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APP CFE

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2010. 9. <14pt>

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APP CFE (2010. 07. 01. ~ 2010. 06. 30.)
.
2010. 08.

34
.

1 APP CFE
1 APP
2 T/F
2 APP CFE
1 APP CFE T/F Meeting
2 APP PIC Meeting
3 KIER-NETL
4 : PIC
5
(World CTL 2010 Conference )
3
KIER-NETL :

- 1 -

APP

APP

CFE

Asia Pacific Partnership on Clean Development and Climate

. APP
7(, , ,
, , , ) . 2005 7 (
(ARF) ) 6(, , , , , )
, 2006 1 (
) , Work Plan, .
, 2007 7 . APP 1
, (PIC, Policy Implementation
Committee), 8 T/F(Task Force) .
APP

[ 1] APP
APP 7

, , ,
,
. , APP

. APP T/F
1 .

- 2 -

1] APP T/F

T/
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APP 8 T/F Cleaner Fossil Energy(

) , ,
T/F . ()
() T/F , 6 T/F
.
-
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- CO
-
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APP CFE 2 , 16 12
, (KIER) National
Energy Technology Laboratory (CFE-07-16)
.
APP CFE

- 3 -

 2] APP CFE

CFE-06-01
CFE-06-02 CO /
CFE-06-03
CFE-06-04
CFE-06-05 Callide-A (
CFE-06-06 CO (
CFE-06-07 CCS IGCC
CFE-06-08
,
CFE-06-09

CFE-06-10 LNG
CFE-06-11
CFE-06-12
CFE-06-13 CO
CFE-07-14 IGCC CO
IGCC
CFE-07-15


[

Flagship)

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CFE-07-16

,
()
, ,
APP
,
,
()
,
, APP
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,

,

- 4 -

APP

CFE

APP

CFE T/
F M eeting

5 T/F T/F
.
1: 2006 4 ( )
- 6
- 8, 3 11
-
2: 2006 7 ()
- 13
3: 2007 7 (, )
- 3 PIC Action Plan 13
- 4 PIC 4
NETL()
4: 2008 4 ( )
- PowerGen Task Force , IGCC-CCS workshop
CCS .
- CO
.
- CFE 14 (KIER-NETL
)-2 .
- 3 , 1 .
- APP 7 ()
2

5: 2009 3-4 ()
-
- APP 7 47
-
- 12
- 5 -

APP

7
.

PI C

PIC

M eeti ng

PIC

- 2006 10 11-13, ( )
- CO ,

- ( 2
AP6 )
- ,
FutureGen
-
R&D ,

2

PI C

- 2007 7 19-20, ( )
- 2 (IGCC /)
-
IGCC CO ( )
IGCC ( IGCC
CSIRO Thermal Power Research Institute )
( NETL
)
- 13
3

PI C

- 2008 5 19-20, Seattle( )
- 2008 4 Task Force Meeting
150 ,
-
4

PI C

- 6 -

- IGCC-CCS (-Andra
Pradesh)

(, , )
Wyoming Shanxi CCD

APP 7 ( )
6
- 2008 10 29-30, Vancouver( )
- CCS(Carbon Capture and Storage)

- Global CCS Institute
CCS

Global CCS Institutue CCS /
/
2008 8 , 2009 1
FutureGen ,
CCS

- 2010 CCS


CCS
- stackholder ACA(Australian Coal Association)
APP PIC
1 , 10
3 working group (IGCC, Oxy-Fuel, Gas)
2008 4 APP PowerGen T/F joint meeting
PIC
:

PIC

7
- 2009 5 19-20, Gold Coast( )
-
:

PI C

- 7 -

 (2009 3, )
: Harmonisation of APP

Gas Markets - Analysis of Gas

Markets and their Growth in APP Partner Economies

Energy Agency(IEA)

- 1
: ,
: /
: (Guidelines for Safe and Effective Carbon Capture
International
IGCC

and Storage: Building Rugulatory Capacity)

1.

KI ER-NET L

Pittsburgh, Westin Convention Center
2009 09 21()-23()
.

2007 09 KIER 30 NETL MOU
2008 08 19() KIER/NETL Meeting Minutes
Web Conference 5
.

: "CFE-07-16: Cooperative R&D on Cleaner Fossil Energy"
KIER-NETL

: :
.

KIER-NETL Workshop

KIER-

NETL Lab Tour(Pittsburgh, Morgantown)

- 8 -

3-1:
3-2: KIER-NETL
.

2.

