7.

Enunciado
Diferenciar los datos experimentales de una corrida por algn mtodo numrico y
use el mtodo diferencial para interpretar los datos.

7.1 Solucin
Este mtodo es muy impreciso ya que la solucin se basa en una relacin de
diferenciales de concentraciones y de tiempos.

7.2 Tabla de resultados

Se muestra la tabala de resultados obtenidos para uno de los experimentos
variando la concenrtacion inicial de Yoduro. Seleccionamos el experimento con
CA0=300 mg/L
Tiempo, min
0
0.25
0.5
0.75
1
1.25
1.5
1.75
2
2.5
3
3.5
4
4.5
5
5.5
6
6.5
7
7.5
8
8.5
9
9.5
10

C/C0
1
0.9876468
0.97544621
0.96339633
0.9514953
0.93585564
0.92429483
0.91666708
0.90159989
0.88311369
0.86859802
0.83334412
0.81625742
0.79952107
0.7766651
0.75759503
0.7359376
0.72684642
0.70899958
0.68873136
0.67182039
0.65261501
0.64188803
0.6287269
0.61075344

dt

dCa

-ra

-ln(-ra)

0.25
0.25
0.25
0.25
0.25
0.25
0.25
0.25
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5

-0.0123532
-0.0122006
-0.01204988
-0.01190103
-0.01563966
-0.01156081
-0.00762776
-0.01506719
-0.01848619
-0.01451567
-0.0352539
-0.01708669
-0.01673635
-0.02285597
-0.01907008
-0.02165743
-0.00909118
-0.01784684
-0.02026822
-0.01691097
-0.01920538
-0.01072698
-0.01316112
-0.01797346

-0.04941279
-0.04880239
-0.04819952
-0.0476041
-0.06255863
-0.04624324
-0.03051103
-0.06026875
-0.03697239
-0.02903135
-0.0705078
-0.03417339
-0.0334727
-0.04571194
-0.03814015
-0.04331485
-0.01818237
-0.03569367
-0.04053645
-0.03382194
-0.03841076
-0.02145397
-0.02632225
-0.03594693

3.00754596
3.01997609
3.03240622
3.04483636
2.7716511
3.07384
3.48966713
2.8089415
3.29758389
3.53937908
2.6520319
3.37630806
3.39702495
3.08539581
3.26648775
3.13925972
4.00730308
3.33278179
3.20555376
3.3866457
3.25941767
3.84184564
3.63734085
3.32571171

10.5
11
11.5
12
12.5
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50

0.5982307
0.58839762
0.57395023
0.55754267
0.54837838
0.53270185
0.51108101
0.4903377
0.4704363
0.45134264
0.43302394
0.41544874
0.39858686
0.38559147
0.36994142
0.3564002
0.34478024
0.33353914
0.32266454
0.31214449
0.30322119
0.29333506
0.28494947
0.2768036
0.26889059
0.26012377
0.25373675
0.24853419
0.24043106
0.23452756
0.23067265
0.22594299
0.21948394
0.2149837
0.21057572
0.20625812
0.20455598
0.20036181
0.19625364
0.19382928
0.18985505
0.18750973
0.18519338

0.5
0.5
0.5
0.5
0.5
0.5
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

-0.01252275
-0.00983307
-0.01444739
-0.01640756
-0.00916429
-0.01567653
-0.02162084
-0.02074331
-0.0199014
-0.01909366
-0.0183187
-0.0175752
-0.01686187
-0.0129954
-0.01565005
-0.01354121
-0.01161996
-0.0112411
-0.0108746
-0.01052005
-0.0089233
-0.00988613
-0.00838559
-0.00814587
-0.00791301
-0.00876682
-0.00638703
-0.00520256
-0.00810313
-0.00590349
-0.00385491
-0.00472966
-0.00645905
-0.00450025
-0.00440798
-0.0043176
-0.00170215
-0.00419417
-0.00410817
-0.00242436
-0.00397423
-0.00234532
-0.00231634

-0.02504549
-0.01966615
-0.02889479
-0.03281512
-0.01832857
-0.03135307
-0.02162084
-0.02074331
-0.0199014
-0.01909366
-0.0183187
-0.0175752
-0.01686187
-0.0129954
-0.01565005
-0.01354121
-0.01161996
-0.0112411
-0.0108746
-0.01052005
-0.0089233
-0.00988613
-0.00838559
-0.00814587
-0.00791301
-0.00876682
-0.00638703
-0.00520256
-0.00810313
-0.00590349
-0.00385491
-0.00472966
-0.00645905
-0.00450025
-0.00440798
-0.0043176
-0.00170215
-0.00419417
-0.00410817
-0.00242436
-0.00397423
-0.00234532
-0.00231634

3.68706138
3.92885657
3.54409404
3.41686602
3.99929399
3.46244317
3.83409764
3.87553141
3.91696519
3.95839897
3.99983274
4.04126652
4.08270029
4.34315999
4.15728109
4.30201728
4.45503119
4.48817821
4.52132523
4.55447225
4.71908971
4.61662292
4.78124037
4.81024401
4.83924766
4.73678087
5.05348661
5.25860461
4.81550504
5.13221078
5.55840709
5.3539023
5.04227316
5.40362283
5.42433972
5.4450566
6.37586418
5.47406025
5.49477713
6.02218771
5.52792416
6.05533473
6.06776487

51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68

0.18214937
0.17989925
0.17841463
0.17621063
0.17475645
0.17259765
0.17117329
0.16976068
0.16905875
0.16766359
0.16627994
0.16354681
0.16219714
0.16152649
0.16019349
0.15953112
0.15821459
0.1575604

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

-0.00304401
-0.00225013
-0.00148462
-0.00220399
-0.00145418
-0.0021588
-0.00142436
-0.00141261
-0.00070193
-0.00139516
-0.00138365
-0.00273313
-0.00134967
-0.00067065
-0.001333
-0.00066237
-0.00131653
-0.00065419

-0.00304401
-0.00225013
-0.00148462
-0.00220399
-0.00145418
-0.0021588
-0.00142436
-0.00141261
-0.00070193
-0.00139516
-0.00138365
-0.00273313
-0.00134967
-0.00067065
-0.001333
-0.00066237
-0.00131653
-0.00065419

5.79457961
6.09676851
6.51259564
6.1174854
6.53331253
6.13820229
6.55402942
6.56231617
7.26168056
6.5747463
6.58303306
5.90230743
6.60789332
7.30725772
6.62032346
7.31968785
6.63275359
7.33211798

Tabla 7.1 Calculo por el mtodo diferencial

Linealizacin de datos por el mtodo

diferencial
8
7

In (-ra)

6
5
4
3

Series1

2
1
0
0

10

20

30

40

50

60

70

80

Tiempo, min

Como se muetsra en la grfica a pesar de que los datos conservan una

misma tendencia, es imposible linealizarlos de forma eficiente lo que implica que
el metoo no es apropiado para anlisis de la reaccin.