1998 5

57

MDEA
730060

MDEA ,
PRO/
,

MDEA
,
,

,
,

,
,

,
MD EA
, ,
,

1 MDEA
MD EA 1
75 CO2 ,
MD EA CO2 ( 1 )

,
MD EA ( )
, 80
, MD EA
[ 16 ] ,

, ( 2)
, ( 2 ) CO2
800pp m ( 1 )
( 3) ,
( 4) ,

, MD EA
,

( 7) ,
MDEA (4) MDEA

1 MDEA
1. 2. 3. 4. 5. 6. 7.
8. 9. 10. 11. 12. 13. /
14. 151 / 161


1998 5
58
( 6 ) 0. 045M Pa ( G) ,
( 5 ) ,
(6 ) MD EA : 3/ 4
MD EA ( 10 ) ( 8 )
6615 , ; 1/ 4

MD EA ( 15 )
, MD EA ( ) ( 15 )

SIMSCI , PRO2
V ISION

, 40 ,

( 1)

411 , PRO/

1
1
, %(v) ( )
kmol/ h ()
,

, OL I1 S YSTEM
,

[ 8 ] SIMSCI OL I

H2

N2

Ar

CO

CO 2

CH4

54. 19 26. 43 0. 34
7442. 2
75

0. 38 17. 16 1. 50
kmol/ h () 7545. 8

,MPa ( G)

2. 8

MD EA 37 % MD EA 3 %
; CO 2 :
116Nm3 / t 2612Nm3 / t

5315 ; 6615
( 2)
: 2. 78M Pa ( G) , ;
0. 09M Pa ( G) , ;

:0. 045M Pa ( G) ,

3 MDEA

AMINE
( 1)
MD EA CO 2
( CO2 + H2 O = H + + HCO3- ) , 25

kOH = 104l/ kg - mol ,s ,

, MD EA
,
, ,
( RESI) ,
RESI 1 , 2
, (

2. 78M Pa ( G) , RESI = 110 )

,CO2 ,
RESI

SIM ISCI

MD EA :
311 PRO/ AMINE
AM IN E [ 7 ]
H2 S CO2 H2 O M EA D EA D GA D IPA
MD EA K ;
K SR KM MD EA D GA ,

K
, RESI 0. 3
110 , RESI = 1. 0

MD EA CO2

H2
N2
Ar
CO
CO 2
CH4

,kmol/ h ( )
,kmol/ h
,kmol/ h ( )
kg/ h

Nm3/ h 10 3 ( )
,
,MPa ( G)

13

,V %

65. 33
31. 91
0. 41
0. 46
0. 08
1. 81
100. 00
6152. 5
35. 1
6187. 6
67540
10. 92
138. 69
75
2. 8

64. 33
31. 42
0. 40
0. 45
1. 60
1. 79
100. 00
6193. 3
53. 2
6246. 5
66229
10. 88
136. 44
75
2. 8

:
0. 69 6. 9M Pa ( G) ; < 185 ;
MD EA 50 % ( )

3. 78M Pa ( G) ,RESI = 1. 0 ,

312 PROVISION

,CO2

1998 5
59

, RESI
,
3. 78M Pa ( G) ,

, ,

, ,
,
,
,
, PRO ( )

, CO2 9911 %

MD EA
3

3 ( 3. 78MPa )

14

13

,k2mol/ h

,k2mol/ h

,V %

,V %

H2
N 2

0. 00

1 10 - 14

0. 00

3 10 - 11

0. 25

0. 66

65. 33

65. 35

0. 00

2 10

- 15

0. 00

7 10 - 12

0. 04

0. 20

31. 91

31. 94

Ar
CO
CO 2
CH4

0. 00

4 10 - 14

0. 00

1 10 - 13

0. 41

0. 416

0. 00

8 10 - 15

0. 00

2 10 - 14

0. 46

0. 454

2. 3

25

1161

1004

99. 70

99. 10

0. 08

0. 02

0. 00

1 10 - 14

0. 00

4 10 - 14

0. 01

0. 04

1. 81

1. 82

40

41

38

38
100. 00

100. 00

100. 00

100. 00

1272. 8

1402. 5

6152. 5

6087. 3

MDEA

,kmol/ h ( )
,kmol/ h
,kmol/ h ( )

