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Reservoir Fluid Study

for
OCCIDENTAL DE COLOMBIA
Caricare-3 Well, Form.: C5
RFL 06089

The analyses, opinions or interpretations in this report are based on observations and material supplied
by the client to whom, and for whose exclusive and confidential use, this report is made. The
interpretations or opinions expressed represent the best judgement of Core Laboratories Venezuela,
S.A. (all errors and omissions excepted); but Core Laboratories Venezuela, S.A. and its officers and
employees assume no responsibility and make no warranty or representations as to the productivity,
proper operation or profitability of any oil, gas or any other mineral well formation in connection with
which such report is used or relied upon.

Core Laboratories
Cra 39 Nro. 168-52, Bogot, Colombia
Tel: +57 (1) 6740400 Fax: +57 (1) 6730060 Web: http://www.corelab.com

Core Laboratories
Cra. 39 Nro. 168-52
Bogot, Colombia
Tel: 57 1 6740400
Web: http://www.corelab.com

August 22nd, 2006

Occidental de Colombia.
Bogota, Colombia.
Attention : Eng. Aldo Caliz
Subject:
Well:
Formation:
Interval:
File:

Reservoir Fluid Study


Caricare-3
C5
9554'-9562'
0603089

Dear Sirs.:
Two bottomhole samples from the subject well were collected on May 23rd of 2006 by Core
Laboratories representatives and delivered to our fluid laboratory in Bogot for use in the
performance of a Reservoir Fluid Study. The samples were transported to the laboratory
whereupon sample validation and analysis commenced.
Preliminary results were reported during the execution of the study and the final report is
presented in the following pages.
It has been a pleasure to perform this study for Occidental de Colombia. Should any
questions arise or if we may be of further service in any way, please do not hesitate to
contact us.

Sincerely,
CORE LABORATORIES VENEZUELA, S.A.

David McEvoy
Manager
Reservoir Fluids Laboratory

OCCIDENTAL DE COLOMBIA
Caricare-3
Well, Form.: C5
RFL 06089
___________________________________________________________________________________________
Table of Contents
Section A - Summary of PVT Methods and Data

Page

Summary of analysis methods........................................................................................

A.1-A.3

Summary of PVT data.....................................................................................................

A.4

Section B - Summary of Samples Received and Validation Data


Well information...............................................................................................................

B.1

Summary of samples received .......................................................................................

B.2

Section C - Compositional Analysis of Bottomhole Fluid Sample to C36+


Compositional analysis of bottomhole fluid sample to C36+...........................................

C.1-C.2

Section D - Constant Composition Expansion


Constant composition expansion at 198 F.....................................................................

D.1-D.2

Graphs from constant composition expansion at 198 F................................................

D.3

Partial constant composition expansion at 120 F..........................................................

D.4-D.5

Partial constant composition expansion at 86 F............................................................

D.6-D.7

Partial constant composition expansion at laboratory ambient temperature (68 F).......

D.8-D.9

Section E - Differential Vaporization


Differential vaporization data...........................................................................................

E.1

Graphs from differential vaporization data.......................................................................

E.2

Differential vaporization data converted to surface separator conditions........................

E.3-E.4

Section F - Bottomhole Fluid Viscosity Data


Bottomhole fluid viscosity data........................................................................................

F.1

Graph from bottomhole fluid viscosity data.....................................................................

F.2

Section G - Separator Test Data


Separator test 1...............................................................................................................

G.1

Compositional analysis of gas sample from separator test 1..........................................

G.2

Separator test 2...............................................................................................................

G.3

Compositional analysis of gas sample from separator test 2..........................................

G.4

Section H - Appendix
Data used in gas compositional calculations...................................................................

H.1

Data used in liquid compositional calculations................................................................

H.2

___________________________________________________________________________________________
Core Laboratories
Bogot, Colombia

OCCIDENTAL DE COLOMBIA
Caricare-3
Well, Form.: C5
RFL 06089
___________________________________________________________________________________________

Section A - Summary of PVT Analysis Methods and Data

___________________________________________________________________________________________
Core Laboratories
Bogot, Colombia

OCCIDENTAL DE COLOMBIA
Caricare-3
Well, Form.: C5
RFL 06089
___________________________________________________________________________________________

Summary of Analysis Methods

Sample Validation
The bubble point pressure at ambient temperature and free water content of each bottomhole
sample were determined as initial quality checks. From this quality control, the measured bubble
point pressures of the samples showed good agreement with one another and very little free water
was measured.
Heat Treatment
The selected bottomhole fluid sample was heated to 200F prior to subsampling for laboratory tests
to avoid potential wax deposition problems.
Pressurized Fluid Composition
Approximately 30 cc of pressurized fluid was flashed to atmospheric pressure at 120 F and
separated into gas and oil phase. The evolved gas and residual liquid were analyzed separately,
using gas-liquid chromatography and recombined on a weight basis to produce a C36+ weight
percent composition.
Gas Compositions
Gas composition were measured using a "one shot" Varian 3800 gas analyzer using GPA 2286
method. The gas chromatograph utilizes 3 columns to clearly identify all of the eluted components
from N2, CO2 and C1 through C11+.
The chromatograph is calibrated weekly using air and synthetic hydrocarbon gas with a known
composition. The resultant calibration data is checked statistically against previous calibrations
prior to performing analyses on unknown samples.
Liquid Composition
Residual/stocktank liquid composition were measured using a Varian 3400 chromatograph. The
gas chromatograph utilizes a cold on column, "sandwich injection" technique to ensure that a
representative sample is injected and swept onto the column. The sample is run twice; first the
original fluid and then fluid spiked with n-tetradecane. This allows the laboratory to take into
account any heavy end (C36+) losses that may have occurred during the chromatographic run, and
make an accurate correction prior to reporting the liquid composition. The data obtained from the
gas chromatograph is in weight %. Calculations to mole% and the plus fractions properties are
described later.
The chromatograph for liquid samples is checked daily, using a gravimetric n-paraffin mix
containing a range of pure components from C8 through C36 and a synthetic gas-oil mix (D2887)
with known composition. The resultant calibration data is checked statistically against previous
calibrations prior to performing analyses on unknown samples.

