A=

1.213

B= 0.0289

C=

-0.000008824

Cp= R[A+(B/2)*(To)*(J+1)+(C/3)*(To^2)*(J^2+J+1)+D/(J*To^2)

1.213 A
28.7966 (B/2)*(To)*(J+1)
-9.45502 (C/3)*(To^2)*(J^2+J+1)
0 D/(J*To^2)
20.5546
170.891

A=

-0.747

[A+(B/2)*(To)*(J+1)+(C/3)*(To^2)*(J^2+J+1)+D/(J*To^2)]
Cp

B= 0.06796

C=

Q= n*R [(A)*(To)*(J-1)+(B/2)*(To^2)*(J

-49.302 (A)*(To)*(J-1)
1489.81 (B/2)*(To^2)*(J^2-1)
-275.99 (C/3)*(T0^3)*(J^3-1)
345.862 n*R

1164.52 [(A)*(To)*(J-1)+(B/2)*(To^2)*(

402762 Q= n*R [(A)*(To)*(J-1)+(B/2)*

D=

To= 523.15

R=

8.314

T1= 1473.2

J=

J^2+J+1)+D/(J*To^2)]

J^2+J+1)+D/(J*To^2)]

Q=n*Cp(T1-To)

-0.00003778

D=

To=

299.15

T1=

365.15

J-1)+(B/2)*(To^2)*(J^2-1)+(C/3)*(T0^3)*(J^3-1)]

^2)*(J^2-1)

^3)*(J^3-1)

*(J-1)+(B/2)*(To^2)*(J^2-1)+(C/3)*(T0^3)*(J^3-1)]

(A)*(To)*(J-1)+(B/2)*(To^2)*(J^2-1)+(C/3)*(T0^3)*(J^3-1)]

R=

8.314

J=T/To

Q=

7000

n=

n=

41.6

2.81592

T=To+Q/n*Cp
523.15

To

7000

Q
n*Cp

2050.692

Q/n*Cp

3.413482

T=To+Q/n*Cp

526.5635

Q=n*Cp(T1-To)
n*Cp
2050.692
Q=n*Cp(T1-To)
1948158

J=T/To
J= 1.22063

Cp= Q/n(T1-To)
Q

402762

n*(T1-To)

2745.6

Cp=

146.694

12

A=

n:

Cp:

0.25

43.167

n*CP:
n*CP:
n*CP:
n*CP:
Cpm:

To=

298.15

T=

360.15

n:
B=

10.79175
10.32605
35.7144
0
56.8322

A=

-0.747

B= 0.06796

n*R

5.32948718

A*(T-To)
(B/2)*(T-To)

-46.314
1386.88011

(C/3)*(T-To)

-254.520968

D*(T-To)/T*To

Q=

0.35

0
5788.063648

Cp:
29.503

C=

C=

-0.00003778

D=

n:

Cp:

0.4

89.286

n= 0.64103

D=

n=m/Pm
n=

n:

Cp:

PM de A=

32

n=

0.2

MT=

100

nT=MT/(yM + yM + y
nT= 3.546099

0.64103

m=

50

Pm=

78

R= 8.314

PM de B=

28

PM de C=

26

PM de D=

28

n=

0.4

n=

0.3

n=

0.1

T/(yM + yM + yM + yM)

nT= 3.5460993

Cpm=

56.8322

To=
T=

QT=nT*Cpm*(To-T)
QT=

34260.5

To=

362.2

Q=

-5900

T=To*(Q/(n*Cp))
T= 298.999

n=

303.15
473.15

0.64103

Cp=

145.63

P=
V=
n=
T=
R=

14.696 psia
250 ft/s

n=(P*V)/(R*T)
0.588323838

0.588324 lb-mol/s
582 R
10.73

Comprobacion:

ft*psia/lb-mol*R

PV=nRT
PV

3674

nRT

3674

Van der Waals

(P+(a/V))*(V-b)=RT
a=27RTcr/64Pcr
b=RTcr/8Pcr

Calculos para a
R=
Tcr=
Pcr=

Calculos para b
83.14 cm*bar/mol*K
369.8 k
42.48 bar

a=27RTcr/64Pcr
a=
9387568.87 cm/mol

R=
Tcr=
Pcr=

83.14 cm*bar/mol*K
369.8 k
42.48 bar

b=RTcr/8Pcr
b=
90.4695504 cm/mol

R=
83.14 cm*bar/mol*K P=((R*T)/(V-b))-(a/V)
T=
323.15 K
V= 1638.2313
P=
13.860553
a= 9387568.87
b= 90.4695504
P= 13.860553 bar

comprobacion:
(P+(a/V))*(V-b)=RT

(P+(a/V))*(V-b)
26866.691

RT
26866.691

Ecuacion virial
[P+((a*T)/(V*(V-b)))]*(V-b)=(R*T)
Tc=

282.3

Pc=

50.4

bar

R=

83.14

cm*bar/mol*k

V=((R*T)/P)+B

B=

-140

cm/mol

V=

C=

7200

cm/mol

T=

298.15

P=

12

bar

a) Virial muy truncada

1925.682583

V=((R*T)/P)
V=

2065.682583

Z=V/V
Z=

0.932225793

V=Z*V
V=

1925.682583

Ecuacion de estado cubica generica

P=((R*T)/(V-b))-(((T))/(V+b)*(V+b))

