UNIVERSITE MOHAMMED V

Facult des Sciences

-Anouar jebraou
Dpartement de Chimie
-Mehdi hsinat
Rabat

Groupe B02

Caracterisation dune solution solide par diffraction des

rayons X
Pour KUP :
CYCLE NUMERO 2
1 1 0 17.9200 17.9219 -0.0019 4.9458 4.9453
0 0 2 20.4200 20.4213 -0.0013 4.3456 4.3453
1 0 2 24.0900 24.0921 -0.0021 3.6912 3.6909
2 0 0 25.4500 25.4509 -0.0009 3.4970 3.4968
1 1 2 27.3000 27.2985 0.0015 3.2640 3.2642
2 1 1 30.3500 30.3471 0.0029 2.9426 2.9429
2 0 2 32.8500 32.8487 0.0013 2.7241 2.7243
2 1 2 35.3300 35.3291 0.0009 2.5384 2.5385
2 2 0 36.3000 36.3020 -0.0020 2.4728 2.4726

ecart-type 0.0020 0.0020

delta 2 theta moyen 0.0016

RESULTAT DU CYCLE
6.9937 0.0000 6.9937 0.0002
6.9937 0.0000 6.9937 0.0002
8.6906 0.0000 8.6906 0.0005
90.0000 0.0000 90.0000 0.0000

90.0000 0.0000 90.0000 0.0000

90.0000 0.0000 90.0000 0.0000

H K L D

2 *THETA 2 *THETA CORR

0 0 1 8.691 10.17

10.17

1 0 0 6.994 12.65

12.65

1 0 1 5.449 16.25

16.25

1 1 0 4.945 17.92

17.92

0 0 2 4.345 20.42

20.42

1 1 1 4.298 20.65

20.65

1 0 2 3.691 24.09

24.09

2 0 0 3.497 25.45

25.45

1 1 2 3.264 27.30

27.30

2 0 1 3.244 27.47

27.47

2 1 0 3.128 28.51

28.51

2 1 1 2.943 30.35

30.35

0 0 3 2.897 30.84

30.84

2 0 2 2.724 32.85

32.85

1 0 3 2.676 33.45

33.45

2 1 2 2.538 35.33

35.33

1 1 3 2.500 35.90

35.90

2 2 0 2.473 36.30

36.30

2 2 1 2.378 37.80

37.80

3 0 0 2.331 38.59

38.59

Pour k0.8Rb0.2UP :
CYCLE NUMERO 3
1 1 0 17.9100 17.9127 -0.0027 4.9485 4.9478
0 0 2 20.2200 20.2222 -0.0022 4.3881 4.3876
1 0 2 23.9200 23.9186 0.0014 3.7171 3.7173

2 0 0 25.4400 25.4377 0.0023 3.4983 3.4986

1 1 2 27.1400 27.1411 -0.0011 3.2829 3.2828
2 1 1 30.3000 30.2988 0.0012 2.9473 2.9475
2 0 2 32.7100 32.7104 -0.0004 2.7355 2.7355
2 1 2 35.2000 35.1969 0.0031 2.5475 2.5477
2 2 0 36.2800 36.2828 -0.0028 2.4741 2.4739

ecart-type 0.0024 0.0024

delta 2 theta moyen 0.0019

RESULTAT DU CYCLE
6.9972 -0.0000 6.9972 0.0003
6.9972 -0.0000 6.9972 0.0003
8.7753 0.0000 8.7753 0.0006
90.0000 0.0000 90.0000 0.0000
90.0000 0.0000 90.0000 0.0000
90.0000 0.0000 90.0000 0.0000