___________________________________________________________________________________________
A.1
Core Laboratories
Bogot, Colombia

OCCIDENTAL DE COLOMBIA
Caricare-3
Well, Form.: C5
RFL 06089
___________________________________________________________________________________________

Summary of Analysis Methods (Continuation)

Calculation of Mole% Compositions and Plus Fraction Properties


The residue or stocktank liquid whole sample molecular weight and density are measured using a
cryscope and a PAAR densitometer respectively.
The mole% data is calculated using GPSA mole weight and density data, where individual
components are identified, from carbon dioxide through decanes. Katz and Firoozabadi data are
used from undecanes through pentatriacontanes. The residue mole weight and density values are
calculated so that the pseudo average mole weight and density are the same as the measured
values. This can lead to anomalous residue mole weights and densities where the Katz and
Firoozabadi values may not be suitable for the isomer groups detected.
Other alternatives are to use an assumed C36+ molecular weight and density value, use a linear
extrapolation technique for components from C10 to C35 to calculate the C36+ properties or to
utilise distillation analysis to produce a C11+, C20+ or C36+ residual oil fraction and physically
measure the molecular weight and density.
Constant Composition Expansion
A portion of the bottomhole fluid sample was charged to a high pressure visual cell at ambient
laboratory temperature . A partial constant composition expansion was carried out during which
the bubble point pressure at ambient temperature was determined. This process was repeated for
temperatures of 86F and 120F and finally the sample was thermally expanded to the reservoir
temperature for the complete constant composition expansion test. Pressure-volume data for the
single phase and two phase fluid were also determined. The density of the single phase fluid was
determined by weighing measured volumes pumped from the cell at 5000 psig. Density data for
other pressures were calculated using the volumetric data.
Differential Vaporization
This was carried out in a high pressure visual cell, at reservoir temperature. At several pressure
stages below the observed saturation pressure, the sample was stabilized. The gases evolved
were then pumped out of the cell and its volume, compressibility and gravities were determined.
The final stage was carried out at atmospheric pressure when the residual liquid was pumped out of
the cell and its volume, density and molecular weight were measured.

___________________________________________________________________________________________
A.2
Core Laboratories
Bogot, Colombia

OCCIDENTAL DE COLOMBIA
Caricare-3
Well, Form.: C5
RFL 06089
___________________________________________________________________________________________

Summary of Analysis Methods (Continuation)

Reservoir Fluid Viscosity


Live-oil viscosity was measured in an electromagnetic viscometer at reservoir temperature.
Viscosity determinations were carried out over a wide range of pressures from above the reservoir
pressure to atmospheric pressure.
The measurements were repeated at each pressure stage until five or more results agreed to within
0.5%. The densities, obtained from the constant composition expansion and differential
vaporization tests, were used in the calculation of viscosities in centipoise.
Separator Tests
Finally, two single-stage separator tests were carried out using a pressurized test separator cell. A
portion of the bottomhole fluid sample, at a pressure above saturation pressure, was pumped into
the separator cell and stabilized at the pressure and temperature required for the first stage
separation. The gas evolved was pumped out of the cell and the volume and composition were
determined. The final stage was carried out at atmospheric pressure and separator temperature
and the density of the residual liquid was determined.

___________________________________________________________________________________________
A.3
Core Laboratories
Bogot, Colombia

OCCIDENTAL DE COLOMBIA
Caricare-3
Well, Form.: C5
RFL 06089
___________________________________________________________________________________________

Summary of PVT Data


Constant Composition Expansion at Laboratory Ambient Temperature (68 F)
Saturation pressure (bubble-point)

66 psig

Constant Composition Expansion at 86 F


Saturation pressure (bubble-point)

72 psig

Constant Composition Expansion at 120 F


Saturation pressure (bubble-point)

83 psig

Constant Composition Expansion at 198 F


Saturation pressure (bubble-point)

104 psig

Average single phase compressibility


(From 2526 psig to 104 psig)

7.00

Thermal expansion at 5000 psig


(Vol at 198F)/(Vol at 60F)

x 10 -6 psi-1

1.0320 vol / vol

Differential Vaporization at 198 F


Solution gas-oil ratio at saturation pressure

19 scf/bbl of residual oil at 60F

Relative oil volume at saturation pressure

1.075 vol / vol of residual oil at 60F

Density at saturation pressure

0.8214 g cm-3

Bottomhole Fluid Viscosity at 198 F


Viscosity at reservoir pressure

centipoise at 2526 psig

Viscosity at saturation pressure

centipoise at 104 psig

Separator Test Data


Pressure
(psig)

Temperature Formation Volume


(F)
Factor
(Bl sat/bbl)

Total Solution
Gas-oil ratio
(scf/bbl)

Stocktank Oil
Density at 60 F
(g cm-3)

Test 1
104

198

60
0

200
200

959

198

30
0

200
200

1.076

20
0.8782

Test 2
1.075

19
0.8776

___________________________________________________________________________________________
A.4
Core Laboratories
Bogot, Colombia

OCCIDENTAL DE COLOMBIA
Caricare-3
Well, Form.: C5
RFL 06089
___________________________________________________________________________________________

Section B - Summary of Samples Received and Validation Data

___________________________________________________________________________________________
Core Laboratories
Bogot, Colombia

OCCIDENTAL DE COLOMBIA
Caricare-3
Well, Form.: C5
RFL 06089
___________________________________________________________________________________________

Reported Well and Sampling Information


Reservoir and Well Information
Field......................................................................... Caricare
Well.......................................................................... Caricare-3
Reservoir Fluid......................................................... Black Oil
Formation................................................................. C5
Current Reservoir Pressure .................................... 2541.2 psia
Reservoir Temperature............................................ 197.9 F
Installation................................................................ *
DST.......................................................................... *
Perforated Interval .................................................. 9554'-9562'
Sampling Information
Date sampled...........................................................
Time sampled .........................................................
Type of samples.......................................................
Sampling company..................................................
Sampling Depth......................................................

