Metanol - Agua

Estado Liquido
C1
105800
276370

C2
-362.23
-2090.1

C3
0.9379
8.125

C4
0
-0.014116

C5
0
9.3701E-06

Metanol
Agua

C1
52390000
52053000

C2
0.3682
0.3199

C3
0
-0.212

C4
0
0.25795

C5
0
0

T (C)
100
96.4
93.5
91.2
89.3
87.7
84.4
81.7
78
75.3
73.1
71.2
69.3
67.6
66
65
64.5

T (K)
373.15
369.55
366.65
364.35
362.45
360.85
357.55
354.85
351.15
348.45
346.25
344.35
342.45
340.75
339.15
338.15
337.65

XA
0
0.02
0.04
0.06
0.08
0.1
0.15
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
0.95
1

YA
0
0.134
0.23
0.304
0.365
0.418
0.517
0.579
0.665
0.729
0.779
0.825
0.87
0.91
0.958
0.979
1

XA
1.00
0.95
0.90
0.85
0.80
0.75
0.70
0.65
0.60
0.55

KJ/mol A
0
-0.071
-0.151
-0.251
-0.356
-0.473
-0.594
-0.724
-0.866
-1.013

Metanol
Agua
Estado Vapor

PARA Hs
T 0=
A = CH4OH

100
95

90
85
80
75
70
65
60

0.2

42.37

B = H2 O
%molB
0
5
10
15
20
25
30
35
40
45

%molA
100
95
90
85
80
75
70
65
60
55

KJ/mol mez
0
-0.06745
-0.1359
-0.21335
-0.2848
-0.35475
-0.4158
-0.4706
-0.5196
-0.55715

KJ/Kmol mez
0.00
-67.45
-135.90
-213.35
-284.80
-354.75
-415.80
-470.60
-519.60
-557.15

50
55
60
65
70
75
80
85
90
95
100

50
45
40
35
30
25
20
15
10
5
0

0.50
0.45
0.40
0.35
0.30
0.25
0.20
0.15
0.10
0.05
0.00

-1.193
-1.402
-1.632
-1.908
-2.264
-2.691
-3.185
-3.725
-4.352
-4.997
0

-0.5965
-0.6309
-0.6528
-0.6678
-0.6792
-0.67275
-0.637
-0.55875
-0.4352
-0.24985
0

-596.50
-630.90
-652.80
-667.80
-679.20
-672.75
-637.00
-558.75
-435.20
-249.85
0.00

T(prom)
344.335
342.535
341.085
339.935
338.985
338.185
336.535
335.185
333.335
331.985
330.885
329.935
328.985
328.135
327.335
326.835
326.585

XA
0
0.02
0.04
0.06
0.08
0.1
0.15
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
0.95
1

CLA.MWA
92.27514
91.76757
91.36311
91.04513
90.78433
90.56602
90.11955
89.75805
89.26822
88.91482
88.62940
88.38472
88.14174
87.92577
87.72374
87.59808
87.53543

CLB.MWB
75.44551
75.42013
75.40069
75.38594
75.37420
75.36464
75.34586
75.33148
75.31323
75.30101
75.29176
75.28430
75.27732
75.27151
75.26641
75.26341
75.26196

A = CH4OH

Tc A (K)=
TC B (K)=

512.64
647.13

CLA.MWA
92.27514
91.76757
91.36311
91.04513
90.78433
90.56602
90.11955

CLB.MWB
75.44551
75.42013
75.40069
75.38594
75.37420
75.36464
75.34586

Para HL
T0(C)=
T0(K)=

42.37
315.52

T (C)
100
96.4
93.5
91.2
89.3
87.7
84.4
81.7
78
75.3
73.1
71.2
69.3
67.6
66
65
64.5

T (K)
373.15
369.55
366.65
364.35
362.45
360.85
357.55
354.85
351.15
348.45
346.25
344.35
342.45
340.75
339.15
338.15
337.65

