Slurres 40

SLURREX 40
CALCULO DE LOS PRAMETROS DE EXPLOSION Y DET
a)
BALANCE DE OXIGENO
- BALANCE DE ECUACION
b)
CALCULO DE PARAMETROS DE DETONACION

- cuadro de resumen
c)
CALCULO DE PARAMETROS DE EXPLOSION :

- cuadro de resumen2
EX 40
S DE EXPLOSION Y DETONACION
S DE DETONACION :
S DE EXPLOSION :
BALANCE DE OXIGENO
DATOS
AN (NH4NO3)
H2O
AL
FO (CH2)
TNT (C7H5O6N3)
(NH4NO3)
H2O
Al
AL
FO
atomo gr/Kg = 1000 x N de atomos x %

PM
%
%
%
%
COMPOSICIN
N2 H 4
O3
H2
O1
INGREDIENTES
AN
81
12
5
1
1
C1
H2
C7 N3 H 5
(CH2)
TNT (C7H5O6N3)
O6
DENSIDAD 1,15 g/cc

BALANCE DE OXIGENO =
PM
C.
80.04
18.02
27
14.03
227.12
81
12
5
1
1
100
0
0
0.7128
0.3082
1.021
4.7415
O - 2C-1/2H - 3/2AL =
CORRECCION DEL BALANCE DE OXIGENO

COMPOSICIN
N2 H 4
O3
H2
O1
INGREDIENTES
AN
(NH4NO3)
H2O
Al
AL
FO
C1
H2
C7 N3 H 5
(CH2)
TNT (C7H5O6N3)
O6
PM
80.04
18.02
27
14.03
227.12
A
B
5
1
1
C.
DENSIDAD 1,15 g/cc

BALANCE DE OXIGENO =
Variables:
O - 2C - 1/2H - 3/2AL
A y B
( 0.264 + 0.375 A + 0.555 B )-( 2 (
0.1249 A
1.021 ))-( 0.5 (
-0.00005 B
1.6456 +
-5.37845
0.1249 A -0.00005 B
0.4998 A+ 1.1099
5.37845
1A
1B
93
SOLUCIN DEL SISTEMA DE ECUACIONES CON DOS INCG

PARA HALLAR A y B USAMOS MATRICES
A
5.37845
-0.00005
93
0.1249
1
-0.00005
1
0.1249
5.37845
93
0.1249
1
-0.00005
1
5.3831
0.12495
= 43.0820328
6.23725
0.12495
= 49.9179672
SUMATORIA DE TODOS LOS PORCENTAJES

=
5 %+
1%
1%
= 43.082 % + 49.92 % +
5%+
1%
1%
100
E OXIGENO
1000 x N de atomos x %
PM
C.
Al
40.4798
30.3598
20.2399
13.3185
6.6593
1.8519
0.7128
1.4255
0.3082
0.2201
0.2642
0.1321
1.021
55.4439
37.2833
20.372
1.8519
Al
4.7415
GENO
C.
-
A 0.4998 A 0.3748 A 0.2499
B 1.1099 B 0.5549
1.8519
0.7128
1.4255
0.3082
0.2201
0.2642
0.1321
1.1099 B )-( 2 ( 1.852 )) = 0
NES CON DOS INCGNITAS
BALANCE DE ECUACIN
Ingredientes
AN (NH4NO3)
H2O
AL
FO (CH2)
TNT (C7H5O6N3)
DENSIDAD
PM
80.04
18.02
27
14.03
227.12
1.15
%
43%
50%
5%
1.00%
1.00%
gr/cc
N DE MOLES =
% x 1000
PM
ECUACION DE LA REACCION QUIMICA:

