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Date: 15.08.

13
REPEATERS TEST [1]
Main Level
Batch: Repeater-14
ANSWERKEY
PHYSICS
1 (B) 2 (C) 3 (A) 4 (A) 5 (C)
6 (C) 7 (C) 8 (A) 9 (D) 10 (A)
11 (C) 12 (B) 13 (A) 14 (B) 15 (A)
16 (C) 17 (D) 18 (C) 19 (D) 20 (C)
21 (B) 22 (B) 23 (A) 24 (A) 25 (B)
26 (A) 27 (A) 28 (A) 29 (C) 30 (A)
CHEMISTRY
31 (B) 32 (D) 33 (D) 34 (D) 35 (A)
36 (A) 37 (C) 38 (D) 39 (A) 40 (C)
41 (B) 42 (B) 43 (B) 44 (C) 45 (A)
46 (B) 47 (B) 48 (C) 49 (B) 50 (B)
51 (C) 52 (C) 53 (A) 54 (B) 55 (A)
56 (C) 57 (A) 58 (B) 59 (D) 60 (A)
MATHEMATICS
61 (A) 62 (A) 63 (C) 64 (A) 65 (A)
66 (A) 67 (B) 68 (C) 69 (A) 70 (B)
71 (D) 72 (B) 73 (A) 74 (C) 75 (C)
76 (A) 77 (A) 78 (B) 79 (D) 80 (C)
81 (B) 82 (A) 83 (B) 84 (D) 85 (A)
86 (A) 87 (B) 88 (B) 89 (B) 90 (D)
RAO IIT Academy _Repeaters Test [1] MAIN_SOLUTION [2]
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2
PART-A: PHYSICS [ SOLUTION]
= = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = =
1. (B)
Sol:
|
u
Equation perpendicular to incline
1
sin( )
cos

=
u
t
g
2
sin( )
cos

=
u
t
g
2. (C)
Sol: (V t) graph
t
2
v
1
v
v
2
t
1
t
from graph
1 2
< t t
3. (A)
Sol: For same range
1 2
2

+ =
If
1
0 =
2
2

=
where
1
and
2

are angle of projection with horizontal.


4. (A)
Sol:
2
20 = x t t
20 2 =
dx
t
dt
10sec = t
Distance moved in 15 sec.
= Distance moved in 10 sec + Distance moved in next 5 second.
100 25 +
= 125
average speed =
125
8.33
15
=
RAO IIT Academy _Repeaters Test [1] MAIN_SOLUTION [3]
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3
5. (C)
Sol: Basic theory
6. (C)
Sol:
u
u
A
u
O
2
2
t
u
V
A
B
A
V cos 2 ucos
2
t | |
u = u
|
\ .
A
u
V
2sin
=
u
7. (C)
Sol: Distance
5 15 30 50 = + + =
average speed =
50
2.5
20
=
8. (A)
Sol: Basic theory
9. (D)
Sol: Basic theory
10. (A)
v
u
L

min
=
L
t
v
11. (C)
Sol: Relative acceleration is zero straight line
12. (B)
Sol: When distance is max relative velocity is zero.
( )
2
2

+
u v
L
a
is max distance
13. (A)
Sol: Relative velocity is zero
( ) O v u at =
v u
t
a

=
RAO IIT Academy _Repeaters Test [1] MAIN_SOLUTION [4]
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4
14. (B)
Sol: Basic theory
15. (A)
Sol:
u
3
5
4

3
sin 37
5
= =
16. (C)
Sol:
relative
v 5m/ sec. =
17. (D)
Sol:
2 2
V u 2gh = +
Independent of angle of projection.
18. (C)
Sol:
u
a
net
a
t
a
r
19. (D)
Sol:
R 2 Displacement
time
R
2v

=

2 2V

=
A
B
R 2

R
2
t
v

=
20. (C)
Sol:
2
V V 2 2 2V
t R
R
2V


A
= =
A

21. (B)
Sol:
x
1 2
1 2
1 2
2x 2u u
v
x x
u u
u u
= =
+
+
RAO IIT Academy _Repeaters Test [1] MAIN_SOLUTION [5]
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5
22. (B)
Sol:
2 2 2
u sin u sin 2
2g g

=
tan 4 =
23. (A)
Sol:
8
12
40
A
1
A
2
20
1
2
A 160
A 40
=
=
1 2
A A
average velocity
12

