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Ecuacin de Redlich Kwong

La ecuacin de Redlich-Kwong para un gas es:


=

Donde P es la presin (atm), V es el volumen molar (L/mol), T es la temperatura (K) y


R=0.082054atm.L/mol.K.
Hallar el volumen molar del CO2 A 500K Y 10atm, utilizando el mtodo de Newton Raphson.
a=3.592L2.atm/mol2.k1/2
b=0.04267L/mol

Solucin:
UTILIZANDO EL METODO DE NEWTON RAPHSON
() = ( +

() = ( +

+ =

()
()

( +
+ =

( +

Volumen inicial:
.
(. . )

=
=
= .

Si: K=0
.
. .
) . +

.
. . . (. . + .
)

. . . (. . + .
=

= . /
K=1
= . /

K=2
= . /
= | | <
= |. . | <
= . <
Por lo tanto el volumen molar es:
= . /

Solucin utilizando Matlab:


>> a=inline('(10*x^3)-(41.027*x^2)-1.608190255*x+6.8544714*10^(-3)')

a=

Inline function:
a(x) = (10*x^3)-(41.027*x^2)-1.608190255*x+6.8544714*10^(-3)
>> Vm=fzero(a,4.1027,optimset('disp','iter','tolx',1e-6))

Search for an interval around 4.1027 containing a sign change:

Func-count a

f(a)

f(b)

4.1027

-6.59107

4.1027

3.98666

-24.8475

4.21874

Procedure
-6.59107 initial interval
13.8752 search

Search for a zero in the interval [3.98666, 4.21874]:


Func-count x

f(x)

Procedure

4.21874

13.8752

initial

4.13558

-1.02027

interpolation

4.14128 -0.0370336

interpolation

4.14149 6.5788e-06

interpolation

4.14149 6.5788e-06

interpolation

Zero found in the interval [3.98666, 4.21874]

Vm =

4.141491263055221

>>