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Constantes de Antoine

presin en KiloPa y T en C

Sistema:
A1
A2
A3

Acetonitrilo(A)
14.2724
2945.47
224

Nitrometano(B)
14.2043
2972.64
209

Constantes de Antoine
presin en KiloPa y T en C

Sistema:
A1
A2
A3

Benceno(A)
13.8858
2788.51
220.79

Etilbenceno(B)
14.0045
3279.47
213.2

Constantes de Antoine
presin en KiloPa y T en C

Sistema: 1-Clorobutano(A) Clorobenceno(B)


A1
13.96
13.9926
A2
2826.26
3295.12
A3
224.1
217.55

Constantes de Antoine
presin en KiloPa y T en C

Sistema:
A1
A2
A3

Acetona(A)
14.5463
2940.46
237.22

Acetonitrilo(B)
14.2724
2945.47
224

Constantes de Antoine
presin en KiloPa y T en C

Sistema:
A1
A2
A3

n-Pentano(A)
13.8183
2477.07
233.21

n-Heptano(B)
13.8587
2911.32
216.64

Constantes de Antoine
presin en KiloPa y T en C

Sistema:
A1
A2
A3

Benceno(A)
13.8858
2788.51
220.79

Tolueno(B)
13.9987
3096.52
219.48

lnP sat A1

A2
T A3

Constantes de Antoine
presin en KiloPa y T en C

Sistema:
A1
A2
A3

Constantes de Antoine
presin en KiloPa y T en C

Sistema: 1-Clorobutano(A)
A1
13.96
A2
2826.26
A3
224.1

Benceno(B)
13.8858
2788.51
220.79

Constantes de Antoine
presin en KiloPa y T en C

Sistema:
A1
A2
A3

n-Pentano(A)
13.8183
2477.07
233.21

n-Hexano(B)
13.8216
2697.55
224.37

Sistema:
A1
A2
A3

n-Hexano(A)

Trietilamina(B)

lnP sat A1

A2
T A3

Benceno(A)
13.8858
2788.51
220.79

Etilbenceno(B)
14.0045
3279.47
213.2

Sistema:
A1
A2
A3

Constantes de Antoine
presin en mm Hg y T en C

xA
yA

P B PvB
A PvA B PvB

A PvA
P

ln

ln

Etanol(A)
8.1122
1592.864
226.184

alfa=
beta=

xA

Benceno(B)
6.89272
1203.531
219.888

Ingrese la Presin,mm Hg =

0.8552
0.7526

lnP sat A1

A2
T A3

L
A

xA
xB

xB
xA

L
B

1bar=
1atm=
1atm=
1atm=
1atm=

100 Kpa
760 mm Hg
14,696 psi
1,01325 bar
101,325 Kpa

DIAGRAMA P-x,y a Temperatura con


Ingrese la Temperatura en C =
1000

950

900

850

EATANOL(A)-BENCENO(B)

800

750
0

0.1

0.2

0.3

0.4

0.5

X,Y

0.6

0.7

0.8

0.9

Ingrese la Presin,mm Hg =

760
78.2981919
80.1017998

TsA=
TsB=
T C
80
79
77
75
74
73.4595
74
75
76
77
78
78.8

PsA
812.625185
781.346747
721.79442
666.079346
639.599122
625.657011
639.599122
666.079346
693.469667
721.79442
751.078377
775.213095

PsB
xAsupuesto
757.620493 0.002702611
734.555105 0.02456515
690.078278 0.08611708
647.745466 0.19561888
627.360348 0.30888862
616.554615
0.45
627.360348 0.68334327
647.745466 0.80876185
668.64843 0.88552103
690.078278 0.94242932
712.044112 0.98798258
730.008852 1.01892289

A
2.33955
2.24404
2.00926
1.6904
1.45663
1.25817
1.0744
1.0257
1.00896
1.00223
1.0001
1.00024

B
xA calculado yA
1.00001 0.00207611
0.0067607
1.00058 0.02456515 0.05667348
1.00707 0.08611708 0.16433342
1.03591 0.19561888 0.28980975
1.08913 0.30888862 0.37865777
1.19088 0.48653351 0.46609411
1.4619 0.68334327 0.61787114
1.67475 0.80876185 0.72703002
1.83437 0.88552103 0.81524489
1.96948 0.94242932 0.89704734
2.08912 0.98798258 0.97647834
2.17671 1.01892289
1.0395643

DIAGRAMA P-x,y a Temperatura constante


Ingrese la Temperatura en C =
PsA=
PsB=
P mm Hg
760
770
780
790
800
820
850
860
890
900
950
960
955
950
900

PsA
812.625185
812.625185
812.625185
812.625185
812.625185
812.625185
812.625185
812.625185
812.625185
812.625185
812.625185
812.625185
812.625185
812.625185
812.625185

80
812.625185 puro
757.620493 puro
PsB
xAsupuesto
757.620493 0.00207384
757.620493
0.0110403
757.620493 0.02044134
757.620493 0.03032052
757.620493 0.04072834
757.620493 0.06337627
757.620493 0.10319225
757.620493
0.1184953
757.620493 0.17326121
757.620493 0.19558541
757.620493 0.38801372
757.620493
0.49
757.620493 0.62134627
757.620493 0.66536752
757.620493
0.8528907

2.3424
2.3023
2.26153
2.22003
2.17775
2.09057
1.952
1.90327
1.74693
1.69048
1.33499
1.21586
1.10984
1.08383
1.01496

1
1.00012
1.0004
1.00089
1.0016
1.00384
1.01011
1.0133
1.02823
1.0359
1.14108
1.22755
1.37557
1.43568
1.76351

xA calculado yA
0.00207384 0.00519413
0.0110403 0.02682517
0.02044134 0.04816224
0.03032052 0.06924016
0.04072834 0.09009571
0.06337627 0.13130114
0.10319225 0.19257446
0.1184953 0.21310474
0.17326121 0.27636172
0.19558541 0.29853487
0.38801372 0.44308865
0.5167472 0.50431183
0.62134627
0.5867868
0.66536752 0.61686235
0.8528907 0.78161273

860
820
810

812.625185 757.620493 0.93176209 1.00314 1.94298


812.625185 757.620493 0.99055167 1.00006 2.09619
812.625185 757.620493 1.003278734 1.00001 2.13176

0.93176209
0.99055167
1.00327873

0.8831987
0.98170114
1.00653749

ETANOL(A)-BENCENO(B)
81
80
79
78

77

76
75
74
73
0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

x, y

gE
RT

P mm Hg
760
770
780
790
800
820
850
860
890
900
950
960
955
950
900

0.00176937
0.00932339
0.0170765
0.02504039
0.03322778

xi ln xi

-0.01488458
-0.06072896
-0.09975179
-0.13585457
-0.17025199

g
RT
-0.01311522
-0.05140557
-0.08267529
-0.11081418
-0.13702421

0.9

0.8

0.7

0.6

0.5

0.4

860
820
810

0.3

0.2

0.1

0
0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9