C7H
N3 O
+ N2 H
+ C1 H
PARA
AN
+ H
+ AL
C1 O
43%
x
1000
80.04
5.38256
H2O =
+ N2 + H
+ AL
50%
x
1000
18.02
27.7026
1.00%
x
1000
14.03
0.7128
PARA
=
5%
x
1000
14.03
3.56379
1.00%
x
1000
227.12
0.04403
FO =
PARA
TNT
PARA
PARA
AL
HALLANDO COEFICIENTES DEL PRODUCTO:
PARA N
= 5.38255872 x 2 =
0.04402959 x 3 =
S
S/2
10.76511744
0.132088764
10.8972062
5.448603102
PARA C
0.04402959 x 7 =
0.71275837 x 1 =
S
S/1=
PARA H
= 0.04402959
5.38255872
0.71275837
27.7025527
0.220147939
21.53023488
1.42551675
55.40510544
78.58100501
39.29050251
PARA O1
0.04402959 x 6 =
5.38255872 x 3 =
27.7025527 x 1 =
S
PARA O2
x
x
x
x
5
4
2
2
=
=
=
=
S
S/2
= 1.02096549 x 2 =
39.2905025 x 1 =
S
2.04193098
39.29050251
41.33243349
(O1 - O2)
(O1 - O2)
O
AL
CALOR DE FORMACION DEL REACTANTE (QR)

TNT
AN
FO
H2O
AL
:
:
:
:
:
0.04402959
5.38256
0.71275837
27.7025527
1.85464862
mol/kg
mol/kg
mol/kg
mol/kg
mol/kg
x
x
x
x
x
-13
-87.3
-7
-68.4
0
=
=
=
=
=
S =
kcal/mol
kcal/mol
kcal/mol
kcal/mol
kcal/mol
-0.57238464
-469.897376
-4.98930862
-1894.85461
0
kcal/kg
kcal/kg
kcal/kg
kcal/kg
kcal/kg
-2370.31368
kcal/kg
CALOR DE FORMACION DEL PRODUCTO (QP)

CO2
1.02096549
mol/kg x
-94.1
kcal/mol = -96.0728526
kcal/kg
=
=
=
=
0.30820712
0.71275837
1.02096549
1.02096549
0.264177527
16.14767616
27.70255272
44.11440641
44.11440641 41.33243349
2.781972923
0.927324308
1.854648615
N2
H2O
AL2O3
:
:
:
5.4486031
39.2905025
0.92732431
mol/kg x
mol/kg x
mol/kg x
0
-57.8
-392
kcal/mol =
0
kcal/mol = -2270.99104
kcal/mol = -363.511129
kcal/kg
kcal/kg
kcal/kg
= -2730.57503
kcal/kg
CALOR LIBERADO POR LA REACCION

Qe = Qp - Qr
Qe = -360.2614 kcal/kg
.264177527
6.14767616
7.70255272
4.11440641
1.33243349
CALCULO DE PARAMETROS D
DETONACIN
V2 = V1 { O.72 + 0.1 (1 -0.9)
ASUMIMOS UNA T (2000 - 6000)

DENSIDAD =
1.15
gr/cc
V1 =
d1
= 0.86957 cc/gr
1
1.15
V 2 = 0.86956522 ( 0.72 +
V2 =
4400
0.1
1.15 -
0.9 ))
0.64783 cc/gr
PRIMERA PRUEBA
INTERPOLANDO
IDEAL CV - GAS
T K
N2
4000
CO2
7.002
13.368
500
0.046
4500
7.048
T ASUMIDA = 4400
N2
CAPACIDAD DE CALOR IDEAL (Cv)

:
:
:
1.02096549
5.448603102
39.29050251
13.488
500
400
0.046
X
X=
CO2
N2
H2O
0.12
mol/kg
mol/kg
mol/kg
x
x
x
500
400
0.0368
=
X=
7.0388
CO2 =
0.12
X
0.096
13.464
T = 4400 K
13.464
7.0388
11.4138
cal/mol.k
cal/mol.k
cal/mol.k
SmiCv
=
=
=
=
13.7462794
38.3516275
448.453937
500.551844
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
SmiCv = 0.50055184
CAPACIDAD DE CALOR IDEAL
CV )
INTERPOLANDO
IDEAL CV - SOLIDO -GAS
T K
N2
4000
CO2
6.415
12.039
500
0.073
4500
T ASUMIDA = 4400
12.204
500
400
X=
0.073
X
:
:
:
:
1.02096549
5.448603102
39.29050251
0.927324308
mol/kg
mol/kg
mol/kg
mol/kg
x
x
x
x
1.02096549 +
45.7600711 +
0.92732431 =
(Sni)(R)+ (SniCv)
(SniCv)
=
=
=
=
=
=
12.171
12.426171
35.2709873
384.339696
25.9650806
458.001934
0.45800193
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
N DE MOLES
45.7600711
N DE MOLES
46.68739541
CALCULO DE COEFICIENTE DE COMPRESIBILIDAD (b 1)

