Pgina 1 de 5

12/3/2014 9:24 PM

Tabla B-1

Tabla B-1.- PARAMETROS DE FUERZA INTERMOLECULAR Y CONSTANTES CRITICAS

Parametros de
Lennard-Jones
PESO
MOLECULAR
(-M-)

SUBSTANCIA

/K

(-A-)

(-K-)

Constantes Criticas b,c,d

Tc
(K)

Pc
(atm)

Vc
3
-1
(cm .g-mol )

Uc
(gcm-1sec-1 x 106)

Elementos
Ligeros
H2
He

2.02
4.00

2.915
2.576

38.0
10.2

33.3
5.26

12.8
2.26

65.0
57.80

34.7
25.4

Ne
Ar
Kr
Xe

20.18
39.94
83.80
131.30

2.789
3.418
3.498
4.055

35.7
124.0
225.0
229.0

44.5
151.0
209.4
289.8

26.9
48.0
54.3
58.0

41.7
75.2
92.2
118.8

156.0
264.0
396.0
490.0

3.617
3.681
3.433
0.000
3.590
3.996
3.470
3.879
4.290
3.653
4.115
4.268
4.982

97.0
91.5
113.0
0.0
110.0
190.0
119.0
220.0
252.0
112.0
357.0
520.0
550.0

132.0
126.2
154.4
268.0
133.0
304.2
180.0
309.7
430.7
0.0
417.0
584.0
800.0

36.4
33.5
49.7
67.0
34.5
72.9
64.0
71.7
77.8
0.0
76.1
102.0
0.0

86.6
90.1
74.4
89.4
93.0
94.0
57.0
96.3
122.0
0.0
124.0
144.0
0.0

193.0
180.0
250.0
0.0
190.0
343.0
258.0
332.0
411.0
0.0
420.0
0.0
0.0

16.04
26.04
28.05
30.07
42.08
44.09
58.12
58.12
72.15
86.17
100.20
114.22
128.25
84.16
78.11

3.822
4.221
4.232
4.418
0.000
5.061
0.000
5.341
5.769
5.909
0.000
7.451
0.000
6.093
5.270

137.0
185.0
205.0
230.0
0.0
254.0
0.0
313.0
345.0
413.0
0.0
320.0
0.0
324.0
440.0

190.7
309.5
282.4
305.4
365.0
370.0
425.2
408.1
469.8
507.9
540.2
569.4
595.0
553.0
562.6

45.8
61.6
50.0
48.2
45.5
42.0
37.5
36.0
33.3
29.9
27.0
24.6
22.5
40.0
48.6

99.3
113.0
124.0
148.0
181.0
200.0
255.0
263.0
311.0
368.0
426.0
485.0
543.0
308.0
260.0

159.0
237.0
215.0
210.0
233.0
228.0
239.0
239.0
238.0
248.0
254.0
259.0
265.0
284.0
312.0

50.49
84.94
119.39
153.84
52.04
60.08
76.14

3.375
4.759
5.430
5.881
4.380
4.130
4.438

855.0
406.0
327.0
327.0
339.0
335.0
488.0

416.3
510.0
536.6
556.4
400.0
378.0
552.0

65.9
60.0
54.0
450.0
59.0
61.0
78.0

143.0
0.0
240.0
276.0
0.0
0.0
170.0

338.0
0.0
410.0
413.0
0.0
0.0
404.0

Gases
Nobles

Sustancias
Poliatomicas
sencillar
Aire
N2
O2
O3
CO
CO2
NO
N2O
SO2
F2
Cl2
Br2
I2
Hidrocarburos
CH4
C2H2
C2H4
C2H6
C3H6
C3H8
n-C4H10
i-C4H10
i-C5H12
i-C6H14
i-C7H16
i-C8H18
i-C9H20
ClicloHexano
C6H6
Otros
Compuestos
CH3Cl
CH2Cl2
CHCl3
CCl4
C2N2
COS
CS2

28.97
28.02
32.00
48.00
28.01
44.01
30.01
44.02
64.07
38.00
70.91
159.83
253.82

Pgina 2 de 5

12/3/2014 9:24 PM

Tabla B-1

OS DE FUERZA INTERMOLECULAR Y CONSTANTES CRITICAS

C
o
n
Kc
(calsec-1cm-1K-1x 106)

0.0
0.0

79.2
71.0
49.4
40.2

90.8
86.8
105.3
0.0
86.5
122.0
118.2
131.0
98.6
0.0
97.0
0.0
0.0
158.0
0.0
0.0
203.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0

0.0
0.0
0.0
0.0
0.0
0.0
0.0

Tabla B-2.- FUNCIONES PARA LA PREDICCION

DE PROPIEDADES DE TRANSPORTE
DE GASES A BAJA DENSIDAD
kT/

u = k

(Para Viscocidad y
Conductividad Calorfica)

kT/AB

,AB
(Para Difusividad)