23-May-06
1:30 PM
Bottomhole
Core Laboratories
6,800 ft

Choke....................................................................... *
Status of well............................................................ *
Bottomhole pressure................................................ 1770 psia
Bottomhole temperature.......................................... *
Wellhead pressure................................................... *
Wellhead temperature............................................. *
Separator pressure ................................................. *
Separator temperature ............................................ *
Pressure base.......................................................... *
Temperature base ................................................... *
Separator gas rate...................................................
Separator oil rate .....................................................
Water flowrate..........................................................
Gas gravity (Air = 1).................................................
Supercompressibility factor......................................
H2S..........................................................................
BS&W......................................................................
API Oil Gravity .........................................................

*
*
*
*
*
*
*
30

Comments:
* Data not provided to Core Laboratories

___________________________________________________________________________________________
B.1
Core Laboratories
Bogot, Colombia

OCCIDENTAL DE COLOMBIA
Caricare-3
Well, Form.: C5
RFL 06089
___________________________________________________________________________________________

Summary of Samples Received


Bottomhole Samples

Sampling :Pressure
Temp.
(psig)
(F)

Laboratory
Bubble point :Pressure
Temp.
(psig)
(F)

Sample
Number

Cylinder
Number

1.1

818424

1755

90

1.2

818438

1755

88

Free water
drained
(cc)

Sample
Volume
(cm3)

72

530

72

390

Note:
Sample No.1.2 selected for compositional and further PVT analyses.

___________________________________________________________________________________________
B.2
Core Laboratories
Bogot, Colombia

OCCIDENTAL DE COLOMBIA
Caricare-3
Well, Form.: C5
RFL 06089
___________________________________________________________________________________________

Section C - Compositional Analysis of Bottomhole Fluid Sample to C36+

___________________________________________________________________________________________
Core Laboratories
Bogot, Colombia

OCCIDENTAL DE COLOMBIA
Caricare-3
Well, Form.: C5
RFL 06089
___________________________________________________________________________________________
Compositional Analysis of Bottomhole Sample to C36 plus
Component
Hydrogen
Hydrogen Sulphide
Carbon Dioxide
Nitrogen
Methane
Ethane
Propane
i-Butane
n-Butane
Neo-Pentane
i-Pentane
n-Pentane
Hexanes
Methyl-Cyclopentane
Benzene
Cyclohexane
C7
Heptanes
Methyl-Cyclohexane
Toluene
C8
Octanes
EthylBenzene
M/P-Xylene
O-Xylene
C9
Nonanes
TrimethylBenzene
C10 Decanes
C11 Undecanes
C12 Dodecanes
C13 Tridecanes
C14 Tetradecanes
C15 Pentadecanes
C16 Hexadecanes
C17 Heptadecanes
C18 Octadecanes
C19 Nonadecanes
C20 Eicosanes
C21 Heneicosanes
C22 Docosanes
C23 Tricosanes
C24 Tetracosanes
C25 Pentacosanes
C26 Hexacosanes
C27 Heptacosanes
C28 Octacosanes
C29 Nonacosanes
C30 Triacontanes
C31 Hentriacontanes
C32 Dotriacontanes
C33 Tritriacontanes
C34 Tetratriacontanes
C35 Pentatriacontanes
C36+ Hexatriacontanes +
H2
H2S
CO2
N2
C1
C2
C3
iC4
nC4
C5
iC5
nC5
C6

Totals :

Mole %
0.00
0.00
0.37
0.02
1.90
0.04
0.04
0.14
0.45
0.00
0.75
1.30
3.42
1.02
0.00
0.43
4.92
2.02
0.55
6.35
0.65
0.36
0.27
5.68
0.70
5.92
5.54
4.94
5.58
4.49
4.28
3.40
3.12
3.19
2.91
2.23
2.17
1.89
1.77
1.50
1.47
1.17
1.08
0.97
0.89
0.79
0.73
0.60
0.55
0.52
0.51
6.41
_____

Weight %
0.00
0.00
0.07
0.00
0.13
0.00
0.01
0.03
0.11
0.00
0.22
0.39
1.22
0.36
0.00
0.15
2.05
0.83
0.21
3.02
0.29
0.16
0.12
3.03
0.35
3.50
3.38
3.31
4.06
3.54
3.66
3.14
3.08
3.34
3.19
2.55
2.63
2.40
2.34
2.07
2.11
1.74
1.68
1.56
1.49
1.37
1.30
1.12
1.06
1.03
1.03
25.57
_____

100.00

100.00

Note: 0.00 means less than 0.005.


___________________________________________________________________________________________
C.1
Core Laboratories
Bogot, Colombia

OCCIDENTAL DE COLOMBIA
Caricare-3
Well, Form.: C5
RFL 06089
___________________________________________________________________________________________
Compositional Analysis of Bottomhole Sample to C36 plus

Calculated Residue Properties


C7 plus

Mole %
Mole Weight (g mol-1)
Density at 60F (g cm-3)

91.57
257
0.8844

C11 plus

Mole %
Mole Weight (g mol-1)
Density at 60F (g cm-3)

62.70
321
0.9169

C20 plus

Mole %
Mole Weight (g mol-1)
Density at 60F (g cm-3)

25.25
505
0.9790

C36 plus

Mole %
Molecular Weight (g mol-1)
Density at 60F (g cm-3)

6.41
960
1.1018

Calculated Whole Sample Properties


Average mole weight (g mol-1)
Density at 60F (g cm-3)

240
0.8756

___________________________________________________________________________________________
C.2
Core Laboratories
Bogot, Colombia

OCCIDENTAL DE COLOMBIA
Caricare-3
Well, Form.: C5
RFL 06089
___________________________________________________________________________________________

Section D - Constant Composition Expansion (CCE)

___________________________________________________________________________________________
Core Laboratories
Bogot, Colombia

OCCIDENTAL DE COLOMBIA
Caricare-3
Well, Form.: C5
RFL 06089
___________________________________________________________________________________________

Constant Composition Expansion at 198F


Single-phase Fluid Properties
Saturation pressure (bubble-point pressure)

104 psig

Thermal expansion factor of single phase fluid at 5000 psig


(Vol at 198F)/(Vol at 60F)
Average single phase compressibility
(From 2526 psig to 104 psig)

