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Second Edition

SYNTHESIS AND TECHNIQUE IN INORGANIC CHEMISTRY


Robert J. Angelici
Department of Chemistry lowa State University Ames. lowa

ir... .

UNIVERSITY SCINCE BOOKS

Mili Valley, California

Appendices

APPENDIX 1

Approxirnate Concentrations of Cornrnercial, Reagent-grade Acids and Bases


% by Weight
Molarity

Acid or Base
Acetic acid (glacial) Ammonia (aqueous) Hydrochloric acid Nitric acid Perchloric acid Phosphoric acid Sulfuric acid

99.8 29 37 70 70 85 96

17.4 14.8 12.0 15.9 11.7 14.7 18

APPENDIX 2 Expected Molar Conductance (AM) Ranges a for 2, 3, 4, and 5 Ion Electrolytes (-10- 3 M) in Sorne Cornrnon Solvents at 25Cb
Electrolyte Types Solvent
WaterC Nitromethane Nitrobenzene Acetone Acetonitrile Dimethylformamide Methanol Ethanol

Dielectric Constant

1 :1

2:1

3:1

4:1

78.4 35.9 34.8 20.7 36.2 36.7 32.6 24.3

118-131 75-95 20-30 100-140 120-160 65-90 80-115 35-45

235-273 150-180 50-60 160-200 220-300 130-170 160-220 70"-90

408-435 220-260 70-82 340-420 200-240

-560 290-330 90-100

'U nits on al! molar conductances are ohm-'cm2 mole- ' . bW. J. Geary, Coord. Chem. Rev., 7, 81 (1971). CM. Sneed and J. Maynard, General Inorganic Chemistry, Van Nostrand, New furk, 1942, p. 813.

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