=
160 40 120
10sec.
12 12

= =
24. (A)
Sol:
1 2
A A 200 50
12 12 3
+
= =
25. (B)
Sol:
,
+ +
uvt uvt
u v u v
u
v
L
(ut,0)
(0, ) vt
+
=
+ +
u o uvt uvt
u v u v
2 2
( )
uvt uv
l
u v t u v
= =
+ +
26. (A)
27. (A)
Sol: of (26, 27)
V
0
t
1
t
2
T
v
t
1 2
+ = t t T
0 0
+ =
V V
T
a b
.....(1)
RAO IIT Academy _Repeaters Test [1] MAIN_SOLUTION [6]
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6
0 0
0 0
1
2
(
= = +
(

V V
L TV V
a b
2
0
1 1
2
(
+ =
(

V
L
a b
0
2Lab
V
a b
=
+
Putting
0
V in equation (1)
Value of T is calculated.
28. (A)
Sol:
o
V
u
u
cos cos = u V
29. (C)
Sol:
u
u
g
u cos
30. (A)
Sol:
u
u
RAO IIT Academy _Repeaters Test [1] MAIN_SOLUTION [7]
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7
PART-B: CHEMISTRY [SOLUTION]
= = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = =
31. (B)
2 3 3 2
CaCl 2AgNO 2AgCl Ca(NO ) + +

4.31
n
143.5
=
moles of
2
4.31 1
CaCl 0.015
143.5 2
= =
32. (D)
Sol: The screening effect of electron will be in the order s > p > d > f
33. (D)
3 2 2 2
CaCO 2HCl CaCl CO H O + + +
25 0.75
n
1000

=
Moles of
3
CaCO required =
25 0.75 1
1000 2


Mass of
3
25 0.75 1
CaCO 100 0.9375gm
1000 2

= =
34. (D)
Sol: Experimental fact.
35. (A)
Sol.:
2
NO
OH
(Density)
Due to high ionic character of nitrobenzene.
36. (A)
Experimental fact.
37. (C)
2 2 2 2
4HCl MnO MnCl Cl 2H O + + +

5
n
87
=
Moles of HCl reacted
5
4 0.05747
87
= =
Mass of HCl 0.05747 36.5 8.4gm = =
RAO IIT Academy _Repeaters Test [1] MAIN_SOLUTION [8]
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8
38. (D)
Sol: Isoelectrionic species contain same number of electrons.
39. (A)
I
2
+ 2Cl
2

ICl + ICl
3
254 gm 142 gm 1 : 1
25.4 gm 14.2 gm 0.1 : 0.1
but Cl
2
given is only 12.2 gm (less than normal ratio hence limiting reagent)
14.2 gm Cl
2
produces

0.1moles of each
12.2 gm

=
0.1
12.2 0.086
14.2
=
mole of each
hence molar ratio remain equal (1 : 1)
40. (C)
Sol: Completely filled and half filled p-subshells are more stable than d-subshells
41. (B)
42. (B)
Sol.:
Na
1
3 3 2 2
Acidic
CH C C H CH C C Na H
+
+ |
H H
Acidic
Na

Na
1
2 2
H + |
Aromatic
1) Na
3 3 2) R OH
No acidic ' H'
CH C C CH

C = C
CH
3
CH
3 H
H
No acidic H
Na
No rea
n
.
43. (B)
Sol: 1s
2
2s
2
2p
6
3s
1
the second ionisation energy will be very high for this electronic
configuration as it involves removal of the electron from s
2
p
6
stable electronic configuration.
RAO IIT Academy _Repeaters Test [1] MAIN_SOLUTION [9]
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9
44. (C)
45. (A)
2Fe + 3H
2
O

Fe
2
O
3
+ 3H
2
54 gm H
2
O(g) convert 112 gm Fe to its oxide
189 m


112
18 37.3
54
gm =
46. (B)
Sol: From the electronic configuration s
2
p
1
unipositive ion with configuration s
2
is readily formed.
47. (B)
ClO

+ Cr
2
OX

Cl
-
+ Cr
2
O
7
2-
2(6-x) +6 2
no. of eq. of ClO
-
= no. of eq. of Cr
2
OX
0.15 2 =
12.6
2(6 )
(104 16 )
x
x

+
or 31.2 + 4.8 x = 151.2 25.2 x
x = 4
hence formula = Cr
2
O
4
or CrO
2
48. (C)
Sol.: , , , , *
*
(3 isomers)
49. (B)
Let the number of sulphate ions in FeSO
4
be x
The number of Fe
2+
will be = number of sulphate = x
The number of sulphate ions in Fe
2
(SO
4
)
3
= x
The number of Fe
3+
per SO
4
2-
= 2/3
The number of Fe
3+
for x SO
4
2-
= 2/3 x
Ratio = x : 2/3 x = 3 : 2
Hence ans is B
50. (B)
Mass of nitrogen given = 7 g
Mass of nitrogen reacted = 80% of 7 g = 5.6 g
N
2
+ 3/2 O
2