1.0320 vol / vol

7.00 x 10 -6 psi-1

Density at saturation pressure

0.8214 g cm-3

Mean Single-phase Compressibilities


Pressure Range
Initial Pressure
(psig)

Final Pressure
(psig)

Mean
Compressibility
(psi-1) (1)

5000

4000

4.63

x 10 -6

4000

2526

5.35

x 10 -6

2526

1000

6.51

x 10 -6

1000

104

7.84

x 10 -6

(1) Mean compressibility = (V2-V1) / [(V1+V2)/2] x 1/(P1 - P2)

___________________________________________________________________________________________
D.1
Core Laboratories
Bogot, Colombia

OCCIDENTAL DE COLOMBIA
Caricare-3
Well, Form.: C5
RFL 06089
___________________________________________________________________________________________

Constant Composition Expansion at 198F


Pressure
(psig)

Relative
Volume (1)

Density
(g cm-3)

5000
4000
3000
2526
2000
1500
1000
900
800
700
600
500
400
300
200
104
103
102
97
92
82
68
55
42
36
25

0.9710
0.9755
0.9805
0.9832
0.9863
0.9895
0.9930
0.9937
0.9945
0.9952
0.9960
0.9968
0.9976
0.9984
0.9992
1.0000
1.0023
1.0047
1.0178
1.0330
1.0723
1.1578
1.2980
1.5727
1.7993
2.6624

0.8460
0.8421
0.8377
0.8355
0.8328
0.8301
0.8272
0.8266
0.8260
0.8253
0.8247
0.8241
0.8234
0.8227
0.8221
0.8214

Reservoir pressure

Saturation pressure

Instantaneous
Compressibility
(psi-1 x 10-6) (2)

Y-Function (3)

4.64
5.20
5.69
6.06
6.51
7.03
7.39
7.50
7.61
7.72
7.84
7.94
8.09
8.18
8.35

3.406
3.148
2.759
2.359
1.909
1.678
1.197

(1) Relative Volume = V / Vsat ie. volume at indicated pressure per volume at saturation pressure.
(2) Instantaneous compressibility = (V2-V1) / V1 x 1/(P1-P2)
'(3) Y-function = (Psat - P ) / ((Pabs)(V/Vsat - 1)).

___________________________________________________________________________________________
D.2
Core Laboratories
Bogot, Colombia

OCCIDENTAL DE COLOMBIA
Caricare-3
Well, Form.: C5
RFL 06089
___________________________________________________________________________________________

Graphs of Constant Composition Expansion Data


Relative Volume vs Pressure

Relative Volume, V/Vsat

1.0000

0.9900

0.9800

0.9700

0.9600
0

1000

2000

3000

4000

5000

Pressure, psig

Y Function vs Pressure

4.000

Y Function

3.000

2.000

1.000
0

40

80

120

160

Pressure, psig

___________________________________________________________________________________________
D.3
Core Laboratories
Bogot, Colombia

OCCIDENTAL DE COLOMBIA
Caricare-3
Well, Form.: C5
RFL 06089
___________________________________________________________________________________________

Constant Composition Expansion at 120F


Single-phase Fluid Properties
Saturation pressure (bubble-point pressure)

83 psig

Thermal expansion factor of single phase fluid at 5000 lpcm


(Vol at 120F)/(Vol at 60F)

1.0043 vol / vol

Average single phase compressibility


(From 2526 psig to 83 psig)

4.88

x 10 -6 lpc-1

Mean Single-phase Compressibilities


Pressure Range
Initial Pressure
(psig)

Final Pressure
(psig)

Mean
Compressibility
(psi-1) (1)

5000

4000

3.42

x 10 -6

4000

2526

3.88

x 10 -6

2526

1000

4.58

x 10 -6

1000

83

5.38

x 10 -6

(1) Mean compressibility = (V2-V1) / [(V1+V2)/2] x 1/(P1 - P2)

___________________________________________________________________________________________
D.4
Core Laboratories
Bogot, Colombia

OCCIDENTAL DE COLOMBIA
Caricare-3
Well, Form.: C5
RFL 06089
___________________________________________________________________________________________

Constant Composition Expansion at 120F


Pressure
(psig)

Relative
Volume (1)

5000
4000
3000
2526
2000
1500
1000
500
400
300
200
100
83

0.9792
0.9825
0.9862
0.9881
0.9904
0.9926
0.9951
0.9977
0.9982
0.9988
0.9993
0.9999
1.0000

Reservoir pressure

Saturation pressure

Instantaneous
Compressibility
(psi-1 x 10-6) (2)

3.43
3.79
4.09
4.31
4.58
4.90
5.25
5.41
5.50
5.53
5.67
5.88

Graph of Constant Composition Expansion Data


Relative Volume vs Pressure

1.0000

Relative Volume, V/Vsat

0.9950

0.9900

0.9850

0.9800

0.9750
0

1000

2000

3000

4000

5000

Pressure, psig

(1) Relative Volume = V / Vsat ie. volume at indicated pressure per volume at saturation pressure.
(2) Instantaneous compressibility = (V2-V1) / V1 x 1/(P1-P2)
___________________________________________________________________________________________
D.5
Core Laboratories
Bogot, Colombia

OCCIDENTAL DE COLOMBIA
Caricare-3
Well, Form.: C5
RFL 06089
___________________________________________________________________________________________

Constant Composition Expansion at 86F


Single-phase Fluid Properties
Saturation pressure (bubble-point pressure)

72 psig

Thermal expansion factor of single phase fluid at 5000 lpcm


(Vol at 86F)/(Vol at 60F)

1.0014 vol / vol

Average single phase compressibility


(From 2526 psig to 72 psig)

4.16

x 10 -6 lpc-1

Mean Single-phase Compressibilities


Pressure Range
Initial Pressure
(psig)

Final Pressure
(psig)

Mean
Compressibility
(psi-1) (1)

5000

4000

2.99

x 10 -6

4000

2526

3.36

x 10 -6

2526

1000

3.92

x 10 -6

1000

72

4.55

x 10 -6

(1) Mean compressibility = (V2-V1) / [(V1+V2)/2] x 1/(P1 - P2)

