d

a
G
e
n
e
r
a
l
i
z
a
d
e
s
i
b
i
l
i
d
a
d

G
d
e

C
o
m
p
r
e
C
a
r
t
a

d
Cengel,Yunus A.;Boles,MichaelA.Termodinmica.Ed.McGrawHill.CuartaEdicin.2001.pp.765
d
a
G
e
n
e
r
a
l
i
z
a
r
e
s
i
b
i
l
i
d
a
d

d
e

C
o
m
p
r
C
a
r
t
a
R.C.Reid,J.M.Prausnitz,B.E.Poling.Thepropertiesofgasesandliquids.Ed.McGrawHill.2001.pp.3132
Mtodos para Estimar Z MtodosparaEstimarZ
Ecuacin de OttGoatesHall: EcuacindeOtt Goates Hall:
Z = 1 +
P
r
17 - I
r
- _1 -
7.S
I
r
2
_
17 I
r
_
I
r
_
J.BevanOtt,J.Rex Goates,H.TracyHall.Journal OfChemical Education.Vol.48(8),pp.515,1971.
Mtodos para Estimar Z MtodosparaEstimarZ
Ecuacin Virial: Mtodo de VanNess Abbott EcuacinVirial:MtododeVan NessAbbott
Z = 1 +
B - P
R - I

R - I
B - Pc
R - Ic
= B
(u)
+ - B
(1)

R - Ic
B
(u)
= u.u8S -
u.442
I
1.6
B
(1)
= u.1S9 -
u.172
I
r
4.2

I
r
I
r
B:TieneUnidadesdevolumenespecfico
Mtodoapropiadoparamolculasnopolares.
R.C.Reid,J.M.Prausnitz,T.K.Sherwood.Thepropertiesofgasesandliquids.Ed.McGrawHill.2001.pp.40
J.MSmith,J.M.,VanNess,H.C.,Abbott,M.A.IntroductiontoChemicalEngineeringThermodynamics.Ed.McGraw
Hill.2007.
Z
(0)
Mtododetresparmetros:LeeandKesler
Z = Z
(u)
+ - Z
(1)

Z
R.C.Reid,J.M.Prausnitz,T.K.Sherwood.Thepropertiesofgasesandliquids.Ed.McGrawHill.2001.pp.3639
Z
(1)
Mtododetresparmetros:LeeandKesler
Z = Z
(u)
+ - Z
(1)

R.C.Reid,J.M.Prausnitz,T.K.Sherwood.Thepropertiesofgasesandliquids.Ed.McGrawHill.2001.pp.3639
Z =
R I
0 b
-
o
0
2
+ u b 0 + w b
2

EXPRESIONGENERALIZADAPARAECUACIONESCUBICASDEESTADO
0 -b 0
2
+ u b 0 + w b
2
Z
S
- (1 +B
-
-u B
-2
) Z
2
+ (A
-
+w B
-2
-u B
-
- u B
-2
) Z
-A
-
B
-
-w B
-2
-w B
-S
= u
A
-
=
o P
R
2
I
2
; B
-
=
b P
R I

EOS u w b a EOS u w b a

VDW
(1873)
0 0
R I
C
8 P
C

27
64
R
2
I
C
2
P
C


2 2 S
RK
(1949)
1 0
u.u8664 R I
C
P
C

u.42748 R
2
I
C
2.S
P
C
I
1
2
,


SRK
u.u8664 R I
C
u.42748 R
2
I
C
2
_1 + _1 - I
1
2
__
2
SRK
(1972)
1 0
C
P
C
P
C
_1 +

_1 - I
r
__

= u.48 + 1.S74 - u.176

2

PR
2 1
u.u778u R I
C
u.4S724 R
2
I
C
2
P
_1 +

_1 - I
r
1
2
__
2
(1976)
2 1
P
C
P
C
_

_
r
__

= u.S7464 +1.S4226 - u.26992

2
R.C.Reid,J.M.Prausnitz,T.K.Sherwood.Thepropertiesofgasesandliquids.Ed.McGrawHill.2001.pp4243

R I
ECUACINMODIFICADADERACKETT
0

=
R I
C
P
C
Z
RA
|1+(1-I
r
)
27
]

Z
RA
= u.29uS6 - u.u87S
R.C.Reid,J.M.Prausnitz,T.K.Sherwood.Thepropertiesofgasesandliquids.Ed.McGrawHill.2001.pp.67