Para Hv
T0(C)=
T0(K)=

42.37
315.52

T (C)
100
96.4
93.5
91.2
89.3
87.7
84.4

T (K)
373.15
369.55
366.65
364.35
362.45
360.85
357.55

B = H2 O
T(prom)
344.335
342.535
341.085
339.935
338.985
338.185
336.535

YA
0
0.134
0.23
0.304
0.365
0.418
0.517

81.7
78
75.3
73.1
71.2
69.3
67.6
66
65
64.5

354.85
351.15
348.45
346.25
344.35
342.45
340.75
339.15
338.15
337.65

335.185
333.335
331.985
330.885
329.935
328.985
328.135
327.335
326.835
326.585

0.579
0.665
0.729
0.779
0.825
0.87
0.91
0.958
0.979
1

89.75805
89.26822
88.91482
88.62940
88.38472
88.14174
87.92577
87.72374
87.59808
87.53543

75.33148
75.31323
75.30101
75.29176
75.28430
75.27732
75.27151
75.26641
75.26341
75.26196

Tc (K)
512.64
647.13

T VS X,Y

liquido
Vapor

0.2

0.4

0.6

0.8

Hs Vs Xa
100.00

0.00
-100.00
-200.00
-300.00
-400.00

0.00

0.20

0.40

0.60

0.80

1.00

1.20

-400.00
-500.00
-600.00
-700.00

-800.00
y = -6348.6x6 + 10346x5 + 5571.6x4 - 21790x3 + 18219x2 - 6002.4x +
2.6229

CL.Mwprom
75.44551
75.74708
76.03919
76.32549
76.60701
76.88478
77.56192
78.21679
79.49972
80.74653
81.96058
83.14455
84.28242
85.39492
86.47801
86.98135
87.53543

TrA
0.72790
0.72088
0.71522
0.71073
0.70703
0.70391
0.69747

Hs
HL (KJ/Kmol)
0
4347.92501
-110.30380 3982.31074
-209.68686 3678.19682
-296.53629 3430.43735
-371.83245 3223.33454
-436.52379 3048.66308
-557.75809 2702.16922
-631.51995 2444.74641
-680.95981 2151.61531
-655.13877 2003.84461
-595.06550 1923.58313
-516.04373 1881.01372
-415.82453 1853.90092
-287.32923 1867.18455
-135.94283 1907.53252
-62.04317 1906.34478
0
1937.15908

TrB
0.57662
0.57106
0.56658
0.56302
0.56009
0.55762
0.55252

KJ/Kmol
A.MWA
32442.64091
32748.45214
32991.28323
33181.71497
33337.62539
33467.95462
33734.04293

KJ/Kmol
B.MWB
40799.21346
40966.65201
41099.84565
41204.43071
41290.13586
41361.82936
41508.33268

Hv (KJ/Kmol)
45147.13847
44058.7185
43277.83006
42679.07057
42188.74781
41766.50363
40976.83642

50000
45000
40000
35000

35000

0.69220
0.68498
0.67972
0.67543
0.67172
0.66801
0.66470
0.66158
0.65962
0.65865

0.54834
0.54263
0.53845
0.53505
0.53212
0.52918
0.52656
0.52408
0.52254
0.52177

33949.10291
34240.07145
34449.75167
34618.99712
34764.02948
34908.03096
35036.01590
35155.74381
35230.21985
35267.35678

41626.85329
41787.34247
41903.07560
41996.53065
42076.63904
42156.19568
42226.91557
42293.08087
42334.24161
42354.76678

40472.74571
39782.46632
39276.07746
38882.43315
38525.77279
38178.91241
37872.83002
37516.06058
37355.88714
37204.51586

30000
25000
20000
15000
10000
5000
0

0.2

Hs Vs Xa
Poly. (Hs Vs Xa)

Poly. (Hs Vs Xa)

Vapor
Liquido

0.4

0.6

0.8

1.2