___________________________________________________________________________________________
D.6
Core Laboratories
Bogot, Colombia

OCCIDENTAL DE COLOMBIA
Caricare-3
Well, Form.: C5
RFL 06089
___________________________________________________________________________________________

Constant Composition Expansion at 86F


Pressure
(psig)

Relative
Volume (1)

5000
4000
3000
2526
2000
1500
1000
500
400
300
200
100
72

0.9820
0.9850
0.9882
0.9898
0.9918
0.9937
0.9958
0.9980
0.9985
0.9989
0.9994
0.9999
1.0000

Reservoir pressure

Saturation pressure

Instantaneous
Compressibility
(psi-1 x 10-6) (2)

2.99
3.28
3.53
3.70
3.91
4.17
4.45
4.57
4.64
4.66
4.75
4.80

Graph of Constant Composition Expansion Data


Relative Volume vs Pressure

Relative Volume, V/Vsat

1.0000

0.9950

0.9900

0.9850

0.9800
0

1000

2000

3000

4000

5000

Pressure, psig

(1) Relative Volume = V / Vsat ie. volume at indicated pressure per volume at saturation pressure.
(2) Instantaneous compressibility = (V2-V1) / V1 x 1/(P1-P2)
___________________________________________________________________________________________
D.7
Core Laboratories
Bogot, Colombia

OCCIDENTAL DE COLOMBIA
Caricare-3
Well, Form.: C5
RFL 06089
___________________________________________________________________________________________

Constant Composition Expansion at 68F


Single-phase Fluid Properties
Saturation pressure (bubble-point pressure)

66 psig

Thermal expansion factor of single phase fluid at 5000 lpcm


(Vol at 68F)/(Vol at 60F)

1.0000 vol / vol

Average single phase compressibility


(From 2526 psig to 66 psig)

3.82

x 10 -6 lpc-1

Mean Single-phase Compressibilities


Pressure Range
Initial Pressure
(psig)

Final Pressure
(psig)

Mean
Compressibility
(psi-1) (1)

5000

4000

2.78

x 10 -6

4000

2526

3.11

x 10 -6

2526

1000

3.61

x 10 -6

1000

66

4.16

x 10 -6

(1) Mean compressibility = (V2-V1) / [(V1+V2)/2] x 1/(P1 - P2)

___________________________________________________________________________________________
D.8
Core Laboratories
Bogot, Colombia

OCCIDENTAL DE COLOMBIA
Caricare-3
Well, Form.: C5
RFL 06089
___________________________________________________________________________________________

Constant Composition Expansion at 68F


Pressure
(psig)

Relative
Volume (1)

5000
4000
3000
2526
2000
1500
1000
500
400
300
200
100
66

0.9834
0.9861
0.9891
0.9907
0.9924
0.9942
0.9961
0.9982
0.9986
0.9990
0.9994
0.9999
1.0000

Reservoir pressure

Saturation pressure

Instantaneous
Compressibility
(psi-1 x 10-6) (2)

2.78
3.04
3.26
3.41
3.60
3.83
4.08
4.17
4.24
4.25
4.33
4.35

Graph of Constant Composition Expansion Data


Relative Volume vs Pressure

Relative Volume, V/Vsat

1.0000

0.9950

0.9900

0.9850

0.9800
0

1000

2000

3000

4000

5000

Pressure, psig

(1) Relative Volume = V / Vsat ie. volume at indicated pressure per volume at saturation pressure.
(2) Instantaneous compressibility = (V2-V1) / V1 x 1/(P1-P2)
___________________________________________________________________________________________
D.9
Core Laboratories
Bogot, Colombia

OCCIDENTAL DE COLOMBIA
Caricare-3
Well, Form.: C5
RFL 06089
___________________________________________________________________________________________

Section E - Differential Vaporization (DV)

___________________________________________________________________________________________
Core Laboratories
Bogot, Colombia

OCCIDENTAL DE COLOMBIA
Caricare-3
Well, Form.: C5
RFL 06089
___________________________________________________________________________________________

Differential Vaporization at 198F

Pressure
(psig)

Solution
Gas-Oil
Ratio
Rs(1)

Relative
Oil
Volume
Bod(2)

Relative
Total
Volume
Btd(3)

104
40
0

19
8
0

1.075
1.071
1.066

1.075
1.738

At 60F =

Density
(g cm-3)

Deviation
Factor
(Z)

0.8214
0.8229
0.8248

0.998

Gas
Formation
Volume
Factor (4)

Incremental
Gas
Gravity
(Air = 1.000)

Saturation Pressure
0.33932
0.891
1.200

1.000

Residual Oil Properties


Density of residual oil

0.8791

API

29.3

g cm-3 at 60F

(1) GOR in cubic feet of gas at 14.70 psia and 60F per barrel of residual oil at 60F.
(2) Volume of oil at indicated pressure and temperature per volume of residual oil at 60F.
(3) Volume of oil plus liberated gas at indicated pressure and temperature per volume of residual oil at 60F.
(4) Volume of gas at indicated pressure and temperature per volume at 14.70 psia and 60F.

___________________________________________________________________________________________
E.1
Core Laboratories
Bogot, Colombia

OCCIDENTAL DE COLOMBIA
Caricare-3
Well, Form.: C5
RFL 06089
___________________________________________________________________________________________

Graphs of Differential Vaporization


Solution Gas-Oil Ratio v Pressure

Gas-Oil Ratio, scf/res.bbl

20

15

10

0
0

40

80

120

160

Pressure, psig

Relative Oil Volume v Pressure

Relative Oil Volume, V/Vr

1.080

1.075

1.070

1.065

1.060
0

40

80

120

160

Pressure, psig

___________________________________________________________________________________________
E.2
Core Laboratories
Bogot, Colombia

OCCIDENTAL DE COLOMBIA
Caricare-3
Well, Form.: C5
RFL 06089
___________________________________________________________________________________________

Differential Vaporization Data Converted to Production Separator Conditions

Pressure
(psig)

Oil
Density
(g cm-3)