N
2
O
3
28 g N
2
reacts with 48 g O
2
to give N
2
O
3
5.6 g of N
2
will react with
48
5.6
28

g of O
2
RAO IIT Academy _Repeaters Test [1] MAIN_SOLUTION [10]
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10
16 g O
2
has 6.022 10
23
atoms
48
5.6
28

g of O
2
has
23
6.022 10 48
5.6
16 28

atoms of O
2
= 3.6 10
23
atoms
Hence the answer is B
51. (C)
Sol.: Electrophilicity
1
stability of C
+
o
S.O. of given C
+
is
O
:
:
>
> >
E
+
order is
O
>>>
(i) (iv) (iii) (ii)
52. (C)
10L
vol. at STP = 11.6gm

22.4L vol. =
11.6 22.4
10

M.W = 26
EF = CH, MF=
2 2
C H
53. (A)
Sol.: (A)
O
NH
2
is highly polar than
O
OH
(B) is highly polar than
(C)
O
O
+
>
O
> ( C
O
bond length)
RAO IIT Academy _Repeaters Test [1] MAIN_SOLUTION [11]
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11
54. (B)
(A) 2 gm atom of nitrogen = 28 gm
(B) 6 10
23
atoms of C has mass = 12 gm
3 10
23
atoms of C has mass =
23
23
12 3 10
6
6 10

=

gm
(C) 1 mole of S has mass = 32 gm
(D) 7.0 gm of Ag
So, lowest mass = 6 gm of C.
55. (A)
56. (C)
Sol: Chain having 4 C atoms and NH
2
group
57. (A)
concept of solubillity
58. (B)
Sol: Among Na, Mg, K and Ca, Mg is the smallest metal atom which requires radiation of highest frequency
to cause emission of electrons.
59. (D)
60. (A)
RAO IIT Academy _Repeaters Test [1] MAIN_SOLUTION [12]
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12
PART-C: MATHEMATICS [SOLUTION]
= = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = =
61. (A)
We must have
2 2
2 0, 2 3 0, 3 8 0 a a a a a + > + > + + >
(since these are sides)
The common solution is ( ) 0,
We must also have
2 2
2 2 3 3 8 a a a a a + + + > + +
2 2
2 3 8 2 3 a a a a a + + + + > +
2 2
3 8 2 3 2 a a a a a + + + + > +
(Sum of two sides must be greater than the third). The common solution is easily found to be
( ) 5,
62. (A)
63. (C)
( )
1
sin15 cos15 . 2sin15 cos15
2
=

1
. sin30
2
=
;
1 1
.
2 2
=
;
1
4
=
64. (A)
2 2 2 2
2 4 2sin 4cos 2 4 x x + s + s +

2 5 2sin 4cos 2 5 x x s + s
; so max. value of
2sin 4cos 3 2 5 3 x x + + = +
65. (A)
max. value of
2 2 2
4sin 3cos sin 3 x x x + = +
is 4
hold at
2
x
t
=
and max. value of
sin cos
2 2
x x
+
is
2
at
2
x
t
=
so combining above two results
max value of
2 2
4sin 3cos sin cos
2 2
x x
x x + + +
is
4 2 +
[

Both hold at
2
x
t
=
]
66. (A)
cotA cotB cotC > 0
there are two possible case,

A,B,C 0,
2
| |
e
|
\ .
or two angle are greater than

2
(it is not possible in a triangle)
so, In a triangle

A,B,C 0,
2
| |
e
|
\ .
hence cotA, cotB, cotC > 0
cotA.cotB.cotC > 0
67. (B)
If A =
2 4
sin cos u + u
A =
( ) + u
u
+
2
1 cos2
1 cos2
2 4
RAO IIT Academy _Repeaters Test [1] MAIN_SOLUTION [13]
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13
A = ( )
2
1
2 2cos2 1 cos 2 2cos2
4
u + + u + u
=
2
3 cos 2
4
+ u
=
3
1
4
A s s
68. (C)
( ) ( )
2
2 2 2 2
3 sin cos sin 2 6 sin cos sin2 x x x x x x + + + + +
( )( )
2 2 4 4 2 2
4 sin cos sin cos sin cos x x x x x x + +
( ) ( ) ( )
2
2 2
3 1 sin 2 6 1 sin 2 4 1 3sin cos x x x x + + +