NETL (Dr. Carl Bauer)

- : 3
- :
2 2010
KIER-NETL Collaboration
NETL
KIER

. K IER -NETL

- : 921()-23()
- : Pittsburgh, Westin Convention Center
- : 1 KIER-NETL workshop on Energy Technology
7 (CO hydrate, Chemical looping, Solid sorbent, CTL,
Gasifier, CO membrane, H separation)
.

K IER -NETL

st

- MOU KIER/NETL NETL

- KIER/NETL

- 2010 2
Anthony V. Cugini, Office of Research and Development, Director
- MOU KIER/NETL
KIER
- DOE/KIER ,
- 9 -

R&D
- : .

: ,
,
- 8 :
: , . CTL, ,
: CO ,
H
- :

KIER/NETL
(on-line & off-line) Fun
2

CO
2

- KIER: Carbon Dioxide Separations through Al-Rich LTA and FAU

Churl-Hee Cho
Membrane ]

Zeolite Membranes
[

- NETL: Supported Liquid Membranes for Natural Gas Purification

Christina Myers

Coal to Liquid

- KIER: Coal-to-Liquids (CTL) Project Status and Collaboration with NETL

Heon Jung

- NETL: Progress in Coal-to-Liquids Research at NETL

Charles Taylor

CO
- KIER: Status Update Seong-Pil Kang
2

- NETL: Experiments on the Rapid Formation of Gas Hydrates

Thomas Brown

- 10 -

Hydrogen

- KIER: A Hybrid PSA/Membrane Unit for Hydrogen Production from

SMR Stream

Kuck-Taek Chue

- NETL: Hydrogen Production via SMR Utilizing a Hybrid

PSA/Membrane Separator

Bret Howard

Advanced Gasifier

- KIER: Status of Coal Gasification R&D in KIER

Jae-Goo Lee

- NETL: Gasification Modeling Research and Development at US Dept. of

Energy-National Energy Technology Laboratory: Overview and Future
Directions

Chris Guenther

Chemical Looping

- KIER: Research Progress of Chemical Looping Combustion Technology

in KIER

Ho-Jung Ryu

- NETL: Progress of Chemical Looping Combustion Research - Ranjani

Siriwardane

CO

Capture Sorbent

- KIER: Economic Analyses of Circulating Fluidized Bed Carbon Dioxide

Capture Process Using Dry Alkali Metal Carbonate Sorbents
Young-Cheol Park
- NETL: Status of NETL CO2 Sorbent and Reactors

- Simulation & Visualization(Bill Rogers)

- Fuel Cells/HYPER(Kirk Gerdes)
- Extreme Drilling Lab(Bill Ayers)
- Cold Flow Facilities(Chris Ludlow)
- Multiphase Flow(Grant Bromhal, Joseph Mei)
- Hydrate(Ray Boswell, Y.G. Seol)

- 11 -

George Richards

- Membrane Separation & Bimass Gasification(Bryan Morreale)

- Computational Science and Chemistry(Dan Sorescu)
- CO2 Capture(Henry Pennline)
- Core Flow Lab & Sequestration(Brian Strazisar)
- Surface Science(Christopher Matranga)

3.

Dr. Andrew Gellman(: Director,

. Carnegie

M ellon

University (CM U)

NETL Institute

for Advanced Energy Solutions, gellman@cmu.edu)

.
NETL $13 million/year
- CMU :
- KIER web site
-

Bioengineering,

Complex fluids(polymer, multiphase),

Environmental(air quality),
Process system engineering(process design),
Solid state materials(catalyst, capture material, sorbent)

: $100,000-$150,000/year

Dr. Gregory S. Roher

- CMU 4 :
(iron steel, refractory, HT process: FC)
Micro structure science(Ni alloy, SOFC)

Wide band semi-conductor(thermo voltaic, switching electronics)

Magnetic materials(IT, high temp generator)

21%
:
: (1 : $36,000 + tuition)
:
: $80,000-$100,000/year
- 12 -

Dr. Chunshan Song, Director, Energy Institute

- NETL 30 ,
- Penn State
-
. Pennsylvania

S tate

University

Dr. J. Karl Johnson(Interim Department Chair)

- Pittsburgh Coal Conference
- NETL
-
. University

4.

of

Pittsburgh

2 KIER-NETL 2010
KIER-NETL : Carnegie-Mellon, Penn.
State , Univ. of Pittsburgh

- 13 -

< 3-1>

- 14 -

< 3-2> KIER-NETL

- 15 -

1.

2.