5000
4000
3000
2526
2000
1500
1000
500
104
40
0

0.8460
0.8421
0.8377
0.8355
0.8328
0.8301
0.8272
0.8241
0.8214
0.8229
0.8248

Reservoir pressure

Saturation pressure

Solution
Gas/Oil
(scf / bbl)
Rs(1)

Formation
Volume
Factor
Bo(1)

20
9
1

1.045
1.050
1.055
1.058
1.062
1.065
1.069
1.073
1.076
1.072
1.056

Gas Formation
Volume
Factor
Bg(2)

0.33932

Notes:
(1) Differential data corrected to surface separator conditions of :Stage 1
Stage 2

60 psig and 200F


0 psig and 200F

Rs = Rsfb - (Rsdb - Rsd) x (Bofb / Bodb)


Bo = Bod x (Bofb/Bodb)
(2) Volume of gas at indicated pressure and temperature per volume at 14.7 psia and 60F.

___________________________________________________________________________________________
E.3
Core Laboratories
Bogot, Colombia

OCCIDENTAL DE COLOMBIA
Caricare-3
Well, Form.: C5
RFL 06089
___________________________________________________________________________________________

Differential Vaporization Data Converted to Production Separator Conditions

Pressure
(psig)

Oil
Density
(g cm-3)

5000
4000
3000
2526
2000
1500
1000
500
104
40

0.8460
0.8421
0.8377
0.8355
0.8328
0.8301
0.8272
0.8241
0.8214
0.8229

Reservoir pressure

Saturation pressure

Solution
Gas/Oil
(scf / bbl)
Rs(1)

Formation
Volume
Factor
Bo(1)

Gas Formation
Volume
Factor
Bg(2)

19
8

1.044
1.049
1.054
1.057
1.061
1.064
1.068
1.072
1.075
1.071

0.33932

Notes:
(1) Differential data corrected to surface separator conditions of :Stage 1
Stage 2

30 psig and 200F


0 psig and 200F

Rs = Rsfb - (Rsdb - Rsd) x (Bofb / Bodb)


Bo = Bod x (Bofb/Bodb)
(2) Volume of gas at indicated pressure and temperature per volume at 14.7 psia and 60F.

___________________________________________________________________________________________
E.4
Core Laboratories
Bogot, Colombia

OCCIDENTAL DE COLOMBIA
Caricare-3
Well, Form.: C5
RFL 06089
___________________________________________________________________________________________

Section F - Bottomhole Fluid Viscosity Data

___________________________________________________________________________________________
Core Laboratories
Bogot, Colombia

OCCIDENTAL DE COLOMBIA
Caricare-3
Well, Form.: C5
RFL 06089
___________________________________________________________________________________________

Bottomhole Fluid Viscosity Data at 198F


Pressure
(psig)

Oil
Viscosity
(cP)

5000
4000
3000
2526
2000
1000
300
104
40
0

4.813
4.438
4.063
3.885
3.688
3.313
3.051
2.977
3.231
4.290

Reservoir pressure

Saturation pressure

Calculated
Gas Viscosity
(cP) (1)

Oil/Gas
Viscosity
Ratio

0.0122

266

(1) Calculated using the method of Lee, Gonzales and Eakin, JPT, Aug 1966.

___________________________________________________________________________________________
F.1
Core Laboratories
Bogot, Colombia

OCCIDENTAL DE COLOMBIA
Caricare-3
Well, Form.: C5
RFL 06089
___________________________________________________________________________________________

Graph of Bottomhole Fluid Viscosity Data at 198F


Oil Viscosity Vs Pressure

Oil viscosity, cPs

5.000

4.000

3.000

2.000
0

40

80

120

160

Pressurre, psig

Single-phase Fluid Viscosity Vs Pressure

Single-phase Viscosity, cPs

5.000

4.000

3.000

2.000
0

1000

2000

3000

4000

5000

Pressurre, psig

___________________________________________________________________________________________
F.2
Core Laboratories
Bogot, Colombia

OCCIDENTAL DE COLOMBIA
Caricare-3
Well, Form.: C5
RFL 06089
___________________________________________________________________________________________

Section G - Separator Test Data

___________________________________________________________________________________________
Core Laboratories
Bogot, Colombia

OCCIDENTAL DE COLOMBIA
Caricare-3
Well, Form.: C5
RFL 06089
___________________________________________________________________________________________

Data from Separator Test 1

Pressure
(psig)

Temperature
(F)

Gas-Oil
Ratio

Oil
Density
(g cm-3)

(1)

Gas-Oil
Ratio
Rsfb
(2)

Formation
Volume
Factor
Bofb (3)

Separation Gas Gravity


Volume
of flashed gas
Factor
(Air = 1.000)
(4)

1.076

Saturation Pressure

104

198

20

0.8214

60
0

200
200

6
13

6
14

0.8219
0.8229

1.074
1.067

0.868 *
1.575

Residual Oil Properties


Density of residual oil

0.8782

API

29.5

g cm-3 at 60F

Note :
*

Evolved gas collected and analysed to C11+.

(1) GOR in cubic feet of gas at 14.70 psia and 60F per barrel of oil at indicated pressure and temperature.
(2) GOR in cubic feet of gas at 14.70 psia and 60F per barrel of stocktank oil at 60F.
(3) Volume of saturated oil at 104 psig and 198F per volume of stocktank oil at 60F.
(4) Volume of oil at indicated pressure and temperature per volume of stocktank oil at 60F.

