Curva de valoraccin de Acido acetico (HOAc) con Hidroxido de Sodio (NaOH)

14

12

pH

10

0
0

10

20

30

40
50
Volumen(mL) NaOH

60

70

80

90

14

Primera derivada
pH/Vol1

12

10

0
40

41

42

43

44

45

46

47

48

49 50 51
Vprom1

52

53

54

55

56

57

58

59

60

15

Segunda Derivada
(pH / Vol1)

10

0
46

47

48

49

50

-5

-10

-15

Vprom2

51

52

53

54

80

Gram

70

vol/pH

60

50

40

30

20

10

0
0

10

20

30

40
Vprom.1

50

60

70

80

Curva de valoracin de cido actico (HOAc) con hidroxido de sodio (NaOH)

Datos del cido actico
1E-014
Kw
Ka
0.0000175
V(mL)

50

[HOAc] (mol/L )

0.1

Datos del Hidroxido de Sodio

50
V(mL)
[NaOH] (mol/L)
0.1
Vpto.equivalencia (mL)

Determinacn de pH del cido antes

de ser titulado

a
b
c
X(+)
X(-)

50

1
0.0000175
-0.00000175
0.0013141546
-0.0013316546

Metodo de la segunda derivada

VNaOH
(mL)

0
10
30
40
45
49
49.7
49.8
49.9
50
50.1
50.2
50.3
51
52
55
60
70
80

ph
2.881353543
4.15490196
4.93305321
5.359021943
5.711204461
6.447158031
6.976197085
7.153161298
7.455062497
8.727965978
9.999565923
10.30016227
10.47582032
10.99567863
11.29242982
11.67778071
11.95860731
12.22184875
12.3631779

Vprom.1
5
20
35
42.5
47
49.35
49.75
49.85
49.95
50.05
50.15
50.25
50.65
51.5
53.5
57.5
65
75

* : pH/Vol1

pH
1.27354842
0.77815125
0.42596873
0.35218252
0.73595357
0.52903905
0.17696421
0.3019012
1.27290348
1.27159994
0.30059635
0.17565805
0.5198583
0.2967512
0.38535088
0.28082661
0.26324143
0.14132915

Vol1
10
20
10
5
4
0.7
0.1
0.1
0.1
0.1
0.1
0.1
0.7
1
3
5
10
10

pH/Vol1
0.12735484
0.03890756
0.04259687
0.0704365
0.18398839
0.75577008
1.76964213
3.01901199
12.7290348
12.7159994
3.00596352
1.75658048
0.74265472
0.2967512
0.12845029
0.05616532
0.02632414
0.01413292

vol/pH
7.85207681
25.7019442
23.4759015
14.197184
5.43512548
1.32315373
0.565086
0.33123419
0.07856055
0.07864109
0.33267203
0.56928789
1.34652076
3.36982633
7.78511259
17.8045806
37.9879406
70.7568099

Vprom.2
12.5
27.5
38.75
44.75
48.175
49.55
49.8
49.9
50
50.1
50.2
50.45
51.075
52.5
55.5
61.25
70

(*)
-0.08844728
0.00368931
0.02783963
0.11355189
0.57178168
1.01387205
1.24936985
9.71002282
-0.01303536
-9.71003593
-1.24938304
-1.01392575
-0.44590352
-0.1683009
-0.07228497
-0.02984118
-0.01219123

vprom.2
15
11.25
6
3.425
1.375
0.25
0.1
0.1
0.1
0.1
0.25
0.625
1.425
3
5.75
8.75
-70

(*)/vpro
m2
-0.00589649
0.00032794
0.00463994
0.03315384
0.41584123
4.05548821
12.4936985
97.1002282
-0.13035362
-97.1003593
-4.99753216
-1.62228121
-0.31291475
-0.0561003
-0.0125713
-0.00341042
0.00017416