: PI C

8 APP PIC 3 APP

- , Oriental Riverside Hotel
- 2009 10 26()-27()

- 4-1: Draft Agenda

(CFE) ,

, CCS, 12 ( 2
)
- KIER-NETL (CFE-07-16)

. T/
F

5 Task Force Meeting (2009.03.31-04.01, )
- Workshop ( 33,
37 )
- CFE
- - CCS
.

(Clean Fossil Energy Expert Forum)

(2007.03-)
- 5 Task Force Meeting
, APP CFE
CFE-07-16
- 2007 11 KIER-NETL Web-Conference -
- 16 -

( 5 )
(2009.09.21-09.22,
Pittsburgh)
KIER NETL , ,
,
CCS 15
KIER NETL

- KIER-NETL Offline Joint-Conference

CFE-06-03 , CFE-06-13 CO


.

KIER-NETL Offline Joint-Conference(2009.09.21-09.22, Pittsburgh)
-

.

APP
- CFE , APP CFE


.

APP

T/
F

- CFE

-
, activity

- APP

- 17 -

) Workshop(2009.03.31,
, 5 Task Force Meeting ), KIER-NETL Offline
Joint-Conference(2009.09.21-09.22, Pittsburgh)}
{

- CO
2 NETL
- , CTL, Membrane, , , 6

.

(240,000)
- Web-conference (30,000),
(150,000), (60,000)

-
NETL
- KIER-NETL Offline Joint-Conference (2009.09.21-09.22,
Pittsburgh)
KIER NETL ,
(CTL), ,
CCS 15
KIER NETL

workshop ( 33,
37 )
CFE
- : CCS
(1500 ton CO / )
- : cool earth
.

CFE T/
F

- 18 -

CO 50% )
: low carbon
(20 MW CCS Alstom )
- CCS
- CCS
(2050

- 19 -

<

4-1> Draft Agenda

- 20 -

- 21 -

(World CTL 2010 Conf erence

1.

- (The Great Wall Sheraton)
- (Shenhua , Yitai )
- 2010 04 13()-16()
World CTL Conference
- CFE

- , , , APP CFE
, , , , , , , ,
, CFE
- CTL, SNG(Substitute Natural Gas), CTC(Coal-To-Chemical)
, ,

- 1 2008 , 2 2009
D.C. , (2010, ) 3

- CFE
, APP CFE

- APP , , APP CFE
, APP CFE

2.

ICC-CAS (I nstitute

S cience)

S ynfuel

of

China

Coal

Chemistry,

Chinese

Academy

of

- 22 -

: Yong-Wang Li

- Synfuels China
. Synfuels China
. .
- ICC-CAS
. ICC-CAS
, KIER --
, scale-up
.
- KIER ,
.


: Ke Liu(Vice President and CTO)
Yong Wang(Chief Scientist PNNL )
.

NI CE(National

Institute

of

Clean-and-Low-Carbon

Energy)

- NICE Shenhua /
.
- CEO
,
.
- (PNNL )
, .
- 2010 6 21 Yong Wang
.

: Fanor Mondragon(, Universidad de Antioquia)
.

-
- 23 -

 .

.
- , ,
- .
-
.
-

- 24 -

Coal

2010

R esearch

collab oration

b etween

Columb ia and R epub lic of

K orea

0417 draft prepared by Heon Jung, Korea Institute of Energy Research

Background
Columbia, being abundant in coal reserves, is seeking to establish a research
capacity on coal utilization. Republic of Korea is a leading nation among
developing countries in terms of economic development and relevant research
activities. Columbia can be benefited from the experience of Korean research
institutions in the area of coal utilization. Through collaboration between two
countries, Columbia can build a coal research unit fast and efficiently and
Republic of Korea can improve accessibility the Columbian resources.
Area of collaboration
Establish a coal research institute in Columbia with emphasis on following
areas
- gasification of coal
- coal liquefaction
- coal combustion
Expand utilization opportunities of Columbian coal in Korea
Methods of Collaboration
- Transfer of Korean coal research expertise
- Help on material research knowhow (high temperature materials, valves,
etc.)
- People exchange
- Test Columbian coal in Korea for future utilization
Possible Vehicles
- Research program of International Cooperation Research of Ministry of
Knowledge and Economy (MKE), Korea
- Fund from Colciencias, Columbia
Steps and Milestones
- Pre agreement made by Prof. Fanor Mondragon, University of Antioquia
and Dr. Heon Jung of KIER on details of collaboration (by May 31, 2010)
- Report to both Governments (by June 30, 2010)
- Columbian Minister contacts Korean Minister of MKE requesting
collaboration (by July 9, 2010)
- Fix visit scheduling of Columbian delegates to MKE and Korea Institute
of Energy Research (KIER) (August 31, 2010)
- Columbian delegates visit Korea and sign Memorandum of Understanding
th
(4 quarter of 2010)
- Collaboration starts (November 1, 2010)

- 25 -

3.