H K L D

2 *THETA

2 *THETA CORR

0 0 1 8.775 10.07

10.07

1 0 0 6.997 12.64

12.64

1 0 1 5.471 16.19

16.19

1 1 0 4.948 17.91

17.91

0 0 2 4.388 20.22

20.22

1 1 1 4.310 20.59

20.59

1 0 2 3.717 23.92

23.92

2 0 0 3.499 25.44

25.44

1 1 2 3.283 27.14

27.14

2 0 1 3.250 27.42

27.42

2 1 0 3.129 28.50

28.50

2 1 1 2.947 30.30

30.30

0 0 3 2.925 30.54

30.54

2 0 2 2.735 32.71

32.71

1 0 3 2.699 33.17

33.17

2 1 2 2.548 35.20

35.20

1 1 3 2.518 35.63

35.63

2 2 0 2.474 36.28

36.28

2 2 1 2.381 37.75

37.75

3 0 0 2.332 38.57

38.57

3 0 1 2.254 39.96

39.96

Pour K0.6Rb0.4UP :
CYCLE NUMERO 3
1 1 0 17.9000 17.9050 -0.0050 4.9513 4.9499
0 0 2 20.0300 20.0289 0.0011 4.4293 4.4295
1 0 2 23.7500 23.7511 -0.0011 3.7433 3.7431
2 0 0 25.4300 25.4267 0.0033 3.4997 3.5001
1 1 2 26.9900 26.9898 0.0002 3.3008 3.3008
2 1 1 30.2500 30.2541 -0.0041 2.9521 2.9517
2 0 2 32.5800 32.5784 0.0016 2.7461 2.7462
2 1 2 35.0700 35.0712 -0.0012 2.5566 2.5565
2 2 0 36.2700 36.2669 0.0031 2.4747 2.4749

ecart-type 0.0031 0.0031

delta 2 theta moyen 0.0023

RESULTAT DU CYCLE
7.0002 0.0000 7.0002 0.0004
7.0002 0.0000 7.0002 0.0004

8.8591 0.0000 8.8591 0.0009

90.0000 0.0000 90.0000 0.0000
90.0000 0.0000 90.0000 0.0000
90.0000 0.0000 90.0000 0.0000

H K L D
0 0 1 8.859

2 *THETA 2 *THETA CORR

9.98

9.98

1 0 0 7.000 12.63

12.63

1 0 1 5.492 16.12

16.12

1 1 0 4.950 17.90

17.90

0 0 2 4.430 20.03

20.03

1 1 1 4.321 20.54

20.54

1 0 2 3.743 23.75

23.75

2 0 0 3.500 25.43

25.43

1 1 2 3.301 26.99

26.99

2 0 1 3.255 27.38

27.38

2 1 0 3.131 28.49

28.49

0 0 3 2.953 30.24

30.24

2 1 1 2.952 30.25

30.25

2 0 2 2.746 32.58

32.58

1 0 3 2.721 32.89

32.89

2 1 2 2.557 35.07

35.07

1 1 3 2.536 35.36

35.36

2 2 0 2.475 36.27

36.27

2 2 1 2.384 37.71

37.71

3 0 0 2.333 38.55

38.55

2 0 3 2.257 39.91

39.91

3 0 1 2.256 39.92

39.92

Pour K0.4Rb0.6UP :