=
0.132
CO2 =
5.4486031 + 39.2905025 =
CALCULO DE LAS Sni (GAS + SOLIDO)

Smi gas- solido =
cal/mol.k
cal/mol.k
cal/mol.k
cal/mol.k
SmiCv
SmiCv
=
0.165
X
X=
6.4734
12.171
6.4734
9.782
28
CALCULO DE LAS Sni (GAS)

Sni
500
400
0.0584
N2 =
b1
0.165
6.488
CO2
N2
H2O
AL2O3
kcal/kg.k
da/dv
mol/kg
0.64783
V2
0.6667
R=
0.00198
Kcal/mol-K
0.625
b1
= ( 45.76007 )(
0.00198
)+(
0.500551844
b1
0.607431748
0.500552 ) -
0.573578
0.0417
0.01887
da/dv
da/dv
CALCULO DE (b2)
b2
(V2 - a)
0.64783
V2
( V1 - V2 )
0.6667
0.625
b2
b2
0.647826
0.526137
0.86956522 -
0.64783
0.0417
0.01887
0.548792495
a
a
CALCULO DE bpromedio
bpromedio =
b1 + b2
2
0.607432 + 0.548792
2
= 0.578112122
CALCULO DE (V2)
V2 =
V1 (bpromedio) + a
1 + bpromedio
V2 = 0.86956522 ( 0.57811212
1 +
0.578112122
0.651945762
V2 =
CALCULO DE LA T2
T2
(Q2 + T1(SmiCV)) bpromedio

bpromedio(SmiCV) - 0,5(R)(Smi)gas-solido
T2
= (
360.26135 +
0.57811212 (
T2
1313
298
0.458001934
0.458001934 ))
)- 0.5 (
0.578112122
0.00198
) X 46.6873954
T2(ASUMIDA)
1313
4400
2856
RESUMEN:
N DE
PRUEBA
V2
ESTIMADA
b1
b2
0.64783
0.60743
0.54879
t2 k
t2 k
(Asumida) (Calculada)
4400
1313
SEGUNDA PRUEBA
DATOS
DENSIDAD
=
V 1 = 0.869565
T2
asumida
V2
1.15
cc/gr
gr/cc
2856
0.651945762
cc/gr
INTERPOLANDO
IDEAL CV - GAS
T K
N2
2500
CO2
6.772
500
0.102
3000
T ASUMIDA = 2856
12.83
0.235
6.874
13.065
500
0.102
500
0.235
356
356
X = 0.072624
X = 0.16732
N2
CO2 = 12.99732
= 6.844624
T =
2856
CO2
N2
H2O
:
:
:
1.02096549
5.448603102
39.29050251
mol/kg
mol/kg
mol/kg
x
x
x
12.99732
6.844624
10.82261
cal/mol.k
cal/mol.k
cal/mol.k
SmiCv
SmiCv
CAPACIDAD DE CALOR IDEAL PROMEDIO

INTERPOLANDO
2500
CO2
6.082
11.293
500
0.137
3000
2856
1.02096549
5.448603102
39.29050251
0.927324308
mol/kg
mol/kg
mol/kg
mol/kg
Sni
0.137
500
0.307
356
356
x
x
x
x
X = 0.097544
X = 0.218584
N2
CO2 = 11.51158
= 6.179544
11.51158
6.179544
8.932968
28
1.02096549 +
45.7600711 +
cal/mol.k
cal/mol.k
cal/mol.k
cal/mol.k
SmiCv
SmiCv
=
0.92732431 =
(Sni)(R)+ (SniCv)
da/dv
11.75293
33.6698826
350.980802
25.9650806
422.368695
0.4223687
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
N DE MOLES
45.7600711
N DE MOLES
46.68739541