Peng/Robinson

[P+((T))/(V+b)*(V+b)]*(

W=
0.345
Tc=
647.1
Pc=
220.55
T=
523.15
P=
18
=
0.0778
=
0.45724
= 2.414213562
= -0.414213562
Zc=
0.3074

Tr=T/TC
Tr=

0.808453098

Pr=P/Pc
Pr=

0.081614146

Soave/Redlich/kwong
W=

0.152

Tr=T/Tc

Tc=

369.8

Tr=

Pc=

42.48

T=

323.15

P=

17.16

0.08664

0.42748

Zc=
R=

0.8738507

Pr=P/Pc
Pr=

0.4039548

b=*(R*Tc/Pc)
b=

62.706255

B=(b*P)/(R*T)
83.14

B=

0.0400511

Tr= 0.8738507
Pr= 0.4039548
b= 62.706255

(Tr)=Tr^-
(Tr)=

1.0697477

B=

0.0400511

q=

6.0400631

(T)=(*(Tr)*R*Tc)/Pc

(Tr)=

1.0697477

(T)=

(T)=

10175752

V=

1565.658

Z=

0.7503141

V=

1174.7352

Z=

0.0731263

Z=1+B-qB*(Z-B)/(Z+B)*(Z+B)

V=

114.49084

Z=

10175752

q=(T)/(b*R*T)
q=

6.0400631

0.750314081
0.750313804

Z=B+(Z+B)*(Z+B)*((1+B-z)/(q*B))
Z=

0.073126338
0.073119137

Correlaciones generalizadas para gases:

Pitzer
R=
V=
T=
P=
Pm=
W=
Tc=
Pc=
Tr=
Pr=
B=
B=
Z=
V=
V=
V=

83.14
323.15
115
28.054
0.087
282.3
50.4
1.14470422
2.28174603
-0.2569407
0.0414973
0.49503481
233.6234
115.651716
4.12246796

Tr=T/Tc
Tr=

1.14470422

Pr=P/Pc
Pr=

2.28174603

B=0.083-(0.422/Tr^1.6)
B=
-0.2569407
B=0.139-(0.172/Tr^4.2)
B=
0.0414973
Z=1+B(Pr/Tr)+wB(Pr/Tr)
Z=
0.49503481
V=(R*T)/P
V=

233.6234

V=Z*V
V=

115.651716

V=V/Pm
V=

4.12246796

Correlacciones generalizadas para liquidos:

Rackett
V=
Pm=
w=
Tc=
Pc=

280000
44.097
0.152
369.8
8

Tr=T/Tc
Tr=

0.86533261

V=(Vc*(Zc^(1-Tr)^(2/7)))

Zc=
Vc=
T=
Tr=
V=
V=
m=

0.276
200
320
0.86533261
96.7714386
2.19451297
127590.952

V=

96.7714386

V=V/Pm
V=

2.19451297

m=V/V
m=

127590.952

Redlich/Kwong
[P+(a(T))/(V*(V-b))]*(V-b)=R*T

Redlich/kwong
W=

0.2

Tc=

425.1

Pc=

37.96

T=

350

P=

9.4573

0.08664

0.42748

Tr=T/Tc
Tr=
Pr=P/Pc
Pr=
q=(/)*Tr^-3/2
q=

Tr= 0.82333569

=*(Pr/Tr)

Pr= 0.24913857

q=

6.6043784

= 0.02621697

Z=1+B-qB*(Z-B)/Z*(Z+B)

R=

Z=

83.14

Z= 0.83048968
V=

2555.3191

Z= 0.04331205

V=ZRT/P
V=

V= 133.266079
Z=B+Z(Z+B)*((1+B-Z)/qB)
Z=

V=ZRT/P
V=

Gases ideales PV=RT

P=
V=
n=
T=
R=

14.6954
250

P=(n*R*T)/(V)
14.69540455

0.5883
582

Comprobacion:

