Datos:

MB =

MT =

92

Presion =

78
760 mmHg

Destilado:
wB =

99.5

wT =

0.5

Fondo:
wB =

0.05

wT =

99.95

Calculo de Composiciones molares:

wB
M B

(Ec 1)

wB
wT

M B
M T

xD =

xB =

0.99575764

wB
MB
wB
w
T
MB
MT

0.00053339

Calculo de Temperaturas de Ebullicin:

LnP A

B
T C

(Ec 3)

B
C
A LnP

Coeficientes de Antoin :
Componente
Benceno
Tolueno

A
15.9008
16.0137

TebBenc =

353.251885

TebTol =

383.775975

B
2788.51
3096.52

Diagrama de Equilibrio

T(K)
353.3
355
360
365
370
375
380
383.8

Antoin
P Benc
PSatTol
Sat

761.126926
801.792168
931.318744
1076.60066
1238.87913
1419.42803
1619.55046
1785.55105

C
-52.36
-53.67

Sat
P P2Sat
x B Sat Sat y P1 * x
P1 P2 B P B

xB

yB

292.721255 0.99759412 0.99907335

310.295286 0.91496962 0.96528352
366.960737 0.69643605 0.85342625
431.642541 0.50911439 0.72120117
505.126378 0.34735627 0.56622689
588.235282 0.20664848 0.38595085
681.828216 0.08336347 0.17764652
760.518999 -0.00050632 -0.00118956

1
0.9
0.8
0.7

0.6

0.6
0.5

Calculo de Temperatura de Tope y de Fondo:

0.4

Del Diagrama :

0.3

T Tope

353.55

T Fondo

383.75

0.2
0.1

P exp( A

B
)
T C

(Ec 5)

Remeplazando en la Ec. 5:
Psat BencTope

767.003444 mmHg

Psat BencFondo

1783.28591 mmHg

Psat TolcTope

295.254094 mmHg

Psat TolFondo

759.439204 mmHg

a Tope =

PsatTolTope
a Fondo =

2.59777412

Calculo de a fondo:
a Tope =

2.34816151

Calculo de a promedio:

a PROM (aTOPE * a Fondo )1/ 2

a prom =

2.46981643

PsatBenFondo
PsatTolFondo

Calculo de a Tope:
a Tope =

PsatBenTope

RPTA

wB
MB

(Ec 2)

wB
w
T
MB
MT

B
C
A LnP

(Ec 4)

T (K)
383

378

373

368

363

Series1

358

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

353
0
0.9

0.1

0.2

0.3

Curva del Punto de Ebullicion

(Ec 6)

(Ec 7)

Diagrama de Fases

0.4

0.5

0.6

Fraccion Molar
Curva del Punto de Ebullicion

Curva del Punto de Roco

0.7

0.8

0.9

383.75
T (K)

384
383
382
381
380
379
378
377
376
375
374
373
372
371
370
369
368
367
366
365
364

364
363
362
361
360
359
358
357
356
355
354
353.55
353
0

0.1

0.2

0.3

0.4

Diagrama de Fases

0.5

0.6

Fraccion Molar
Curva del Punto de Ebullicion

Curva del Punto de Roco

0.7

0.8

0.9