=
=
=
=
=
=
=
5.4486031 + 39.2905025 =

Sni gas- solido
11.6
500
CALCULO DE LAS Sni (GASEOSO)
b1
0.307
6.219
:
:
:
:
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
( CV )
N2
T ASUMIDA =
13.2698152
37.2936396
425.225707
475.789161
0.47578916
T K
CO2
N2
H2O
AL2O3
=
=
=
=
=
mol/kg
V
= 0.65194576
V2
(SniCv)
0.6667
0.625
b1
= ( 45.76007 )(
0.00198
)+(
0.475789 ) -
0.570615
0.475789161
b1
0.0417
0.01475
0.619816303
da/dv
da/dv
CALCULO DE (b2)
b2
(V2 - a)
0.65195
V2
( V1 - V2 )
0.6667
0.625
b2
b2
0.651946
0.528508
0.86956522 -
0.65195
0.0417
0.01475
0.567216792
a
a
bpromedio =
b1 + b2
2
0.619816 + 0.567217
2
= 0.593516548
CALCULO DE (V2)
V2 =
V1 (bpromedio) + a
1 + bpromedio
V2 = 0.86956522 ( 0.59351655
1 +
0.593516548
V2 =
CALCULO DE LA T2
0.655537402
T2
T2
= (
360.26135 +
0.59351655 (
T2
1411
T2(ASUMIDA)
298
0.422368695
0.422368695 ))
)- 0.5 (
0.593516548
0.00198
) X 46.6873954
K
=
1411
2856
2133
RESUMEN:
N DE
PRUEBA
V2
ESTIMADA
b1
b2
0.65195
0.61982
0.56722
t2 k
t2 k
2856
1411
TERCERA PRUEBA
DATOS
DENSIDAD
=
V 1 = 0.869565
T2 asumida
V2
=
=
1.15
cc/gr
gr/cc
2133
0.655537402
cc/gr
INTERPOLANDO
T K
IDEAL CV - GAS
N2
2000
6.615
500
2500
CO2
12.515
0.157
6.772
0.315
12.83
T ASUMIDA = 2133
500
0.157
500
0.315
133
133
X = 0.041762
X = 0.08379
N2
CO2 = 12.59879
= 6.656762

CO2
N2
H2O
:
:
:
1.02096549
5.448603102
39.29050251
mol/kg
mol/kg
mol/kg
x
x
x
T =
12.59879
6.656762
10.16624
2133
cal/mol.k
cal/mol.k
cal/mol.k
SmiCv
SmiCv
CAPACIDAD DE CALOR IDEAL PROMEDIO
INTERPOLANDO
k
=
=
=
=
=
CV )
N2
2000
CO2
5.9
500
10.884
0.182
2500
0.409
6.082
T ASUMIDA = 2133
11.293
500
0.182
500
0.409
133
133
X = 0.048412
X = 0.108794
N2 = 5.948412
:
:
:
:
1.02096549
5.448603102
39.29050251
0.927324308
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
T K
CO2
N2
H2O
AL2O3
12.8629298
36.2700541
399.436521
448.569505
0.4485695
mol/kg
mol/kg
mol/kg
mol/kg
x
x
x
x
10.99279
5.948412
8.297808
28
cal/mol.k
cal/mol.k
cal/mol.k
cal/mol.k
SmiCv
SmiCv
CO2 = 10.99279
=
=
=
=
=
=
11.2232633
32.4105361
326.025046
25.9650806
395.623926
0.39562393
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
CALCULO DE LAS Smi (GASEOSO)

Sni
1.02096549 +
5.4486031 + 39.2905025 =
CALCULO DE LAS Smi (GAS + SOLIDO)

