Thermodynamic Properties for Mixtures from the Peng-Robinson Equation of State

Solution by Phillip Savage - University of Michigan

R = 8.31E-06 m^3 MPa/mol-K

Enter data into outlined cells only

T=
500.0
K
P = 5.00E+01 MPa
use binary interaction parameters?
yes
Compound
Z=
1.09E+00
f=
4.79E+01 MPa
Argon
H=
6.25E+03 J/mol
CO2
S = -7.13E+01 J/mol-K
CO
G=
4.19E+04 J/mol
Ethane
A=
3.74E+04 J/mol
Methane
U=
1.72E+03 J/mol
Methanol
V=
9.06E-05 m^3/mol
N2
O2
H-Higm = -2.93E+03 J/mol
Propane
S-Sigm = -5.51E+00 J/mol-K
Water
G-Gigm = -1.80E+02 J/mol
Higm =
9.18E+03 J/mol
Sigm = -6.58E+01 J/mol-K
Compound Moles in
Mixture
Argon
CO2
CO
Ethane
Methane
Methanol
N2
O2
Propane
Water

0.000
50.000
0.000
0.000
50.000
0.000
0.000
0.000
0.000
0.000

TOTAL

100.000

Tc
(K)
150.8
304.2
133.0
305.4
190.7
513.2
126.2
154.4
369.8
647.3

Pc
(MPa)
4.874
7.376
3.496
4.884
4.600
7.954
3.394
5.046
4.246
22.048

Pseudocritical Properties from Kay's Rules

T'c = 247.45
K
P'c = 5.99
MPa
T'r = 2.0206
P'r = 8.3500
Mole
Frac
0.000
0.500
0.000
0.000
0.500
0.000
0.000
0.000
0.000
0.000

T ref =
P ref =

Calculate parameters in Peng-Robinson EOS

am = 1.87E-07 m^6 MPa/mol^2
bm = 2.67E-05 m^3/mol
Am = 5.40E-01
Bm = 3.22E-01
dam/dT = -3.74E-10 m^6 MPa/mol^2-K
Solve Peng-Robinson EOS for Z
a1 = -6.78E-01
Q = 1.9E-01
a2 = -4.13E-01
R = -7.7E-02
a3 = -3.71E-02Q^3-R^2= 8.4E-04

fugacity
(MPa)
0.00E+00
2.13E+01
0.00E+00
0.00E+00
2.69E+01
0.00E+00
0.00E+00
0.00E+00
0.00E+00
0.00E+00 0.00E+00

Three Real Roots Exist

Theta =
2.7804 Z min = -0.2959
Z1 =
-0.2959 fugacity = #NUM!
Z2 =
1.0892 Z max = 1.0892
Z3 =
-0.1150 fugacity = #######
Flag for Z<0
1fug ratio = #NUM!

1.000
w

-0.004
0.225
0.049
0.098
0.008
0.559
0.040
0.021
0.152
0.344

2.00E-05
2.67E-05
2.46E-05
4.04E-05
2.68E-05
4.17E-05
2.41E-05
1.98E-05
5.63E-05
1.90E-05

0.368
0.708
0.450
0.523
0.387
1.152
0.436
0.407
0.603
0.873

0.487
0.640
0.334
0.729
0.578
1.030
0.323
0.455
0.813
1.223

7.17E-08
2.54E-07
5.34E-08
4.40E-07
1.44E-07
1.08E-06
4.79E-08
6.80E-08
8.28E-07
7.34E-07

Constants in Cp=a+bT+cT^2+dT^3 (J/mol-K)

Cpa
Cpb
Cpc
Cpd
2.08E+01
2.22E+01
2.71E+01
6.90E+00
1.99E+01
1.90E+01
2.89E+01
2.82E+01
6.80E+01
2.92E+01

0.00E+00
5.98E-02
6.55E-03
1.73E-01
5.02E-02
9.15E-02
-1.57E-03
6.30E-03
2.26E-01
1.45E-02

273.159 K
0.001 MPa

0.00E+00
-3.50E-05
-9.99E-07
-6.40E-05
1.27E-05
-1.22E-05
8.08E-06
-7.49E-07
-1.31E-04
-2.02E-06

0.00E+00
7.46E-09
0.00E+00
7.28E-09
-1.10E-08
-8.03E-09
-2.87E-09
0.00E+00
3.17E-08
0.00E+00

2.11E+01 5.50E-02 -1.12E-05 -1.77E-09

Binary Interaction Parameters:

Argon
CO2
CO
Ethane
Methane
Methanol
N2
O2
Propane
Water

Argon

CO2

CO

0
0
0
0
0
0
0
0
0
0

0
0
0.3
0.13
0.09
0
-0.02
0
0.12
0

0
0.3
0
0.026
0.03
0
0.012
0
0.03
0

Ethane Methane
0
0.13
0.026
0
-0
0
0.044
0
0.001
0

0
0.09
0.03
-0.003
0
0
0.03
0
0.016
0

Methanol

N2

O2

Propane

Water

0
0
0
0
0
0
0
0
0
0

0
-0.02
0.012
0.044
0.03
0
0
0
0.078
0

0
0
0
0
0
0
0
0
0
0

0
0.12
0.03
0.001
0.016
0
0.078
0
0
0

0
0
0
0
0
0
0
0
0
0