68.

Calculate the difference

of its molar Gibbs energy from that of a perfect gas in the same state.
2. Calculate the fugacity of pure ethylene at 100 bar and 373 K. The van der Waals constants are
a=0.453 Jm3/mol2, b=0.571x10-4 m3/mol, molar volume at 100 bar and 373 K is 2.072x10 -4
m3/mol.
3. Los coeficientes de van der Waals a (L2atm/mol) y b (L/mol) para nitrgeno son a=1.390 y
b=0.0391. Para metano (CH4) a=2.253 y b=0.0428, estime las fugacidades de estos gases en la
mezcla de 30% CH4 y 70% N2 a temperatura ambiente y una presin de 1'000 atm.
4. Un flujo de 90% CH4 y 10% H2 pasa por un horno a 900 K. Calcula la composicin de la
mezcla de gases a esta temperatura. Asumiendo el equilibrio y una presin de 1.2 atm. La
energa libre de Gibbs estndar de formacin del metano a 900 K es 2'030 cal.
5. En un reactor a 600 K y 1 atm. de presin, 10,000 m3 de dixido de azufre es mezclado con 15,
000 de sulfuro de hidrgeno. Calcule, asumiendo el equilibrio, la composicin del flujo de
gases a 600 K. Las energas de libres estndar de formacin de SO 2, H2S y H2O son: -71'790,
-10'130 y -51'160 cal/mol, respectivamente.
6. Un investigador desea mezclar dos flujos de SO3 y SO2 en una razn tal que la presin parcial
resultante de oxigeno sea igual a 0.05 atm. en un reactor a 1'100 K y abajo una atmsfera total
de 1.2 atm. Asumiendo el equilibrio, calcule dado los siguientes datos:
SO2(g) + O2(g)
G = -22'600 + 21.36 T (cal)
7. For a certain chemical reaction, H = -35.4 kJ and S = -85.5 J/K. (a) Is the reaction
exothermic or endothermic? (b) Does the reaction lead to an increase or decrease in
the randomness or disorder of the system? (c) Calculate G for the reaction at 298 K. (d) Is
the reaction spontaneous at 298 K under standard conditions?
8. Consider the reaction 2NO2(g) N2O4 (g). (a) Calculate G at 298 K. Calculate G at 298 K
if the partial pressures of NO2 and N2O4 are 0.40 atm. and 1.60 atm., respectively.
9. Consider the decomposition of barium carbonate: BaCO 3(s) BaO(s) + CO2(g) calculate the
equilibrium pressure of CO2 at (a) 298 K and (b) 110 K.
10. A 0.831 g sample of SO3 is placed in a 1.00 L container and heated to 1100 K. The SO 3
decomposes to to SO2 and O2: 2SO3 2SO2(g) + O2(g). At equilibrium the total pressure in the
container is 1.3 atm. Find the values of Kp and Kc for this reaction at 1100K.
11. When 1.50 mol CO2 and 1.50 mol H2 are placed in 3 L container at 395 C, the following
reaction occurs: CO2(g) + H2(g) CO(g) + H2O(g). if Kc = 0.802, what are the concentrations
of each substance in the equilibrium mixture.
12. A deep-sea diver uses a gas cylinder with a volume of 10 L and a content of 51.2 g of O 2 and
32.6 g He.Calculate the partial pressure of each gas and the total pressure if the temperature of
the gas is 19 C.