CFE

. Technical
E-G as

TM

(World

CT L 2010

Conference)

Workshop
G asification

Technology

(Phil Amick, ConocoPhillips, USA)

: IGCC(Integrated Gasficiation Combined Cycle),

- E-Gas Technology: ConocoPhillips

-

SNG(Substitute Natural Gas)

: petcoke, bituminous coal, sub-bituminous coal

( 2 )
- Kentucky NewGas (SNG) project : Peabody
, , CO .
- 40%
- Petcoke IGCC+CCS project (Sweeny E-Gas project) 14
CCS
-

- E-Gas Technology Gasifier: 2

2] ConocoPhillips E-Gas

TM

S hell

G asification

&

Clean

(Jiang Tao, Shell, China)

Coal

Technology Gasifier

Energy

12 , 7
H (2)

- SCGP: Shell Coal Gasification Process,

- SCGP for CTL: Shenhua

- 26 -

(CAPEX) 3
95% 15-20%
-
-
- Shell

Cost

Ef fective

S yngas

Purification

(William Rouleau, Merichem, USA)

Merichem
: ( 3)

- LO-CAT: Liquid Oxidation Catalyst

- LO-CAT

[ 3] Merichem LO-CAT
: , H S elemental sulfur ,
99.9+%, LO-CAT (
)
- LO-CAT : methanol process sulfur, CO
, LO-CAT sulfur

- : Rectisol + Claus
- : $200/ton S removed
-
- LO-CAT

An

I ntroduction

to Clean

Coal

Underground Coal

- 27 -

G asification

(Rob Abbanat, Clean Coal, China)

in-situ
, 100
- UCG : (), ,
CO , surface footprint
(), deep/un-mineable coal ()
- CRIP: Controlled Retraction Injection Point , Clean Coal
UCG , injection point UCG
surface footprint ,
( 4), 30 m 500-1000 m.
- : H 17, CO 10.8. CH 9, CO 22.5, H O 40, H S 0.6%, 43 bar,
- UCG: Underground Coal Gasification,

8 MJ/m .

[ 4] Clean Coal UCG: CRIP

: EI Tremedal project()

91.6% Yerostigaz UCG

100 m Angren (40 )
- Chinchilla UCG GTL
- ( ) , GTL
Co FBR

Linc Energy

The

Progress

of

UCG

to G TL

and

its

Potential

- Linc

EER C

CB TL

Process

Development

- 28 -

(Bruce Folkedahi, EERC, USA)

()
block diagram ( 5)

- EERC: Energy & Environment Research Center

- CBTL: Coal/Biomass to Liquid,

5] EERC CBTL

- EERC gasifier: entrained-flow gasifier

10 ppb
- EERC FT synthesis: , bench-scale (0.5 in I.D.
8 in H), large-scale (1 in I.D. 10 in H, 2 kg loading, oil
), EERC FT ()
- 1
- EERC syncrude upgrading: (1 cc/min - 3 l/h, 1000 psig),
(250 cc - 2 gal, 5000 psig), upgrade / chromatogram
( 6 )
- EERC syngas cleaning: hot-syngas desulfurization process, 2
syngas

- CBTL test: coal:biomass = 70:30

-

- 29 -

 6]

Advanced

O nce-Through

FT

Process

(Ray Swanepoel, CCT, South Africa)

: FT process
, FT process 1350 bpd ,

- Once-through FT process : ( bpd
$54,000-$69,000, ), ( $29),
carbon footprint(carbon efficiency 3-6% )
- Modular FT system: FT system

- GNI/CCT pilot plant: Baoji ammonia plant ,
ammonia plant syngas, H -rich , , , FT
5(: 5 bpd, 14m 5cm), , gas compression, air
compressor, ,
- CCT CTL /
(1) air-blown gasifier
(2) (shift )
(3) (
FBR series reactor knock-out
[80% ], 1,350-10,000 bpd
- CCT: Clean Coal Technology
- Once-through FT process

- 30 -

(4)

CT L D evelopment:

From Fundamental

to I ndustrial

Practices

(Yong-Wang Li, Synfuel China, China)

:
ICC-CAS(Institute of Coal Chemistry, Chinese Academy of
Science) CTL (1980-1997)
(2) FT pilot plant (1997-2005, ICC-CAS)
(3) CAS Synfuel China (2006)
(4) 3 4000 bpd commissioning(2009)
(5) 80,000 bpd (2010)
- Synfuel China :
- Synfuel China
(1)

(1) Synfuel China Research(Taiyuan, Beijing, Inner Mongolia):

( 12, 15, 55, 25, 10),

(2) Synfuel China Engineering LtD(Beijing): ( 25,
50, 130), CTL
(3) Synfuel China Catalyst LtD(Anhui): ( 80), 2,000
t/y, metal salt 5,000 t
(4) Synfuel China organization(Taiyuan)