2 2
3 3sin 2 6sin2 6 6sin2 4 3sin 2 x x x x + + + +
= 13
69. (A)
2
2
1 tan
2sec 2
1 tan
+ u
u =
u
=
1
1
n
n
+

rational number
70. (B)
tan
a
A
b
=
tan
b
B
a
=

= +
2 2 2
c a b

A
B
C
a
b
c
B
tan tan
a b
A B
b a
+ = +
=
2 2 2
a b c
ab ab
+
=
71. (D)
( ) ( ) , , o | e t t , as cos( ) 1 o | =
2 2 t < o | < t, o | = 2nt
so o | = 0, o = |
Now,
1
cos( )
e
o + | =

1
cos2
e
o =
so, there are four sets, as two in [0,
2t
) & two in (
2 t
,0]
72. (B)
2
12sin 9sin u u
( )
2
4 9sin 12sin 4 u u +
=
( )
2
4 3sin 2 u
max. value is 4.
73. (A)

5cos 3 cos .cos sin .sin 3
3 3
t t | |
u + u u +
|
\ .

13 3 3
cos sin 3
2 2
u u +

13 3 3
7 3 cos sin 3 7 3
2 2
+ s u u + s +
i.e 4 to 10
RAO IIT Academy _Repeaters Test [1] MAIN_SOLUTION [14]
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14
74. (C)
3 1
3 sin cos 2 sin cos
2 2
x x x x
| |
+ = +
|
|
\ .
=
2sin
6
x
t | |
+
|
\ .
max. at
3
x
t
=
. i.e 60
75. (C)
sin12 sin48 sin54
= { }
1
sin12 sin48 sin54
2

= { }
1
cos36 cos60 sin54
2

=
1 1
cos36 sin54 sin54
2 2


`
)
= { }
1
2cos36 sin54 sin54
4

= { }
1
sin90 sin18 sin54
4
+
=
1 5 1 5 1
1
4 4 4

+
+
`

)
= { }
+
1 1
4 5 1 5 1
4 4
=
1
8
76. (A)
Using
2 2 2 2
cos sin a b a b a b + s + s +
77. (A)
Use 2sinA sinB = cos (A-B)- cos(A+B)
78. (B)
tan sec
x
e u + u =

1 sin
cos
x
e
+ u
=
u

cos sin
2 2
cos sin
2 2
x
e
u u
+
=
u u

(using componendo & Dividendo rule)



1
tan
2 1
x
x
e
e
u
=
+
as
2
2
1 tan
2
cos
1 tan
2
u

u =
u
+

2
cos
x x
e e

u =
+
79. (D)
( )
2
2
tan cot 4 A A + =
2 2
tan cot 14 A A + =
80. (C)
here sinx =
2
cos x
81. (B)
2 4
cos cos
3 3
x y z
t t
= =

2 2
y z
x k

= = =
(let)
so, ( )( ) ( ) ( 2 ) 2 2 2 xy yz zx k k k k k k + + = + + = 0
82. (A)

0
1 57
c
>
RAO IIT Academy _Repeaters Test [1] MAIN_SOLUTION [15]
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15
83. (B)
180 A B C + + =
then ( )( )( ) cot cot cot cot cot cot B C C A A B + + +

( ) ( ) ( )
2 2 2
sin sin sin
sin .sin sin
B C C A A B
A B C
+ + +
cosec A cosecB cosecC
( ) sin sin A B C + = (

84. (D)
1
sin cos
5
x x + =
3
2 4
x
t t | |
< <
|
\ .
24
sin2
25
x =

24
tan2
7
x =
as
2x
is in III
rd
quadrent.
85. (A)
Based on formula
sin(A+B) = sinA cosB + cosA sinB
86. (A)
cos2

+ cos

= 2 cos
2

+cos

1
Min. Value
(1 4.2( 1) 9
4.2 8

=

minimum value of ax
2
+ bx + c = 0 is
4
D
a

, when a > 0.
87. (B)
Sqaure both the sides
88. (B)
cot

2 cot 2

=
cos 2cos2
sin sin2

=
sin2 .cos 2cos2 . sin
sin sin2

=
sin(2 ) cos2 sin
sin .sin2

=
{ }
2
sin 1 1 2sin
sin .2sin cos


+
=
tan
89. (B)
A+2B =
2

90. (D)
( )
2 2
sec 1 tan ( ) x y x y = +
=
tan tan
1
1 tan . tan
x y
x y
| |
+
|
+
\ .
{ minimum value of tan cot 2 x y n + >
s

( )
2
1
1
tan cot
n
x y
| |
+
|
+
\ .
s

( )
2
1
1
4
n
n

+
s

( )
2
1
4
n
n
+

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