TALLER ESPECTROSMETRIA DE MASAS

1.

CH3

m/z=114
-CH3

1,2 Hm/z=99

m/z=99

-CH2

-H2

-CH2
m/z=71
m/z=85

m/z=69

-CH2

-CH2

1,2 Hm/z=55

-H2

m/z=57

m/z=57
m/z=55

-CH2
-CH2
-H2
m/z=43

-H2
m/z=41

-CH2

-H2
m/z=29

HC=CH2
m/z=27

m/z=39

2-PENTENO
ruptura alfa

CH3

HC

CH3
H

m/z=70

H2C

m/z=55

HC

m/z=41

-CH2

CH2

CH3
H2C

-CH2

m/z=55

m/z=41
HC
CH2

m/z=27

-H2

H2C

H2C

m/z=41

m/z=39
m/z=39

HC

-CH2CH3

CH2

CH3

m/z=70

m/z=41

HC

-CH2

CH2

m/z=27

CH3
H2C

-H2

m/z=41

CH3
H2C

m/Z=53
m/z=55

H2C

ruptura beta
H
H

-H
CH3

CH3

CH3

CH3

m/z=70

m/z=69
1,2 H-

H2C

-CH2

CH3

H2C

HC

m/z=41

CH3

CH2

m/z=55

-CH2

CH2

CH3
H2C

-CH2

m/z=55

m/z=41
HC
CH2

m/z=27
rearreglo McLafferty
H
H3C

CH2

CH

CH2
HC

m/z=70

ruptura alcano

C
H2

H3C

CH2

-CH2=CH2
HC

m/z=42

CH2

CH2CH3

e-

CH2

CH3

m/z=70

m/z=55

-CH3-CH=CH

H2C
CH

CH3

H2C
CH3

m/z=29
m/z=70
-H2

HC
CH2

m/z=27

2-HEXINO

CH2
H3C

m/z=53

-CH2

H2C
H m/z=39

1,2 H-

H2C

m/z=39

CH3

CH3

e-

H3C

H3C

-CH3-C
C

H2C

CH3

m/z=43

-H2
m/z=43

-H2
m/z=41

-CH2

-H2
m/z=29

HC=CH2
m/z=27

fragmentacion tipo alcano

m/z=39

Clorobenceno PM:112/114 g/mol

Cl

Cl

-Cl

- CHCH

-35 ; -37
H

H
51

77

112 / 114

Propil Butil Amina PM: 115g/mol

NH
H3C

CH3

NH

CH3

H3C

115
H

- CH2CH2CH3

NH
H3C

- CH3CH=CH2

CH2

CH2

H
30

72

.
NH

CH3

H3C

NH

CH3

H3C

115
H

H
+

NH
H2C

- CH3CH2
CH3
86

CH2

H
30

CH3

e-

CH2 CH3

H3C

m/z=82
-CH3

-CH2

CH2
H3C

CH2

m/z=53
-CH2

H2C
H m/z=39

m/z=67

1,2 H-

H2C

m/z=39