- HTSFTP: High-Temperature Slurry Fischer-Tropsch Process, Synfuel

FT
: type - SBCR, - 275 C,
/ ( ppm
) , - C >92%, - 1.0-1.4
g/g -h, ( 3)
- HTSFTP 1.0-1.4 g/g -h
(1) (270 C) -
(2) (Sasol 2500bpd[5m x 22m]
60% Yitai 4000bpd[5.3m 50m]
20% )
(3) ( CH 3% )
China

- HTSFTP

5+

(cat)

(cat)

- 31 -

 3> Synfuel China FT

<

: Yitai, Luan, Shenhua 3 (2005, Yitai

- HTSFTP

- water-slurry gasification, Luan - fixed-bed gasification, Shenhua - Shell

Yitai 5.3 m I.D. Luan

5.8 m I.D., ( 7),
HTSFTP 2
switch
( 8 ), (2010) 5 full operation
- : FT WGS rate Fe H /CO ratio
, Fe CO (WGS
) , FT on-site /

gasification), FT
Shenhua

- 32 -

7] Synfuel China HTSFTP

8] Synfuel China HTSFTP

M ethanol

to

G asoline

(MT G )

Process

(Mitch Hindman, EMRE)

MTG Jincheng Anthracite Mining Group (JAMG)

-2,500 bpd
- 20000 bpd .
- FT 5% ( : 4 ).
- 2

- 33 -

<

4> 2009 STUDY:LIQUID TRANSPORTATION FUELS FROM

COAL / BIOMASS (Joint Study by the U.S. National Academy of

Sciences and National Academy of Engineering as part of the
America Energy Future Project)

D irect

Coal

Liq uefaction

: Alliance

D CL

(Axens and Headwaters)

1 Axens
Alliance DCL
.
- 30,000 bpd 2 ( 5, 6)
(1: , 2: , 3:
IGCC 3 )
< 5> 1
- 2010

Headwater

- 34 -

6>

<

. S trategies
S tatus

&

O perations

and Future

of

S henhua's

Coal

Conversion

(Yuzhuo Zhang, Shenhua Group Corporation LtD., China)

( 7)
< 7> Shenhua

()

2
DCL

Erdos

() 1.08 mt/y
(2008)

Erdos ICC-CAS
0.18 mt/y
(2009)
ICL
mt/y
Ningxia
Shenhua Ningxia Coal
() 3.8(=93,000
( Industry Group SA
bpd)
-) Sasol
Batou
Methanol
4.72 mt/y
CTM(Coal to Methanol)
(2010)
Batou
IDME(Methanol
DME
0.21 mt/y
(2009)
DME )
Batou
Olefin
1.10 mt/y
MTO(Methanol to Olefin)
(2010)
2.0
billion

Erdos
SNG
m3/y
(2013 )
-

- 35 -

: CTL ,
plant CTL plant
( plant 100 CTL plant
12 ), plant
, IGCC plant .
- : 2008 300, 2009 3 2,736 ,
(90.9%), (56-57%)
- 90% CO
95-96% 10
-

:
: 4,500/
:
Synfuel China
Shell
2009 1
( 8 )
< 8>

- 36 -

JV : 2 93,000bpd
NDRC . 2010 5-6 .
- Shenhua Polygeneration FS :
- Sasol
2009

The

Pure IGCC

60 cents

Methanol

51 cents

FT

50 cents

Coal

I ndustry

Perspective

(Don Elder, World Coal Institute, New Zealand)

-25,
-60, -100
- New Zealand 150 Lignite , Solid Energy 30
- CTL : Coal to fertilizer , ,
Lignite
- : /

- World Coal Institute

The

Oil

Industry

Perspective

50


70%
easy oil

CO
- EGTL $50/bbl
- Pearl GTL project $65/bbl IRR 23%
- Compact GTL 2012 PetroBRAS
-
-

Challenges

and

S tatus

of

CT L D evelopment

(Qingyun Sun, West Virginia University, USA)

in

the

US

and

China

( ):
(Shell, ExxonMobil, BP, GE, Dow, AEP, Shenhua, Peabody, Consol

- CTL

- 37 -

; 9 )

[ 9] CTL
CTL : (1) Shenhua DCL(24,000 bpd), (2) Yitai ICL(4,000

bpd), (3) Luan ICL(4,000 bpd), (4) Yankuan ICL(22,000 bpd), (5)
Sasol-Shenhua/Ningmei ICL(70,000 bpd),

( 10)

10] CTL
- West Virginia CTL : (1) Consol CTL plant, -7,200
bpd, -$8, -ExxonMobil MTG, (2) TGDS CTL plant, -20,000
bpd, -$30, -TransGas
- CTL 15$
[

Yitai

Coal

Liquefaction

16 oil/( 3500 /)
- 38 -

5 , 2008 12
: 21.76 RMB
- 2009 1 450 , 2 5088 4500
- : 360/ 1 (2010-2014)
180/ (2014-2017)
- NDRC
- 2006
-

Coal-to-Hydrocarbons:

Which

R outes

(Matthieu Lelievre, Total, France)

to

S elect?