10.73

PV=nRT
PV

3673.851138

R=
P=
V=
a=
b=
T=

83.14
15
1638.231298
9387568.869
90.46955038
344.3623232

T=((P+(a/V))*(V-b))/R
T=
344.36232

nRT

3673.851138

R=
P=
V=
a=
b=
T=

comprobacion:
(P+(a/V))*(V-b)=RT
(P+(a/V))*(V-b)
28630.28355

RT
28630.28355

b) Virial truncada
V=((R*T)/P)
V=

Real

2065.682583

Ideal

V=((R*T)/P)(1+(B/V)+(C/V))
V=

1919.021765

Real

1919.021765

Ideal

Z=V/V
Z=

Z=1+(B/Vo)
Z=

Z=1+(B/V)+(C/V)
0.92900128

Z=

1919.021765

Real

0.932225793

V=Z*V
V=
Real

+((T))/(V+b)*(V+b)]*(V-b)=RT

0.92900128

V=(R*T)/P
1565.658 cm/mol

V=
V=Z*V

114.4908 cm/mol

V=
V=Z*V

1174.735 cm/mol

V=

R*Tc)/Pc

B)/(Z+B)*(Z+B)
0.750314081
0.750313804

Se empieza con Z=1

Z=

Z+B)*((1+B-z)/(q*B))
0.073126338
0.073119137

Se empieza con Z=B

Z=

0.040051

a gases:
Lee/Kesler
R=
T=
Tc=
P=
Pc=
Z=
Z=
w=
Tr=
Pr=
Z=
V=
V=
Pm=
V=
V=
m=

wB(Pr/Tr)

cm/mol

cm/g

quidos:

Tr)^(2/7)))

83.14
320
369.8
16
42.48
0.35554
-0.05409
0.152
0.8653326
0.3766478
0.3473183
1662.8
577.5209
44.097
13.096603
70000
5344.8975

Tr=T/Tc
Tr=

0.865333

Pr=P/Pc
Pr=

0.376648

Z=Z+wZ
Z=

0.347318

V=(R*T)/P
V=

1662.8

V=Z*V
V=

577.5209

V=V/Pm
V=

13.0966

m=V/V
m=

5344.897

cm/mol

cm/g

0.823336

0.249139

/)*Tr^-3/2
6.604378

*(Pr/Tr)
0.02621697

1+B-qB*(Z-B)/Z*(Z+B)
0.830489683
0.830489676
2555.3191

B+Z(Z+B)*((1+B-Z)/qB)
0.04331205
0.043312

133.266079

Z=1
Z=B

V=RT

P=
V=
n=
T=
R=
3673.851138

14.6954
250.0001

V=(n*R*T)/P
250.0000774

0.5883
582

Comprobacion:

10.73

PV=nRT
PV

3673.851138

Volumen Vapor
83.14
15
1638.2313
9387568.9
90.46955
323.15

R=((P+(a/V))*(V-b))/T
R=
88.597504

R=
P=
V=
a=
b=
T=

83.14
15
1486.087703
9387568.9
90.46955
323.15

comprobacion:
(P+(a/V))*(V-b)=RT
(P+(a/V))*(V-b)
28630.28355

1919.021765

RT
26866.691

(P+(a/V))*(V-b)
26866.67828

cm/mol

cm/mol

cm/g

P=
V=
n=
T=
R=

=(n*R*T)/P
250.0000774

omprobacion:

14.6954
250
0.5883
581.9998
10.73

nRT

3673.851138

3673.85

olumen Vapor
bar
1486.087703

V=(R*T/P)+b
V=
1881.5823
V=((R*T)/(P+(a/V))+b
1486.087703

cm/mol

R=
P=
V=
a=
b=

T=
comprobacion:
1486.086109
(P+(a/V))*(V-b)=RT
(P+(a/V))*(V-b)
26866.67828

RT
26866.691

P=
V=
n=
T=
R=

T=(P*V)/(n*R)
581.9998197
Comprobacion:
PV=nRT
PV

3673.85

14.6954
250
0.5883
582
10.73

nRT

3673.85

83.14
15
9387568.9
90.46955

A=
1
B= -1881.582284
C= 625837.9246
D= -56619275.65

Raiz Cubica
A=
B=
C=
D=

323.15
Ax+Bx+Cx+D=0

R=(P*V)/(n*T)
10.72999668
Comprobacion:
PV=nRT
PV

3673.85

Raiz Cubica
1
-12.3454731
85.5369891
-383.991346

nRT

3673.85

Conversiones de temperaturas
F=32+1.8(C)
F=

C=

F=

68

F=

68

C=

20

20

R=F+460
528

K=C+273.15
K=

20

68

C=(1/1.8)*(F-32)

R=

C=

293.15