11350

11511

31305

31632

437. 4

317. 5

35. 10

20. 82

12523

12727

35628

35802

1710. 2

1720. 0

6187. 6

6066. 5

kg/ h

342500

352000

99200

991248

63750

67000

67540

66229

27. 35

27. 66

27. 84

27. 69

37. 28

38. 95

10. 92

10. 88

38. 33

38. 55

138. 69

136. 44

Nm3/ h 10 3 ( )

,
,MPa ( G)

53. 5

53. 5

77. 0

70. 0

55. 0

53. 5

3. 8

3. 9

0. 045

0. 045

2. 78

3. 78

( 2)

( 3) CO2

MD EA

4 CO2 ( RESI = 1. 0)

MD EA

, CO2 ,

MPa ( G)

15

CO 2 ,mol/ h

,mol/ h

CO2

1. 5

71. 8

74. 5

434. 2407

6685. 64

2. 0

71

76. 8

281. 9467

6485. 23

2. 2

70. 4

77. 7

230. 0310

6417. 53

2. 4

69. 6

78. 4

181. 8185

6354. 74

2. 6

68. 5

79. 1

137. 3115

6296. 47

2. 8

67

79. 7

95. 4409

6241. 25

,MD EA M EA
( 103 Mj/ h) :
MD EA

M EA

3. 0

3. 2

T,

3. 3

65. 31 56. 10

234. 38

,
, ,


,

3. 4

53. 5

81. 5

0. 5156

6101. 07

3. 5

5315

81. 5

0. 5010

6097. 38

3. 8

5315

81. 5

0. 4619

6086. 55

4 :
3. 0 3. 3M Pa ( G) ,
PRO/ IN PU T , ,


1998 5
60
CO2 ,

MD EA CO2 ,
, CO2
, ,
, 15
,MD EA CO2 CO2
,
CO2 , 314
315
318M Pa ( G) , CO 2
, 1
:
( 4) MD EA CO2
5 MDEA
CO2
MDEA , %

,P13

CO 2

P23
CO 2
%

33

31

2. 40

77. 9

7. 26 10

- 3

80. 5

35

33

1. 90

78. 5

7. 34 10 - 3

80. 8

38

36

1. 59

79. 1

7. 49 10 - 3

81. 2

40

38

1. 51

79. 4

7. 63 10 - 3

81. 5

45

43

1. 63

79. 9

8. 07 10 - 3

82. 1

50

48

2. 09

80. 1

8. 70 10 - 3

82. 8

; P1 = 2. 78MPa ( G) ; P2 = 3. 78MPa ( G)

( 2. 78M Pa) MD EA
40 % , BASF ;
3. 78M Pa ( G) ,MD EA
, CO2
,

412 PROVISION
, PROV ISION
MD EA CO2 ,

RESI = 1. 0
6
6 , CO2
, 0108 0197
; ,
,
,
MD EA

13

,V %

H2
N 2
Ar
CO
CO 2
CH4

,kmol/ h ( )
,kmol/ h
,kmol/ h ( )
kg/ h

Nm3/ h 10 3 ( )
,
,MPa ( G)

65. 33
31. 91
0. 41
0. 46
0. 08
1. 81
100100
6152. 5
35. 1
6187. 6
67540
10. 92
138. 69
75
2. 8

64. 33
31. 42
0. 40
0. 45
1. 60
1. 79
100 100
6193. 3
53. 2
6246. 5
66229
10. 88
136. 44
75
2. 8

64. 62
31. 78
0. 40
0. 45
0. 97
1. 78
100100
6151. 1
212. 0
6363. 1
72638
11. 42
142. 5
75
2. 8

5
( 1) PRO/ CO2

( 2) PRO/
, MD EA CO2
,
( 3) PRO RESI
, , CO 2
MD EA
( 4) MD EA CO2

(5) , ,
MD EA
, PRO ( )