___________________________________________________________________________________________
G.1
Core Laboratories
Bogot, Colombia

OCCIDENTAL DE COLOMBIA
Caricare-3
Well, Form.: C5
RFL 06089
___________________________________________________________________________________________

Compositional Analysis of Separator Test Gas to C11+


Sampling Date
Sample Description
Cylinder Number
Sampling Conditions

H2
H2S
CO2
N2
C1
C2
C3
iC4
nC4
iC5
nC5
C6
C7
C8
C9
C10
C11+

Component
Hydrogen
Hydrogen Sulphide
Carbon Dioxide
Nitrogen
Methane
Ethane
Propane
i-Butane
n-Butane
i-Pentane
n-Pentane
Hexanes
Heptanes
Octanes
Nonanes
Decanes
Undecanes plus
Totals :

02-Aug-2006
Gas from first stage separation
-60.0 psig @ 200.0F
Mole %
0.00
0.00
3.33
0.90
83.07
1.47
0.32
1.19
1.41
1.25
0.79
1.84
2.00
1.48
0.58
0.33
0.04
______
100.00

Weight %
0.00
0.00
5.84
1.00
53.01
1.76
0.56
2.76
3.27
3.59
2.28
6.29
7.98
6.72
2.94
1.74
0.26
______
100.00

Mole Weight
(g mol-1)
111.5
120.8
135.6
147.0

Density
(g cm-3 @ 60F )
0.7074
0.7217
0.7794
0.7890

Note: 0.00 means less than 0.005.

Calculated Residue Properties


C7+
C8+
C10+
C11+

Heptanes plus
Octanes plus
Decanes plus
Undecanes plus
Calculated Whole Gas Properties
Real Relative Density
Whole Sample Mole Weight
Real Gas Density
Ideal Gross Calorific Value
Ideal Net Calorific Value
Pseudo Critical Press.
Pseudo Critical Temp.
Gas Compressibility Factor, Z
Gas Viscosity
GPM (C2+)
GPM (C3+)

0.8730
25.14
1.0705
1402.0
1276.4
654.9
413.7
0.9943
0.012
4.980
4.589

(Air=1 @ 14.73 psia & 60F)


g mol-1
kg m-3 @ 15C
BTU.ft-3 @ 14.73psia, 60F
BTU.ft-3 @ 14.73psia, 60F
psia
Rankine
@ 14.73 psia & 60F
cP

___________________________________________________________________________________________
G.2
Core Laboratories
Bogot, Colombia

OCCIDENTAL DE COLOMBIA
Caricare-3
Well, Form.: C5
RFL 06089
___________________________________________________________________________________________

Data from Separator Test 2

Pressure
(psig)

Temperature
(F)

Gas-Oil
Ratio

Oil
Density
(g cm-3)

(1)

Gas-Oil
Ratio
Rsfb
(2)

Formation
Volume
Factor
Bofb (3)

Separation Gas Gravity


Volume
of flashed gas
Factor
(Air = 1.000)
(4)

1.075

Saturation Pressure

104

198

19

0.8214

30
0

200
200

10
7

11
8

0.8218
0.8223

1.071
1.067

1.031 *
1.652

Residual Oil Properties


Density of residual oil

0.8776

API

29.6

g cm-3 at 60F

Note :
*

Evolved gas collected and analysed to C11+.

(1) GOR in cubic feet of gas at 14.70 psia and 60F per barrel of oil at indicated pressure and temperature.
(2) GOR in cubic feet of gas at 14.70 psia and 60F per barrel of stocktank oil at 60F.
(3) Volume of saturated oil at 104 psig and 198F per volume of stocktank oil at 60F.
(4) Volume of oil at indicated pressure and temperature per volume of stocktank oil at 60F.

___________________________________________________________________________________________
G.3
Core Laboratories
Bogot, Colombia

OCCIDENTAL DE COLOMBIA
Caricare-3
Well, Form.: C5
RFL 06089
___________________________________________________________________________________________

Compositional Analysis of Separator Test Gas to C11+


Sampling Date
Sample Description
Cylinder Number
Sampling Conditions

H2
H2S
CO2
N2
C1
C2
C3
iC4
nC4
iC5
nC5
C6
C7
C8
C9
C10
C11+

Component
Hydrogen
Hydrogen Sulphide
Carbon Dioxide
Nitrogen
Methane
Ethane
Propane
i-Butane
n-Butane
i-Pentane
n-Pentane
Hexanes
Heptanes
Octanes
Nonanes
Decanes
Undecanes plus
Totals :

02-Aug-2006
Gas from first stage separation
-30.0 psig @ 200.0F
Mole %
0.00
0.00
4.49
0.41
73.00
3.76
2.29
1.47
2.10
1.85
1.66
2.80
2.73
2.01
0.78
0.56
0.09
______
100.00

Weight %
0.00
0.00
6.62
0.39
39.21
3.78
3.38
2.86
4.09
4.48
4.00
8.08
9.15
7.68
3.35
2.50
0.43
______
100.00

Mole Weight
(g mol-1)
112.1
121.5
135.8
147.0

Density
(g cm-3 @ 60F )
0.7092
0.7242
0.7796
0.7890

Note: 0.00 means less than 0.005.

Calculated Residue Properties


C7+
C8+
C10+
C11+

Heptanes plus
Octanes plus
Decanes plus
Undecanes plus
Calculated Whole Gas Properties
Real Relative Density
Whole Sample Mole Weight
Real Gas Density
Ideal Gross Calorific Value
Ideal Net Calorific Value
Pseudo Critical Press.
Pseudo Critical Temp.
Gas Compressibility Factor, Z
Gas Viscosity
GPM (C2+)
GPM (C3+)

1.0402
29.87
1.2762
1635.5
1494.4
649.1
456.2
0.9915
0.012
8.206
7.205

(Air=1 @ 14.73 psia & 60F)


g mol-1
kg m-3 @ 15C
BTU.ft-3 @ 14.73psia, 60F
BTU.ft-3 @ 14.73psia, 60F
psia
Rankine
@ 14.73 psia & 60F
cP

___________________________________________________________________________________________
G.4
Core Laboratories
Bogot, Colombia

OCCIDENTAL DE COLOMBIA
Caricare-3
Well, Form.: C5
RFL 06089
___________________________________________________________________________________________

Section H - Appendix

___________________________________________________________________________________________
Core Laboratories
Bogot, Colombia

OCCIDENTAL DE COLOMBIA
Caricare-3
Well, Form.: C5
RFL 06089
___________________________________________________________________________________________

Data Used in Gas Compositional Calculations


Component

Hydrogen
Oxygen/(Argon)
Nitrogen (Corrected)
Methane
Carbon Dioxide
Ethane
Hydrogen Sulphide
Propane
i-Butane
n-Butane
Neo-Pentane
i-Pentane
n-Pentane
22DMC4
23DMC4/CYC5
2MC5
3MC5
Hexanes (nC6)
22DMC5
M-C-Pentane
24DMC5
223TMC4
Benzene

