Problema 9.

10

x fraccin mol de Calor int. De sol. y fraccin mol en

Capacidad
Acetona en el
A 15C (kJ/kmol
equilibrio de
Temperatura
calorfica a 17.2
lquido
sol)
acetona en vapor vapor lquido C C (kJ/kg sol C)
0.001
0
0.000
100.0
4.187
0.01
0.253
91.7
4.179
0.02
-188.4
0.425
86.6
4.162
0.05
-447.3
0.624
75.7
4.124
0.10
-668.7
0.755
66.6
4.020
0.15
-770
0.798
63.4
3.894
0.20
-786
0.815
62.2
3.810
0.30
-719
0.830
61.0
3.559
0.40
-509
0.839
60.4
3.350
0.50
-350.1
0.849
60.0
3.140
0.60
-252.6
0.859
59.5
2.931
0.70
0.874
58.9
2.763
0.80
0.898
58.2
2.554
0.90
0.935
57.5
2.387
0.95
0.963
57.0
2.303
1.00
1.000
56.5

t ( C)
Capacidad
calorfica acetona
(kJ/kg C)
Calor latente de
evaporacin (kJ/kg)

20.0

37.8

65.6

93.3

2.22

2.26

2.34

2.43

1013

976

917

863

Calor int. de sol. a 15 C (kJ/kmol

sol)

Calor Integral de solucion a 15C

0
-100 0
-200
-300
-400
-500
-600
-700
-800
-900

0.5

Series1

x fraccin mol de Acetona en el lquido

1.000

1.5

y Fraccin mol de acetona en vapor

1.000
0.900
0.800
0.700
0.600
0.500
0.400
0.300
0.200
0.100
0.000
0

0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9

1
Curva equilibrio

x fraccion molar de acetona en liq

Diagonal

Q'
xD

95462
0.9687

Q''
xw

-9744
0.000406

ENTALPIA COMPOSICION
x

CL (kJ/kg C)

Mav
1
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0.05
0.01
0.002
0

58.05
54.05
50.04
46.04
42.04
38.04
34.03
30.03
26.03
22.02
20.02
18.42
18.10
18.02

Hs (J/kmol)
2258
2389
2554
2763
2931
3140
3350
3559
3810
4020
4124
4179
4182
4182

0
-44194
-100018
-172124
-252600
-350100
-509000
-719000
-186000
-668700
-447300
-93040
0
0

tL ( C)
56.5
57.5
58.2
58.9
59.5
60.0
60.4
61.0
62.2
66.6
75.7
91.7
100.0
100.0

Calor latente A
Calor latente B
(kJ/kg)
(kJ/kg)
519.9
518.7
2364.0
516.4
2358.8
511.7
2349.3
504.7
2335.5
498.9
2323.0
495.4
2314.6
491.9
2306.2
488.5
2297.6
485.0
2290.6
479.2
2274.6
473.2
2258.5
473.3
2258.5
472.2
2251.0

tG ( C)
1
0.92
0.85
0.79
0.72
0.65
0.59
0.53
0.46
0.39
0.21
0.03
0.01
0

56.5
57.8
60.0
63.9
69.6
74.4
77.8
81.1
84.4
87.2
93.3
99.4
99.4
100.0

x vrs. HL

Entalpa composicin

y vrs. HG
Series3

120000

Series4

100000
80000

60000
40000
20000
0
0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

-20000
x, y

Curvas de operacin:
Rectificacin

Agotamiento

y
0.9687

x
0.9687

HG (kJ/kmol)
35728
36632
37479
38296
39288
40206
40964
41694
42497
43246
45088
46817
46983
46976

y
0.12

0.48

0.85
0.69
0.48
0.27
0.12

0.89
0.79
0.67
0.55
0.48

0.09
0.06
0.04
0.02
0.005

0.36
0.26
0.14
0.08
0.025

Diagonal
45 grados
y=x
0.001
0.01
0.02
0.05
0.1
0.15
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
0.95
1

100.0

850

15.0

56.9

2.20

2.32035841

HL (kJ/kmol)
5440
5443
5421
5412
5230
5024
4667
4197
4494
3900
4565
5811
6434
6406

Entalpa composicin
120000

100000

80000

60000

40000

20000

0
0

0.1

0.2

0.3

0.4

0.5

-20000
x, y

1.000

0.900

y Fraccin mol de acetona en vapor

0.800

0.700

0.600

0.500

y Fraccin mol de acetona en vapo

0.500

0.400

0.300

0.200

0.100

0.000
0

0.1

0.2

0.3

0.4

0.5

x fraccion molar de acetona en liq

x vrs. HL

composicin

y vrs. HG
Series3
Series4

0.6

0.7

0.8

0.9

ar de acetona en liq

0.6

0.7

0.8

0.9

Curva equilibrio
Diagonal
Rectificacin
Agotamiento

1.000

0.900

y Fraccin mol de acetona en vapor

0.800

xD / R+1

0.700

0.600

0.500

0.400

0.300

0.200

0.100

0.000
0

0.1

0.2

0.3

0.4

0.5

x fraccion molar de acetona en liq

xW
xD
R
xD / R+1

0.9687
1.8
0.34596429

q
pendiente
x

1.08
13.99
y

0.0937
0.1137

0.0937
0.3793

xF

0.6

0.7

0.8

0.9

Curva equilibrio

ar de acetona en liq

Diagonal
q

xD