Sni gas- solido
45.7600711 +
N DE MOLES
0.92732431 =
N DE MOLES
46.68739541

b1
(Sni)(R)+ (SniCv)
(SniCv)
45.7600711
mol/kg
da/dv
0.6555374
V2
0.6667
0.625
b1
b1
= ( 45.76007 )(
0.00198 )+(
0.448569505
0.44857 ) -
0.568031
0.0417
0.01116
0.633955757
da/dv
da/dv
CALCULO DE (b2)
b2
(V2 - a)
0.65554
V2
( V1 - V2 )
0.6667
0.625
b2
b2
0.655537
0.530575
0.86956522 -
0.65554
0.0417
0.01116
0.583858311
a
a
bpromedio =
b1 + b2
2
0.633956 + 0.583858
2
= 0.608907034
CALCULO DE (V2)
V2 =
V1 (bpromedio) + a
1 + bpromedio
V2 = 0.86956522 ( 0.60890703
1 +
0.608907034
V2 =
0.658869554
CALCULO DE LA T2
T2
(Q2 + T1(SniCV)) bpromedio
bpromedio(SmiCV) - 0,5(R)(Sni)gas-solido
T2
= (
360.26135 +
0.60890703 (
T2
1495
T2(ASUMIDA)
298
0.395623926
0.395623926 ))
)- 0.5 (
0.608907034
0.00198
) X 46.6873954
K
=
1495
2133
1814
RESUMEN:
N DE
PRUEBA
V2
ESTIMADA
b1
b2
0.65554
0.63396
0.58386
CUARTA PRUEBA
DATOS
DENSIDAD
=
V 1 = 0.869565
T2 asumida
V2
=
=
1.15
cc/gr
gr/cc
1814
0.658869554
cc/gr
t2 k
t2 k
2133
1495
INTERPOLANDO
IDEAL CV - GAS
T K
N2
1500
CO2
6.343
500
12.001
0.272
2000
0.514
6.615
T ASUMIDA = 1814
12.515
500
0.272
500
0.514
314
314
X = 0.170816
X = 0.322792
N2 = 6.513816

CO2
N2
H2O
:
:
:
1.02096549
5.448603102
39.29050251
mol/kg
mol/kg
mol/kg
T =
x
x
x
12.32379
6.513816
9.695872
cal/mol.k
cal/mol.k
cal/mol.k
SmiCv
SmiCv
=
=
=
=
=
12.5821663
35.4911981
380.955683
429.029048
0.42902905
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
N2
1500
CO2
5.653
500
2000
( CV )
INTERPOLANDO
T K
1814
CO2 = 12.32379
10.302
0.247
5.9
0.582
10.884
T ASUMIDA = 1814
500
0.247
500
0.582
314
314
X = 0.155116
X = 0.365496
N2 = 5.808116
CO2
N2
H2O
AL2O3
:
:
:
:
1.02096549
5.448603102
39.29050251
0.927324308
mol/kg
mol/kg
mol/kg
mol/kg
x
x
x
x
10.6675
5.808116
7.943312
28

Sni
1.02096549 +
45.7600711 +
=
=
=
=
=
=
0.92732431 =
(Sni)(R)+ (SniCv)
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
45.7600711
N DE MOLES
46.68739541

b1
10.8911453
31.6461189
312.09672
25.9650806
380.599065
0.38059906
N DE MOLES
5.4486031 + 39.2905025 =

Sni gas- solido
cal/mol.k
cal/mol.k
cal/mol.k
cal/mol.k
SmiCv
SmiCv
CO2 = 10.6675
mol/kg
= 0.65886955
da/dv
V2
(SniCv)
0.6667
0.625
b1
= ( 45.76007 )(
0.00198
)+(
0.429029 ) -
0.565633
0.429029048
b1
0.0417
0.00783
0.645552615
da/dv
da/dv
CALCULO DE (b2)
b2
(V2 - a)
( V1 - V2 )
0.65887
V2
0.6667
0.625
b2
b2
0.658870
0.532493
0.86956522 -
0.65887
0.0417
0.00783
0.599804875
a
a
bpromedio =
b1 + b2
2
0.645553 + 0.599805
2
= 0.622678745
CALCULO DE (V2)
V2 =
V1 (bpromedio) + a
1 + bpromedio
V2 = 0.86956522 ( 0.62267874
1 +
0.622678745
V2 =
0.661839597
CALCULO DE LA T2
T2
bpromedio(SniCV) - 0,5(R)(Sni)gas-solido
T2
= (
360.26135 +
0.62267874 (
T2
1546
T2(ASUMIDA)
298
0.380599065
0.380599065 ))
0.622678745
)- 0.5 (
0.00198
1814
) X 46.6873954
K
=
1546
+
2
1680
RESUMEN:
N DE
PRUEBA
V2
ESTIMADA
b1
b2
0.65887
0.64555
0.59980
t2 k
t2 k
1814
1546
QUINTA PRUEBA
DATOS
DENSIDAD
=
V 1 = 0.869565
T2 asumida
V2
=
=
1.15
cc/gr
gr/cc
1680
0.661839597
cc/gr
INTERPOLANDO
IDEAL CV - GAS
T K
N2
1500
CO2
6.343
500
12.001
0.272
2000
0.514
6.615
T ASUMIDA = 1680
12.515
500
0.272
500
0.514
180
180
X = 0.09792
X = 0.18504
N2 = 6.44092