5(SNG, FT, IDME, DDME, MeOH)

/ - 1
- : -Bituminous, -wet slurry type(Texaco type)
- : FT , CO ,
, premium market
.
- Performance /: FT
( 9 )
< 9> SNG, FT, IDME, DDME, MeOH performance

- 39 -

 /: FT CO CO
( 11 )

- CO2

11] CO /
- Plant : FT ,
( 12 )
[

12] /

- 40 -

(Water Consumption): FT process water

( 13 )

[ 13] /
EPC cost , FT EPC cost
( 14 )

- EPC Cost: FT

14] EPC cost /

- 41 -

- Technical Cost: FT

( 15 )

S hanxi

technical cost

15] technical cost /

Indirect Liq uef action

O peration

(Lui Bin, Shanxi Lu'An Coal-Based Synthetic Oil, China)

: 210,000 t/y = 10,000 t/y(FBR, Co ) + 200,000 t/y(SBCR,

)
- : (1) Co 4,000 (2008.12.22), (2) Fe
8 (2009.07.10), (3) diesel, naphtha(2009.08.19), (4)
-demo plant(2010 ), (5) 50 t/y plant (2013
), (6) 300 t/y (2015 )
-

Fe

S INOPEC

Engineering I ncorporation

(S EI )

(Liu Jiaming, CEO)

EPC
Pilot EPC

- Shenhua
-

- 42 -

S asol

and

FT

(John Amstrong, Sasol China, South Africa)

- Sasol

scale-up : SBCR, Co ( 16)

16] Sasol scale-up process

- FBR , scale-up
10m
- LTFT ,
blending agent
- : CO issue (CO , CO /)
[

D emonstrative

O peration

of

D CL

Technology in

China

(Zhang Jiming, China Shenhua CTL Chemical Co., Ltd.)

2008
300, 2009 3 2,736
- (90.9%), (56-57%)
- :
4000
Load 80%


CO 10/

- Shenhua
- 2008

- 43 -

. Environment &
CO 2

I ndustries

S eq uestration

(S. Julio Friedmann, LLNL, USA)

- OECD

No sequestration resource = No project

CO
2

- Site characterization

- MIT report "The Future of Coal"

R e-Enginnering CT L:

Cutting CO 2

Emissions

I nstead of

Cleaning Up

(Diane Hildebrandt, COMPS, South Africa)

,
Witwatersrand
- COMPS FT pilot plant: Chinchilla Linc plant, Baoji
- COMPS: Centre of Material and Process Synthesis

FT pilot plant

CO 4 :
(1) FT plant :
, ,

(2) Coal-bed methane :
FT 1 3.5 CO (3/2C
+ H O -CH - + 1/2 CO ), coal-bed methane

- CTL

- 44 -

co-feeding zero CO
emission (C + CH -CH -),
(3) FT : FT
, CO
, 80,000
bpd CTL plant FT 675 MW

(5) : once-through process
combined fuel
,
CO
, ASU /
(CO , )
FT
- : GNI FT pilot plant(, Baoji),
(FBR, Co )
2

Electricity D ecarb onization: Coproduction

CCS

vs.

S tand-Alone

Power

with

of

Power

and S ynf uels

with

CCS

(Robert Williams, Princeton University, USA)

39% biomass CBTL(coal+

CTL CO
, CBTL CTL
- OT vs. RC: OT(once-through)
RC(recycle) ( 10 )
-
- CBTL vs. CTL:

biomass-to-liquid)

Larson, E.D., G. Fiorese, G. Liu, R.H. Williams, T.G Kreutz, and S.

Consonni, 2010: "Co-production of synfuels and electricity from coal +
biomass with zero net greenhouse gas emissions: an Illinois case study,"
Energy and Environmental Science, 3: 28-42, 2010.
T. Kreutz, E. Larson, G. Liu, and R. Williams, 2008: "Fischer-Tropsch
Fuels from Coal and Biomass," Proceedings of the 25th Annual
International Pittsburgh CoalConference, Pittsburgh, PA, 29 September - 2
October.

