1.

Calcular la temperatura del unto burbuja y la composicin de equilibrio asociada con

una mezcla liquida de 25% mol de pentano y 75% mol de hexano a 90 Kpa utilizando
los mtodos de biseccin , secante y newton raphson con una tolerancia de 1e-4 de
error relativo .
Componente
A
B
C
TC
Pentano
13.8183
2477.07
233.31
30
Hexano
13.8216
2697.55
224.37
69
Ln P = A-

, T = C

P= mmHg

Solucin :
Teorema de la Biseccin:
P= 90 Kpa
1Kpa
90 Kpa

0.0098692atm
x1
X1 = 0.82230946 atm x760mmHg= 675.022 mmHg

X1.Z1 = 1
XI = MOL DE HEXANO =0.75

X2= MOL DE PENTANO = 0.25

ZI= -

Zi-2=

Zi =

+ 0.75

0.25x

- 675 = 0

El intervalo aceptable fue de (4-34) c

F(4) = -4.447233532
F(34)= 9961,22197
F(19) = 2216.626391
F()
19 +
4 -

x=

9:

= 11.5

f(11.5)= 747.9879099

ACEPTABLE

x=

= 19

F()

F()
11.5 +
4

F()
7.75 +
4 -

x=

= 7.75

f(7.75)= 307.3784892

x=

= 5.875

f(5.875)= 137.8036403

F()
5.875 +
4
-

x=

= 4.9375

f(4.9375)= 63.53073078

F()
4.9375 +
4
-

x=

=4.46875

f(4.46875)= 28.78631185

F()
4.46875 +
4
-

x=

=4.234375

f(4.234375)= 11.98448547

F()
4.234375 +
4

F()
4.1171875 +
4

F()
4.05859375 4.1171875 +

x=

=4.1171875

f(4.1171875)= 3.7228307

x=

=4.05859375

f(4.05859375)=-0.3735922254
)= 3.7228307
x=

8 9

8 9

=4.087890625

f(4.087890625)= 1.671764347
)=-0.3735922254

F()
4.05859375 4.087890625 +

F()
4.05859375 4.073242188 +

F()
4.05859375 4.065917969 +

x=

8 89

x=

x=

8 9

88:

8 9

9 9:

8 9

=4.073242188

=4.065917969

=4.06225586


4.05859375
4.05859375
4.06225586
4.06225586

4.05859375
4.060424805

F()
++
F()
+

x=

x=

8 :

8 9

8 9

ENTONCES EL ERROR:

4.060424805-4.059509278 = 9.15527 X 10 -4

La Temperatura para llevarse acabo el punto de burbuja ser :

-

4.059509278 c

=4.060424805

=4.059509278