CO2
N2
H2O
:
:
:
1.02096549
5.448603102
39.29050251
mol/kg
mol/kg
mol/kg
T =
x
x
x
12.18604
6.44092
9.46164
1680
CO2 = 12.18604
cal/mol.k
cal/mol.k
cal/mol.k
SmiCv
SmiCv
=
=
=
=
=
12.4415263
35.0940167
371.75259
419.288133
0.41928813
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
CAPACIDAD DE CALOR IDEAL ( CV )

INTERPOLANDO
T K
N2
1500
CO2
5.653
10.302
500
0.247
2000
0.582
5.9
T ASUMIDA = 1680
10.884
500
0.247
500
0.582
180
180
X = 0.08892
X = 0.20952
N2 = 5.74192
CO2
N2
H2O
AL2O3
:
:
:
:
1.02096549
5.448603102
39.29050251
0.927324308
mol/kg
mol/kg
mol/kg
mol/kg
x
x
x
x
10.51152
5.74192
7.78144
28
1.02096549 +
5.4486031 + 39.2905025 =

Sni gas- solido
45.7600711 +
=
=
=
=
=
=
0.92732431 =
(Sni)(R)+ (SniCv)
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
da/dv
45.7600711
N DE MOLES
46.68739541

b1
10.7318992
31.2854431
305.736688
25.9650806
373.719111
0.37371911
= N DE MOLES

Sni
cal/mol.k
cal/mol.k
cal/mol.k
cal/mol.k
SmiCv
SmiCv
CO2 = 10.51152
mol/kg
0.6618396
V2
(SniCv)
0.6667
0.625
b1
= ( 45.76007 )(
0.00198
)+(
0.419288 ) -
0.563497
0.419288133
b1
0.0417
0.00486
0.652595616
da/dv
da/dv
CALCULO DE (b2)
b2
(V2 - a)
( V1 - V2 )
0.66184
V2
0.6667
0.625
b2
b2
0.661840
0.534203
0.86956522 -
0.66184
0.0417
0.00486
0.61444973
a
a
bpromedio =
b1 + b2
2
0.652596 + 0.61445
2
= 0.633522673
CALCULO DE (V2)
V2 =
V1 (bpromedio) + a
1 + bpromedio
V2 = 0.86956522 ( 0.63352267
1 +
0.633522673
V2 =
CALCULO DE LA T2
T2
0.664264993
bpromedio(SniCV) - 0,5(R)(Sni)gas-solido
T2
= (
360.26135 +
0.63352267 (
T2
1568
T2(ASUMIDA)
298
0.373719111 ))
0.373719111
0.633522673
)- 0.5 (
0.00198
1680
) X 46.6873954
K
=
1568
+
2
1624
RESUMEN:
N DE
PRUEBA
V2
ESTIMADA
b1
b2
0.66184
0.65260
0.61445
t2 k
t2 k
1680
1568
SEXTA PRUEBA
DATOS
DENSIDAD
=
V 1 = 0.869565
T2 asumida
V2
=
=
1.15
cc/gr
gr/cc
1624
0.664264993
cc/gr
INTERPOLANDO
IDEAL CV - GAS
T K
N2
1500
CO2
6.343
500
2000
T ASUMIDA = 1624
12.001
0.272
6.615
500
0.514
12.515
0.272
500
0.514
124
124
X = 0.067456
X = 0.127472
N2 = 6.410456