- 45 -

<

10> CTL vs. CBTL, OT vs. RC, V vs. CCS:

:
( 17 )

CBTL-OT-CCS(~39% biomass)

17]

Catalysts: O utlook

and Focus

on

S NG

(Ian Barton, Johnson Matthey)

Davy Process Technology

, SNG

- SNG Cash Creek, Datang
1()
- Lurgi
- 2006

- Shift, Methanation, methanol

- 46 -

Advantages
Relatively simple and cost effective
High methane in raw gas
Disadvantages
High levels of tars in raw gas
Significant extra processing to clean process gas
Complex effluent treatment system

- Shift

Saves cost of shift system

Less requirement for process steam

Lower cost of acid gas removal
More flexible process with less requirement for tight control of
gas composition

. Industrial
V isit

of

T our in

Inner M ongolia

S henhua D irect

CTL

Plant

: , Ordos ,
, , , coal-to-hydrogen ,
ASU(air separation unit), 54
- : (3.45 mt/y), LPG(102.1 kt/y), naphtha(249.9 kt/y),
-

diesel(714.6 kt/y), phenol(3.6 kt/y)

: Shenhua DCL plant , , 13

- Plant : ( 18)
-

18] Shenhua plant

- 47 -

- Tour

: ( 19)

[ 19] Shenhua plant tour

V isit

of

Yitai

I ndirect

CTL

Plant

: Yitai CTL (2005.12.08, -48/y, -4.975

billion RMB ), Phase 1 (2006.05, -16t/y, -2.637
billion RMB), (2009.03.20), 5,000
(-2010.03.13)
- Yitai CTL plant :
production line
- : 2015 Ordos 500/y CTL plant ,
-CTL-
- : ( 20)
-

20] Yitai plant

- 48 -

: ( 21)

[ 21] Yitai plant

- 49 -

(APP) (CFE)
, , CFE
, APP CFE

. APP CFE 3 , 12
. "CFE-07-16: Cooperative
R&D on Cleaner Fossil Energy" 1 ,
11 .
APP CFE
"CFE-07-16: Cooperative R&D on Cleaner Fossil Energy"
(KIER)- National Energy Technolgy
Laboratory(NETL) Pittsburgh /.
APP (PIC) 1 ,
World CTL Conference APP CFE
.
CFE
.
, APP CFE
. APP
.

- 50 -

K IER -NETL

KIER Coal-to-liquid (CTL) Project

and KIER-NETL Collaboration

Hak-Joo Kim, Hotae Lee, Dong-Hyun Chun,

Jung-Hoon Yang, Jung-Il Yang, Heon Jung

Korea Institute of Energy Research (KIER)

Korea chose Indirect Coal Liquefaction

liquefaction

separation

ICL

coal

gasifier
Oxygen
steam

cleaning

Syngas
(CO+H 2)

Sulfur/par ticulate

Gas
Turbine

HRSG

IGCC
Ste am
turbine

- 51 -

gasoline
diesel
naphtha

electricity

KIER CTL Project

Objective

Develop indirect coal liquefaction process to

convert 10 tons of coal per day into 15 barrels
of coal liquid
Contents

10 ton/day coal gasifier

Coal gas cleaning unit including desulfurization unit
and filter
Liquefaction reaction system of 15 barrel/day
Pilot plant design package of 300 barrel/day

KIER Experimental gasifier

Coal 10 ton/day
Height 7m
Diameter 1.3m
Being scaled-up

gasifier
gasifier
toncoal/day)
coal/day)
(1(1ton
Slurry -f ed entrained bed gasif ier up to 30 atm

- 52 -

High pressure gasifier (1 ton/day) recently

installed

Gasifier parts development

Burner
Burne
r

Refractory
Refractory

- 53 -

Slagdisposer
disposer
Slag

Coal gas cleaning (filter)

Newly developed
filter
Double mem brane

m embrane

Air back puls e

Fine dust difficult

to be removed

Existing ceramic filter

Coal gas cleaning (filter)

Manufacturing process patented.

- 54 -

Coal gas cleaning (desulfurization)

Korean desulfurizing
agent

Name

ZAC-32

Size ?[micron]

84

density [g/cm3]
area

0.91

[m2/g]

16.3

ASTM attrition [%]

29.2

Desulfurization test unit

Cleaned gas

Regenerator

Cyclone

N2

Control valve

1200 mm

Cyclone

Riser

SO2

Riser

50 mm I.D.

Filter

1 in I.D.

Loopseal

Q3

Desulfurizer

2000 mm

Desulf urizer

Solid
Ingection
Nozzle
Bubbling
Fluidized
Bed

Regenerator

120 mm I.D.

