Documentos de Académico
Documentos de Profesional
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Facultad de Ingeniera
Escuela de Ingeniera Qumica
rea de Fisicoqumica
Fisicoqumica 1
Ing. William Fagiani
PRINCIPIOS TERMODINMICOS
PRINCIPIOS BSICOS
Funcin
Funcin de
estado
Gas Ideal
(1834)
= (, , )
=
2
=
1 0 =
= 1 0
2
tr
3
= 0
tr =
1
2
2
( )
= , = tr , + rot , + vib ,
2 2
= 0.125
+
+
+
2 3
= gi
+ 2
3
= 0.421875
3
3
=
2
2
=
= 0 1
2
3
=
= 0 1
0
1
+ 0 0 2 2 +
+
+
1 + 2 exp 2
3
6 3 2
( + )
Hederer Peter
Wenzel
(1976)
gi =
Soave
Redlich
Kwong
(1972)
Peng
Robinson
(1976)
=
tr , = tr =
Sustancias
Reales
= (, , )
= 0.42747
= 0.08664
2 2
= 1 + 1
= 0.08664
2
= 1 + 1
= 0.0778
= 0.42747
( + )
2
+ 2 2
2 2.5
( + )
= 0.42748
LEYES DE LA TERMODINMICA
LEY 0
LEY 1
( )
= , = tr , + rot , + vib ,
= + +
RELACIONES
9
=
+ 32
5
= +
rev =
LEY 2
= + 273.15
K
= +
=+
rev
=
= +
= +
= ( )
=+
= +
= +
= +
sat
sat