Mole Weight
Density
Component
(g mol-1) (g cm-3 at 60F)
*
**
**
**
**
**
**
**
**
**
*
**
**
*
*
*
*
*
*
*
*
*
*

2.016
31.999
28.013
16.043
44.010
30.070
34.080
44.097
58.123
58.123
72.15
72.150
72.150
86.18
78.16
86.18
86.18
86.18
100.20
84.16
100.20
100.20
78.11

N/A
1.1410
0.8086
0.2997
0.8172
0.3558
0.8006
0.5065
0.5623
0.5834
0.5968
0.6238
0.6305
0.6529
0.7129
0.6572
0.6682
0.6631
0.6814
0.7533
0.6757
0.6947
0.8820

33DMC5
Cyclohexane
2MC6/23DMC5
11DMCYC5/3MC6
t13DMCYC5
c13DMCYC5/3EC5
t12DMCYC5
Heptanes (nC7)
22DMC6
MCYC6
ECYC5
223TMC5/24&25DMC6
ctc124TMCYC5
ctc123TMCYC5
Toluene
Octanes (nC8)
E-Benzene
M/P-Xylene
O-Xylene
Nonanes (nC9)
Decanes
Undecanes
Dodecanes

Mole Weight
Density
(g mol-1) (g cm-3 at 60F)
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
***
***
***

100.20
84.16
100.20
99.20
98.19
99.20
98.19
100.20
114.23
98.19
98.19
114.23
112.21
112.21
92.14
114.23
106.17
106.17
106.17
128.26
134
147
161

0.6954
0.7827
0.6917
0.7253
0.7528
0.7262
0.7554
0.6875
0.6994
0.7740
0.7704
0.7060
0.7511
0.7574
0.8734
0.7063
0.8735
0.8671
0.8840
0.7212
0.778
0.789
0.800

Data Source Refs :


* ASTM Data Series Publication DS 4B (1991) - Physical Constants of Hydrocarbon and Non-Hydrocarbon
Compounds.
** GPA Table of Physical Constants of Paraffin Hydrocarbons and Other Components of Natural Gas,
GPA 2145-96.
*** Journal of Petroleum Technology, Nov 1978, Pages 1649-1655.
Predicting Phase Behaviour of Condensate/Crude Oil Systems Using Methane Interaction Coefficients
- D.L. Katz & A. Firoozabadi.

Note :
The gas mole % compositions were calculated from the measured weight % compositions using
the most detailed analysis results, involving as many of the above components as were identified.
The reported component mole % compositions were then sub-grouped into the generic carbon
number components.

___________________________________________________________________________________________
H.1
Core Laboratories
Bogot, Colombia

OCCIDENTAL DE COLOMBIA
Caricare-3
Well, Form.: C5
RFL 06089
___________________________________________________________________________________________

Data Used in Oil Compositional Calculations


Component

Hydrogen
Hyd. sulphide
Carbon Dioxide
Nitrogen
Methane
Ethane
Propane
i-Butane
n-Butane
i-Pentane
n-Pentane
Hexanes
Me-cyclo-pentane
Benzene
Cyclo-hexane
Heptanes
Me-cyclo-hexane
Toluene
Octanes
Ethyl-benzene
Meta/Para-xylene
Ortho-xylene
Nonanes
1-2-4-T-M-benzene
Decanes

Mole Weight
Density
Component
(g mol-1) (g cm-3 at 60F)
*
**
**
**
**
**
**
**
**
**
**
**
*
*
*
**
*
*
**
*
*
*
**
*
**

2.016
34.080
44.010
28.013
16.043
30.070
44.097
58.123
58.123
72.150
72.150
86.177
84.16
78.11
84.16
100.204
98.19
92.14
114.231
106.17
106.17
106.17
128.258
120.19
142.285

N/A
0.8006
0.8172
0.8086
0.2997
0.3558
0.5065
0.5623
0.5834
0.6238
0.6305
0.6634
0.7533
0.8820
0.7827
0.6874
0.7740
0.8734
0.7061
0.8735
0.8671
0.8840
0.7212
0.8797
0.7334

Undecanes
Dodecanes
Tridecanes
Tetradecanes
Pentadecanes
Hexadecanes
Heptadecanes
Octadecanes
Nonadecanes
Eicosanes
Heneicosanes
Docosanes
Tricosanes
Tetracosanes
Pentacosanes
Hexacosanes
Heptacosanes
Octacosanes
Nonacosanes
Triacontanes
Hentriacontanes
Dotriacontanes
Tritriacontanes
Tetratriacontanes
Pentatriacontanes

Mole Weight
Density
(g mol-1) (g cm-3 at 60F)
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***

147
161
175
190
206
222
237
251
263
275
291
305
318
331
345
359
374
388
402
416
430
444
458
472
486

0.789
0.800
0.811
0.822
0.832
0.839
0.847
0.852
0.857
0.862
0.867
0.872
0.877
0.881
0.885
0.889
0.893
0.896
0.899
0.902
0.906
0.909
0.912
0.914
0.917

Data Source Refs :


* ASTM Data Series Publication DS 4B (1991) - Physical Constants of Hydrocarbon and Non-Hydrocarbon
Compounds.
** GPA Table of Physical Constants of Paraffin Hydrocarbons and Other Components of Natural Gas
GPA 2145-96.
*** Journal of Petroleum Technology, Nov 1978, Pages 1649-1655.
Predicting Phase Behaviour of Condensate/Crude Oil Systems Using Methane Interaction Coefficients
- D.L. Katz & A. Firoozabadi.

Note :
The residue mole weight and density values ( eg heptanes plus, undecanes plus, eicosanes plus)
are calculated so that the calculated average mole weights and densities correspond with the
measured values. This can lead to anomalous residue mole weights and densities where the Katz
and Firoozabadi values may not be suitable for the isomer groups detected.
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H.2
Core Laboratories
Bogot, Colombia

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