For each problem show all calculations and assumptions made. Make a detailed schematic describing the scenario. Problem 1. Diffusion of CO2 Through Rubber A flat plug 30 mm thick having an area of 4.0 x l0-4 m2 and made of vulcanized rubber is used for closing an opening in a container. The gas CO2 at 25C and 2.0 atm pressure is inside the container. Calculate the total leakage or diffusion of CO2 through the plug to the outside in kg mol CO2/s at steady state. Assume that the partial pressure of CO2 outside is zero. From R.M. Barrer (Diffusion in and Through Solids, Cambridge University Press, 1941) the solubility of the CO2 gas is 0.90 m3 gas (at STP) per m3 rubber per atm pressure of CO2. The diffusivity is 0.11 x 10-9 m2/s. Problem 2. Loss from a Tube of Neoprene Hydrogen gas at 2.0 atm and 27C is flowing in a neoprene tube 3.0 mm inside diameter and 11 mm outside diameter. Calculate the leakage of H2 through a tube 1.0 m long in kg mol H2/s at steady state. Additional Data: s = 0.053 m3 gas (@STP)/[atm m3 solid]); DAB = 0.180 x 10-9 m2/s. Problem 3. Diffusion Through Membranes in Series Nitrogen gas at 2.0 atm and 30C is diffusing through a membrane of nylon 1.0 mm thick and polyethylene 8.0 mm thick in series. The partial pressure at the other side of the two films is 0 atm. Assuming no other resistances, calculate the flux NA at steady state. Please show ALL derivation steps to obtain the flux model. Additional Data: PM,Nylon = 0.0152 x 10-12 m3 gas (@STP)/[satmm2/m]; PM,Polyethylene = 1.52 x 10-12 m3 gas (@STP)/[satmm2/m] Problem 4. Diffusion of CO2 in a Packed Bed of Sand It is desired to calculate the rate of diffusion of CO2 gas in air at steady state through a loosely packed bed of sand at 276 K and a total pressure of 1.013 x l05 Pa. The bed depth is 1.25 m and the void fraction is 0.30. The partial pressure of CO2 is 2.026 x l03 Pa at the top of the bed and 0 Pa at the bottom. Use a of 1.87. Additional Data: DAB = 0.142 x 10-4 cm2/s.