Plenum

Q1 (Coal gas)

Q2

- 55 -

Desulfurization test result

1200 ppm 1 ppm

KIER Fe liquefaction catalyst

SEM Images

log(W n/ n)

0 .0

Chain growth probability

-0 .5

= 0.91

-1 .0

-1 .5
0

10

15

20

25

30

35

40

45

50

- 56 -

Liquefaction reactor
a)

b)
C)

d)
f)

15 bbl/day
e)

g)

h)

Gas distributer B type

Cold reactor

0.2 bbl/day

0.02 bbl/day

0.02 bpd liquefaction reactor

- 57 -

0.02 bpd liquefaction reactor run results

Catalyst : 720g, Mineral Oil : 2,880g
Reactio n: 265 oC, 25 bar
24 l/min (H 2/CO ratio =1)

CO Conv. (COMMERCIAL)
CO to CO2
CO to HC
CO Conv. (KIER BM10 B)
CO to CO2
CO to HC

100

100

80

80

60

60

40

40

Conversion (%)

Conversion (%)

20
KIER BM 10B
COMMERCIAL
0

10

20

30

40

20

50

10

20

Time (hr)

30

40

T ime (hr)

KIER Fe catalysts productivity: 0.23 g oil/gcat hr

0.2 bbl/day unit has been tested

100

80

60

40

20

0
0.0

5.0

10.0

15.0

20.0

-20
CO to CO2

- Connected to 1 ton/day coal gasifier

- Scale-up design variables are obtained.

H2 Conv . (Ov erall)

CO Co nv (Total)

Oil/Wax

714 .2mol/10.00kg
714.2mol/10.00kg

Productivity
Product ivity

0.1 9 g/gcat h
0.19

Oil yield

63.1%

Scale
Sca le

0.145
bppd
d
0.145 b

- Pressurized system will be operational soon.

- 58 -

KIER-NETL CTL collaboration

Proposed work
NETL

Fundamental analysis on liquefaction catalysts

Develop Co-based catalysts
Catalyst deactivation study
New concept catalyst development

KIER
Develop Fe-based catalysts
Develop slurry bubble column reactor and scaleup technology
Coal/biomass gasifier-linked FT reaction proof
testing including NETLs Co-based catalyst

KIER-NETL CTL collaboration

Expected outcome
Complete design package on CTL and CBTL
processes based on KIER catalysts and NETL
catalysts, respectively.
Scientific knowledge on catalyst deactivation
phenomena reported in peer-reviewed journal
Pilot-testing of the co-developed process (2nd
stage research)

- 59 -

25.0

15 bbl/day unit designed, being constructed.

Thank you !

- 60 -

- KIER-NETL

CFE-07-16: Cooperative R&D on Cleaner Fossil Energy"

KIER-NETL

:
KIER-NETL Workshop: 7 (CO hydrate,
2

Chemical looping, Solid sorbent, CTL, Gasifier, CO2 membrane, H2

separation)
KIER- : KIER-Carnegie Mellon University(CMU),
KIER-Pennsylvania State University,
KIER-University of Pittsburgh

NETL Lab Tour(Pittsburgh, Morgantown)

(NETL 7 )
CO
2

- Supported Liquid Membranes for Natural Gas Purification

[ : Christina Myers]
Coal to Liquid

- Sulfur Effects in Coal-to-Liquids Process

[ : Charles Taylor]
CO
2

- Experiments on the Rapid Formation of Gas Hydrates

[ : Thomas Brown]
Hydrogen

- Hydrogen Production via SMR Utilizing a Hybrid PSA/Membrane

Separator

[ : Bret Howard]
Advanced Gasifier

- Gasification Modeling Research and Development

- 61 -

[ : Chris Guenther]
Chemical Looping

- Chemical Looping Combustion Technology

[ : Ranjani Siriwardane]
CO Capture Sorbent
2

- CO2 Sorbent and Reactors

[

: George Richards]

7 (CO

hydrate,

Chemical looping, Solid sorbent, CTL, Gasifier, CO2 membrane, H2

separation)
2 KIER-NETL 2010
KIER-NETL : Carnegie-Mellon, Penn
State , Univ of Pittsburgh

- 62 -

CFE
, APP CFE

APP , , APP CFE
, APP CFE

- ICC-CAS(Institute of Coal Chemistry, Chinese Academy of Science)

Synfuel China
. .
-

Shenhua /
. CEO

, .
NI CE(National

I nstitute

of

Clean-and-Low-Carb on

Energy)

()
-
.
- .

ICC-CAS
. ICC-CAS
- 63 -

 , --
,
scale-up .
NICE (PNNL )
,
.
, ,
-
.

- 64 -