CYCLE NUMERO 3
1 1 0 17.9000 17.8966

0.0034

4.9513

4.9522

0 0 2 19.8400 19.8409 -0.0009

4.4713

4.4711

1 0 2 23.5900 23.5883

0.0017

3.7683

3.7686

2 0 0 25.4100 25.4147 -0.0047

3.5024

3.5017

1 1 2 26.8400 26.8425 -0.0025

3.3189

3.3186

2 1 1 30.2100 30.2096

0.0004

2.9559

2.9560

2 0 2 32.4500 32.4496

0.0004

2.7568

2.7568

2 1 2 34.9500 34.9483

0.0017

2.5651

2.5652

2 2 0 36.2500 36.2495

0.0005

2.4761

2.4761

ecart-type 0.0026

0.0026

delta 2 theta moyen 0.0018

RESULTAT DU CYCLE
7.0034 -0.0000

7.0034

0.0003

7.0034 -0.0000

7.0034

0.0003

8.9421 -0.0000

8.9421

0.0007

90.0000

0.0000 90.0000

0.0000

90.0000

0.0000 90.0000

0.0000

90.0000

0.0000 90.0000

0.0000

H K L

2 *THETA

2 *THETA CORR

0 0 1 8.942

9.88

9.88

1 0 0 7.003

12.63

12.63

1 0 1 5.514

16.06

16.06

1 1 0 4.952

17.90

17.90

0 0 2 4.471

19.84

19.84

1 1 1 4.332

20.48

20.48

1 0 2 3.769

23.59

23.59

2 0 0 3.502

25.41

25.41

1 1 2 3.319

26.84

26.84

2 0 1 3.261

27.33

27.33

2 1 0 3.132

28.47

28.47

0 0 3 2.981

29.95

29.95

2 1 1 2.956

30.21

30.21

2 0 2 2.757

32.45

32.45

1 0 3 2.743

32.62

32.62

2 1 2 2.565

34.95

34.95

1 1 3 2.554

35.11

35.11

2 2 0 2.476

36.25

36.25

2 2 1 2.386

37.66

37.66

3 0 0 2.334

38.53

38.53

2 0 3 2.270

39.68

39.68

3 0 1 2.259

39.88

39.88

Pour k0.2Rb0.8UP :
CYCLE NUMERO 3
1 1 0 17.8900 17.8866

0.0034

4.9540

4.9549

0 0 2 19.6600 19.6591

0.0009

4.5118

4.5120

1 0 2 23.4300 23.4303 -0.0003

3.7937

3.7936

2 0 0 25.4000 25.4004 -0.0004

3.5037

3.5037

1 1 2 26.7000 26.6992

0.0008

3.3360

3.3361

2 1 1 30.1600 30.1637 -0.0037

2.9607

2.9604

2 0 2 32.3200 32.3234 -0.0034

2.7676

2.7673

2 1 2 34.8300 34.8274

0.0026

2.5737

2.5739

2 2 0 36.2300 36.2287

0.0013

2.4774

2.4775

ecart-type 0.0026

0.0026

delta 2 theta moyen 0.0019

RESULTAT DU CYCLE
7.0073 -0.0000

7.0073

0.0003

7.0073 -0.0000

7.0073

0.0003

9.0240 -0.0000

9.0240

0.0007

90.0000

0.0000 90.0000

0.0000

90.0000

0.0000 90.0000

0.0000

90.0000

0.0000 90.0000

0.0000

H K L

2 *THETA

2 *THETA CORR

0 0 1 9.024

9.79

9.79

1 0 0 7.007

12.62

12.62

1 0 1 5.535

16.00

16.00

1 1 0 4.955

17.89

17.89

0 0 2 4.512

19.66

19.66

1 1 1 4.343

20.43

20.43

1 0 2 3.794

23.43

23.43

2 0 0 3.504

25.40

25.40

1 1 2 3.336

26.70

26.70

2 0 1 3.266

27.28

27.28

2 1 0 3.134

28.46

28.46

0 0 3 3.008

29.67

29.67

2 1 1 2.960

30.16

30.16

2 0 2 2.767

32.32

32.32

1 0 3 2.764

32.36

32.36

2 1 2 2.574

34.83

34.83

1 1 3 2.571

34.86

34.86

2 2 0 2.477

36.23

36.23

2 2 1 2.389

37.62

37.62

3 0 0 2.336

38.51

38.51

2 0 3 2.282

39.45

39.45

3 0 1 2.261

39.83

39.83

0 0 4 2.256

39.93

39.93

Pour RbUP :
CYCLE NUMERO 2
1 1 0 17.8900 17.8863

0.0037

4.9540

4.9550

0 0 2 19.6600 19.6861 -0.0261

4.5118

4.5059

1 0 2 23.4300 23.4531 -0.0231

3.7937

3.7900

2 0 0 25.4000 25.3999

0.0001

3.5037

3.5037

1 1 2 26.7000 26.7193 -0.0193

3.3360

3.3336

2 1 1 30.1600 30.1677 -0.0077

2.9607

2.9600

2 0 2 32.3200 32.3401 -0.0201

2.7676

2.7659

2 1 2 34.8300 34.8429 -0.0129

2.5737

2.5728

2 2 0 36.2300 36.2280

0.0020

2.4774

2.4775

2 0 3 39.5500 39.4817

0.0683

2.2767

2.2805

ecart-type 0.0294

0.0294

delta 2 theta moyen 0.0183

RESULTAT DU CYCLE
7.0075

0.0000

7.0075

0.0034

7.0075

0.0000

7.0075

0.0034

9.0118

0.0000

9.0118

0.0071

90.0000

0.0000 90.0000

0.0000

90.0000

0.0000 90.0000

0.0000

90.0000

0.0000 90.0000

0.0000

H K L

2 *THETA

0 0 1 9.012

9.81

2 *THETA CORR
9.81

1 0 0 7.007

12.62

12.62

1 0 1 5.532

16.01

16.01

1 1 0 4.955

17.89

17.89

0 0 2 4.506

19.69

19.69

1 1 1 4.342

20.44

20.44

1 0 2 3.790

23.45

23.45

2 0 0 3.504

25.40

25.40

1 1 2 3.334

26.72

26.72

2 0 1 3.266

27.29

27.29

2 1 0 3.134

28.46

28.46

0 0 3 3.004

29.72

29.72

2 1 1 2.960

30.17

30.17

2 0 2 2.766

32.34

32.34

1 0 3 2.761

32.40

32.40

2 1 2 2.573

34.84

34.84

1 1 3 2.569

34.90

34.90

2 2 0 2.478

36.23

36.23

2 2 1 2.389

37.62

37.62

3 0 0 2.336

38.51

38.51

2 0 3 2.281

39.48

39.48

3 0 1 2.261

39.83

39.83

0 0 4 2.253

39.99

39.99