, M E2
DA

1 1 ,1991 ( 1) :40
2 1 ,1992 ( 4) :12
3 , 1 ,1994 ( 1) :55
4 , 1 ,1992 ( 6) :39
5 1 ,1995 ( 6) :55
6 , 1 ,1996 ( 4) :310
7 PRO ( ) Input manual , Simulation Sciences Inc. , 1994
8 PRO ( ) Electrolyte user s guide , Simulation Sciences
Inc. , 1994
( 1998 - 01 - 05)

1998 5
3
tion such as t he techniques of conventional feedback
cont rol wit h const raint cont rol , feedforward con2
t rol and composition cont rol etc. .
Key Words et hylene distillation tower ad2
vanced cont rol
Theory and Appl ication of Regionology
Li Yuqiang
( Huanqi u Chem ical Engi neeri ng Corporation
of Chi na , Beiji ng 100029)

The aut hor describes t he t heoretic point s and

t heir application of regionology. As one of t he f un2
damental t heory of Overall Engineering Philoso2
p hy , t he Regionology st udies t he reasonable engi2
neering allocation. Indudst rial regionology has been
applied in t he research of indust rial region plan2
ning , plant site selection and plant allocations etc.
Key Words Overall Engineering Philosop hy
Regionology t heory application
Technology and Appl ication Prospect f or
Liquef ied Gas Blended with Air

Ma Dinghua
( Chem ical Design Instit ute of Hunan
Provi nce , Changsha 410007)

This paper describes t he running problem and

correction met hods for enclosed purification flow by
diluted acid washing , and compared it wit h t he
water washing purification flow , to provide a new
approach for sulf uric acid process design.
Key Words diluted acid washing enclosed
purification flow design summarization
Development and Application of TDC23000
DCS for Electric Furnace of Yellow Phosphorus Unit
Gong Youming
( Chem ical Design Instit ute of
Y unnan Provi nce , Kunm i ng 650041)

This paper int roduces t he hardware set2up and

software configuration of TDC2300 DCS as well as
it s successf ul application for 80 MW elect ric f ur2
nace in yellow p hosp horus unit .
Key Words DCS yellow p hosp horus unit
elect ric f urnace develop ment application

You Zuying
( Pet rochem ical Design Instit ute

On Project Managers Responsibil itis and Roles

of Fujian Provi nce , Fuz hou 350001)

Xu Mian

The aut hor describes t he technical feat ures , air

blending met hod , flow diagram , equip ment and
cont rol system for mixt ure producing by liquefied
gas blended wit h air , it highlight s t he st ruct ure
and performance of t he air blending equip ment un2
der high pressure proportion.
Key Words liquefied gas blended air gas
mixture air blending under high pressure proportion

( Chengda Chem ical Engi neeri ng Corporation

of Chi na , Chengdu 610041)

The aut hor describes t he necessary responsibili2

ties and roles for a project manager , and int roduces
t he major work items to which t he project manager
should pay more attentions and t he practice experi2
ence of t he aut hor himself .
Key Words project manager project planning
quality cont rol , schedule cont rol and cost cont rol

Discussion on Plot Plan of Small L PG Station

Liu Linying
( Pet rochem ical Planni ng Design Instit ute
of Hebei Provi nce , S hijiaz huang 050051)

Take t he design of small L P G station as an ex2

ample , compared wit h t he relevant design codes of
China and of foreign count ries , t he aut hor proposes
t hat t he fire distance limitation in t he plot plan
should be adjusted to reduce t he land occupation
and engineering cost .
Key Words L P G station plot plan fire distance
Design f or Enclosed
Purif ication Flow by Diluted Acid Washing

Discussion on Simulation of
MD EA CO2 Removal System
Tang Hongqing Tang Jinwen
( L anz hou Design Instit ute of Chi na N ational
Pet rochem ical Corporation , L anz hou 730060)

Make simulated calculation for M EDA CO2 re2

moval system by using PRO/ amine and elec2
t rolyte module and make comparison wit h design
figures and state t ruly t he problems encountered in
running t he system wit h different software.
Key Words M EDA CO2 removal system
simulated calculation
( T ransl ated by He Tianton g )