0.30
0.35
0.40
0.45
0.50
0.55
0.60
0.65
0.70
0.75
0.80
0.85
0.90
0.95
1.00
1.05
1.10
1.15
1.20
1.25
1.30
1.35
1.40
1.45
1.50
1.55
1.60
1.65
1.70
1.75
1.80
1.85
1.90
1.95
2.00

2.785
2.628
2.492
2.368
2.257
2.156
2.065
1.982
1.908
1.841
1.780
1.725
1.675
1.629
1.587
1.549
1.514
1.482
1.452
1.424
1.399
1.375
1.353
1.333
1.314
1.296
1.279
1.264
1.248
1.234
1.221
1.209
1.197
1.186
1.175

2.662
2.476
2.318
2.184
2.066
1.966
1.877
1.798
1.729
1.667
1.612
1.562
1.517
1.476
1.439
1.406
1.375
1.346
1.32
1.296
1.273
1.253
1.233
1.215
1.198
1.182
1.167
1.153
1.14
1.128
1.116
1.105
1.094
1.084
1.075

2.10
2.20
2.30
2.40
2.50
2.60
2.70
2.80
2.90
3.00

1.156
1.138
1.122
1.107
1.093
1.081
1.069
1.058
1.048
1.039

1.057
1.041
1.026
1.012
0.9996
0.9878
0.977
0.9672
0.9576
0.949

Tabla B-2.- FUNCIONES PARA LA PREDICCION

DE PROPIEDADES DE TRANSPORTE
DE GASES A BAJA DENSIDAD
kT/

u = k

(Para Viscocidad y
Conductividad Calorfica)

kT/AB

,AB
(Para Difusividad)

3.10
3.20
3.30
3.40
3.50
3.60
3.70
3.80
3.90
4.00
4.10
4.20
4.30
4.40
4.50
4.60
4.70
4.80
4.90
5.00

1.03
1.022
1.014
1.007
0.9999
0.9932
0.987
0.9811
0.9755
0.97
0.9649
0.96
0.9553
0.9507
0.9464
0.9422
0.9382
0.9343
0.9305
0.9269

0.9406
0.9328
0.9256
0.9186
0.912
0.9058
0.8998
0.8942
0.8888
0.8836
0.8788
0.874
0.8694
0.8652
0.861
0.8568
0.853
0.8492
0.8456
0.8422

6.0
7.0
8.0
9.0
10.0

0.8963
0.8727
0.8538
0.8379
0.8242

0.8124
0.7896
0.7712
0.7556
0.7424

20.0
30.0
40.0
50.0
60.0
70.0
80.0
90.0
100.0

0.7432
0.7005
0.6718
0.6504
0.6335
0.6194
0.6076
0.5973
0.5882

0.664
0.6232
0.596
0.5756
0.5596
0.5464
0.5352
0.5256
0.517

Pgina 5 de 6

12/3/2014 9:24 PM

Viscocidad de 01 a 05 GASES

Desarrollo de clculos para hallar Viscosidad de una mezcla de Varios Gases

Ingresar datos Generales solamente en las Celdas Amarillas

SUBSTANCIAS

SUBSTANCIAS

Presion =
Temperatura =

1 Atm
310 K

Redondear =

1.-)

1.- CO2

2.- O2

3.- N2

2
2.00
5.00
10.00
100.00

1.6316

Multiplo
0.05
0.1
1
10

MEZCLA
GASEOSA

1
2
3
4
5

i
1

CO2
O2
N2

Mi/Mj
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5

O2

3.-)

N2

32.00

28.02

3.996

3.433

3.681

190.00

113.00

91.50

2.7434

3.388

KT/
1.60
1.6316
1.65

Viscocodad

() (9/cm.seg)

Ecuacin de WILKE

Nro.

2.-)

44.01

4.5.-

Rango 01 < 0.30

Rango 02 < 2.00
Rango 03 < 5.00
Rango 04 < 10.00

CO2

/K

Ui
Viscosidad
(g/cm*s)
######## 1.5380E-04
######## 2.1197E-04
######## 1.8218E-04
PM
(g)

Ui/Uj

Mj/Mi

Xi
(Fraccin
Molar)
0.1333
0.0390
0.8280

Oij

Xj*Oij

Sumatoria

U
mezcla p.

1.000
1.375
1.571

1.000
0.726
0.844

1.000
0.727
0.637

1.000
0.732
0.731

0.1333
0.0286
0.6052

0.767

2.67293E-05

0.727
1.000
1.142

1.378
1.000
1.164

1.375
1.000
0.876

1.388
1.000
1.009

0.1850
0.0390
0.8351

1.059

7.806E-06

0.637
0.876
1.000

1.185
0.859
1.000

1.571
1.142
1.000

1.360
0.990
1.000

0.1813
0.0386
0.8279

1.048

1.4397E-04

U mezcla
(g/cm*s)

1.7851E-04

1.279
1.2695
1.264
1.538E-04

2.70
2.7434
2.80

1.069
1.0642
1.058
2.120E-04

3.30
3.388
3.40

1.014
1.0078
1.007
1.822E-04

4.-)

5.-)