Constantes de ionizao de cidos e bases fracas a 25C

cido

Equao
CH3CO2H H+ + CH3COOH3SO4 H+ + H2AsO4-

Ka
1,8 x 10-5
K1 = 2.5 x 10-4

H2AsO4- H+ + HAsO42-

K2 = 5.6 X 10-8

Arsenoso

HAsO42- H+ +AsO43H3AsO3 H+ + H2AsO3-

K3 = 3.0 x 10-13
K1 = 6.0 x 10-6

Azotdrico
Benzico
Brico

H2AsO3 H+ + HAsO32HN3 H+ + N3C6H6CO2H H+ + C6H5CO2H3BO3 H+ + H2BO3-

K2 = 3.0 x 10-14
1.9 x 10-5
6.3 x 10-5
K1 = 7.3 x 10-3

H2BO3- H+ + HBO32-

K2 = 1.8 x 10-13

Carbnico

HBO32- H+ + BO33H2CO3 H+ + HCO3-

K3 = 1.6 x 10-14
K1 = 4.2 x 10-7

Cinico
Ciandrico
Ctrico

HCO3- H+ + CO32HOCN H+ + OCNHCN H+ + CNH3C6H5O7 H+ + H2C6H5O7-

K2 = 4.8 x 10-11
3.5 x 10-4
4.0 x 10-4
K1 = 7.4 x 10-3

H2C6H5O7- H+ + HC6H5O72-

K2 = 1.7 x 10-5

HC6H5O72- H+ + C6H5O73C6H5OH H+ + C6H5OHF H+ + FHCO2H H+ + HCO2H3PO4 H+ + H2PO4-

K3 = 4.0 x 10-7
1.3 x 10-3
7.2 x 10-4
1.8 x 10-4
K1 = 7.5 x 10-3

H2PO4- H+ + HPO42-

K2 = 6.2 x 10-8

Fosforoso

HPO42- H+ + PO43H3PO3 H+ + H2PO3-

K3 = 3.6 x 10-13
K1 = 1.6 x 10-2

Hipobromoso
Hipocloroso
Nitroso
Oxlico

H2PO3- H+ + HPO32HOBr H+ + OBrHOCl H+ + OClHNO2 H+ + NO2H2C2O4 HC2O4-

K2 = 7.0 x 10-7
2.5 x 10-9
3.5 x 10-8
4.5 x 10-4
K1 = 5.9 x 10-2

Perxido de Hidrognio
Selnico

HC2O4 H+ + C2O42H202 H+ + HO2H2SeO4 H+ + HSeO4-

K2 = 6.4 x 10-5
2.4 x 10-12
K1 = muito grande

Selenoso

HSeO4 H+ + SeO4H2SeO3 H+ + HSeO3-

K2 = 1.2 x 10-2
K1 = 2.7 x 10-3

Sulfdrico

HSeO3- H+ + SeO32H2S H+ + HS-

K2 = 2.5 x 10-7
K1 = 1 x 10-7

HS- H+ + S2-

K2 = 1 x 10-19

Actico
Arsnico

Fenol
Fluordrico
Frmico
Fosfrico

Sulfrico

H2SO4 H+ + HSO4-

K1 = muito grande

Sulfuroso

HSO4- H+ + SO42H2SO3 H+ + HSO3-

K2 = 1.2 x 10-2
K1 = 1.7 x 10-2

Teluroso

HSO3- H+ SO32H2TeO3 H+ + HTeO3-

K2 = 6.4 x 10-8
K1 = 2 x 10-3

HTeO3- H+ + TeO32NH3 + H2O NH4+ + OH-

K2 = 1 x 10-8
1.8 x 10-5
4.0 x 10-10
7.4 x 10-4
K1 = 8.5 x 10-5

Amnia
Anilina
Dimetilamina
Etilenodiamina

C6H5NH2 + H2O C6H5NH3+ + OH(CH3)2NH + H2O (CH3)2NH3+ + OH(CH2)2(NH2)2 + H2O (CH2)2(NH2)H+ + OH(CH2)2(NH2)2H++H2O(CH2)2(NH2)2H2++OH-

Hidrazina
Hidroxilamina
Metilamina
Piridina
Trimetilamina

N2H4 + H2O N2H5+ + OHN2H5+ + H2O N2H62+ + OHNH2OH + H2O NH3OH+ + OHCH3NH2 + H2OCH3NH3+ + OHC5H5N + H2O C5H5NH+ + OH(CH3)3N + H2O (CH3)3NH+ + OH-

K2 = 2.7 x 10-8
K1 = 8.5 x 10-7
K2 = 8.9 X 10-16
6.6 x 10-9
5.0 x 10-4
1.5 x 10-9
7.4 x 10-5