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4.

a)

Mezcla Nitrgeno (1) / Amoniaco (2)


Datos
P
T
X1
X2

300
293
0.28
0.72

ij
11
22
12
B
-0.19946757

b)

Vc ij
Tc ij
Pc ij
0.0898026
126.22
3414.51
0.07249763
405.3
11130
0.28268673 226.179057 1750.99186

Zc ij
0.29195
0.2345
0.263225

dB/dTr
H[kj/kmol] S[kj/kmol.k] Gr[kj/kmol]
0.39899273 -214.900874 32.5633147 -59.8402717
Mezcla Nitrgeno (1) / Amoniaco (2)

Datos
P
T
X1
X2

120
323
0.83
0.17

ij
11
22
12
B
-0.04919298

Vc ij
Tc ij
Pc ij
0.0898026
126.22
3414.51
0.07249763
405.3
11130
0.28268673 226.179057 1750.99186

Zc ij
0.29195
0.2345
0.263225

dB/dTr
H[kj/kmol] S[kj/kmol.k] Gr[kj/kmol]
0.30459932 -58.1019314 9.94380363 -5.90315749

2)

w ij
B
B
0.039 -0.02668048 0.13399478
0.25 -0.62619689 -0.53296426
0.1445 -0.19589972 0.08100581
Z
V[cm3/kmol]
0.97543
7.92055

coef1
0.985

Tr ij
Pr ij
B^ ij
B ij
2.32134369 0.08786034 -0.02145468 -0.00659374
0.72292129 0.02695418 -0.75943796 -0.22992371
1.29543382 0.17133146 -0.18419438 -0.19781292
coef2
0.969988

f1[kpa]
f2[kpa]
82.74 209.517408

2)

w ij
B
B
0.039 -0.01084119 0.13567634
0.25 -0.52377961 -0.3072103
0.1445 -0.15562297 0.10048961
Z
V[cm3/kmol]
0.997802
22.3293

coef1
0.99969

Tr ij
Pr ij
B^ ij
B ij
2.55902393 0.03514413 -0.00554981 -0.00170564
0.79694054 0.01078167 -0.60058219 -0.18182932
1.42807209 0.06853259 -0.14110222 -0.15153471
coef2
0.98776

f1[kpa]
99.569124

f2[kpa]
290.9964

dB
dB
s
0.07557553 0.00905091 0.22332997
1.56915964 3.90179018 -0.22332997
0.3443691 0.18792216 -0.1591084

dB
0.05865573
1.21785725
0.26727198

dB
s
0.00545193 0.18012367
2.35029524 -0.18012367
0.11319741 -0.11953446

4.b)

Datos
P
120
T
323
X1
0.83
X2
0.17

Mezcla Nitrgeno (1) / Amoniaco (2)

ij
11
22
12
B

Vc ij
Tc ij
Pc ij
0.0898026
126.22 3414.51
0.0724976
405.3
11130
0.2826867 226.1791 1750.992

Zc ij
w ij
B
B
Tr ij
Pr ij
B^ ij
B ij
dB
0.29195 0.039 -0.01084119 0.13567634 2.55902393 0.03514413 -0.00554981 -0.00170564 0.05865573
0.2345
0.25 -0.52377961 -0.3072103 0.79694054 0.01078167 -0.60058219 -0.18182932 1.21785725
0.263225 0.1445 -0.15562297 0.10048961 1.42807209 0.06853259 -0.14110222 -0.15153471 0.26727198

dB/dTr
H
S
Gr
Z
V
-0 0.3045993 -58.10193 9.943804 -5.90315749 0.9978

phi1
22.3293

phi2
0.99969

F1
0.98776

F2
99.569124

290.9964

dB
0.00545193
2.35029524
0.11319741

s
0.18012367
-0.18012367
-0.11953446