CO2
N2
H2O
:
:
:
1.02096549
5.448603102
39.29050251
mol/kg
mol/kg
mol/kg
x
x
x
T =
1624
12.12847
6.410456
9.363752
CO2 = 12.12847
cal/mol.k
cal/mol.k
cal/mol.k
SmiCv
SmiCv
=
=
=
=
=
N2
1500
CO2
5.653
10.302
500
0.247
2000
0.582
5.9
T ASUMIDA = 1624
10.884
500
0.247
500
0.582
124
124
X = 0.061256
X = 0.144336
N2 = 5.714256
1.02096549
5.448603102
39.29050251
0.927324308
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
T K
:
:
:
:
12.3827514
34.9280304
367.906521
415.217303
0.4152173
( CV )
INTERPOLANDO
CO2
N2
H2O
AL2O3
mol/kg
mol/kg
mol/kg
mol/kg
x
x
x
x
10.44634
5.714256
7.713792
28
cal/mol.k
cal/mol.k
cal/mol.k
cal/mol.k
SmiCv
SmiCv
=
CO2 = 10.44634
=
=
=
=
=
=
10.6653486
31.134713
303.078764
25.9650806
370.843906
0.37084391
N DE MOLES
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
Sni
1.02096549 +
5.4486031 + 39.2905025 =

Sni gas- solido
45.7600711 +
0.92732431 =
45.7600711
N DE MOLES
46.68739541
mol/kg

b1
(Sni)(R)+ (SniCv)
= 0.66426499
da/dv
V2
(SniCv)
0.6667
0.625
b1
= ( 45.76007 )(
0.00198
)+(
0.415217 ) -
0.561752
0.415217303
b1
0.0417
0.00244
0.656459095
da/dv
da/dv
CALCULO DE (b2)
b2
(V2 - a)
0.66426
V2
( V1 - V2 )
0.6667
0.625
b2
b2
0.664265
0.535599
0.86956522 -
0.66426
0.0417
0.00244
0.626723308
a
a
bpromedio =
b1 + b2
0.656459 + 0.626723
= 0.641591201
CLCULO DE (V2)
V2 =
V1 (bpromedio) + a
1 + bpromedio
V2 = 0.86956522 (
1 +
V2 =
0.6415912
0.641591201
0.666124397
CLCULO DE LA T2
T2
T2
= (
360.26135 +
0.6415912 (
T2
1575
T2(ASUMIDA)
298
0.370843906
0.370843906 ))
)- 0.5 (
0.641591201
0.00198
) X 46.6873954
K
=
1575
1624
1599
RESUMEN:
V2
N DE
PRUEBA ESTIMADA
0.66426
6
b1
b2
0.65646
0.62672
SEPTIMA PRUEBA
DATOS
DENSIDAD
=
V 1 = 0.869565
1.15
cc/gr
T2 asumida
V2
1599
0.666124397
cc/gr
=
=
gr/cc
t2 k
t2 k
(Calculada
(Asumida)
)
1624
1575
INTERPOLANDO
IDEAL CV - GAS
T K
N2
1500
6.343
500
12.001
0.272
2000
0.514
6.615
T ASUMIDA = 1599
:
:
:
1.02096549
5.448603102
39.29050251
mol/kg
mol/kg
mol/kg
12.515
500
0.272
500
0.514
99
99
X = 0.053856
X = 0.101772
N2
CO2 = 12.10277

CO2
N2
H2O
CO2
x
x
x
= 6.396856
T =
12.10277
6.396856
9.320052
1599
cal/mol.k
cal/mol.k
cal/mol.k
SmiCv
SmiCv
N2
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
CO2
5.653
500
T ASUMIDA = 1599
12.3565125
34.8539294
366.189526
413.399968
0.41339997
T K
2000
=
=
=
=
=
CV )
INTERPOLANDO
1500
10.302
0.247
5.9
0.582
10.884
500
0.247
500
0.582
99
99
CO2
N2
H2O
AL2O3
:
:
:
:
1.02096549
5.448603102
39.29050251
0.927324308
mol/kg
mol/kg
mol/kg
mol/kg
x
x
x
x
X = 0.048906
X = 0.115236
N2
CO2 = 10.41724
= 5.701906
10.41724
5.701906
7.683592
28

Sni
1.02096549 +
45.7600711 +
0.92732431 =
(Sni)(R)+ (SniCv)
10.6356385
31.0674227
301.892191
25.9650806
369.560333
0.36956033
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
N DE MOLES
45.7600711
N DE MOLES
46.68739541

b1
=
=
=
=
=
=
5.4486031 + 39.2905025 =

Sni gas- solido
cal/mol.k
cal/mol.k
cal/mol.k
cal/mol.k
SmiCv
SmiCv
mol/kg
da/dv
0.6661244
V2
(SniCv)
0.6667
0.625
b1
= ( 45.76007 )(
0.00198
)+(
0.4134 ) -
0.560414
0.413399968
b1
0.0417
0.00058
0.658756066
da/dv
da/dv
CALCULO DE (b2)
b2
(V2 - a)
0.66612
V2
( V1 - V2 )
0.6667
0.625
b2
b2
0.666124
0.536669
0.86956522 -
0.66612
0.0417
0.00058
0.636330896
a
a
bpromedio =
b1 + b2
2
0.658756 + 0.636331
2
= 0.647543481
CLCULO DE (V2)
V2 =
V1 (bpromedio) + a
1 + bpromedio
V2 = 0.86956522 ( 0.64754348
1 +
0.647543481
V2 =
0.667508942
CALCULO DE LA T2
T2
T2
= (
360.26135 +
0.64754348 (
T2
1577
T2(ASUMIDA)
298
0.369560333
0.369560333 ))
)- 0.5 (
0.647543481
0.00198
) X 46.6873954
K
=
1577
1599
1588
RESUMEN:
N DE
PRUEBA
7
V2
ESTIMADA
b1
b2
0.66612
0.65876
0.63633
t2 k
t2 k
(Calculada
(Asumida)
)
1599
1577
OCTAVA PRUEBA
DATOS
DENSIDAD
=
V 1 = 0.869565
T2 asumida
V2
=
=
1.15
cc/gr
gr/cc
1588
0.667508942
cc/gr
INTERPOLANDO
IDEAL CV - GAS
T K
N2
1500
6.343
500
12.001
0.272
2000
0.514
6.615
T ASUMIDA = 1588
:
:
:
1.02096549
5.448603102
39.29050251
mol/kg
mol/kg
mol/kg

INTERPOLANDO
12.515
500
0.272
500
0.514
88
88
X = 0.047872
X = 0.090464
N2 = 6.390872
CO2 = 12.09146

CO2
N2
H2O
CO2
x
x
x
T =
12.09146
6.390872
9.300824
1588
cal/mol.k
cal/mol.k
cal/mol.k
SmiCv
SmiCv
=
=
=
=
=
12.3449675
34.821325
365.434049
412.600341
0.41260034
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
CV )
T K
N2
1500
CO2
5.653
10.302
500
0.247
2000
5.9
T ASUMIDA = 1588
CO2
N2
H2O
AL2O3
0.582
:
:
:
:
1.02096549
5.448603102
39.29050251
0.927324308
mol/kg
mol/kg
mol/kg
mol/kg
10.884
500
0.247
500
0.582
88
88
x
x
x
x
X = 0.043472
X = 0.102432
N2
CO2 = 10.40443
= 5.696472
10.40443
5.696472
7.670304
28

Sni
1.02096549 +
45.7600711 +
= 10.622566
= 31.037815
= 301.370099
= 25.9650806
= 368.99556
= 0.36899556
0.92732431 =
(Sni)(R)+ (SniCv)
45.7600711
N DE MOLES
46.68739541

b1
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
N DE MOLES
5.4486031 + 39.2905025 =

Sni gas- solido
cal/mol.k
cal/mol.k
cal/mol.k
cal/mol.k
SmiCv
SmiCv
da/dv
mol/kg
= 0.66750894
V2
(SniCv)
0.7143
0.6667
b1
= ( 45.76007 )(
0.00198
)+(
0.412600341
b1
0.660104762
0.4126 ) -
0.559490
0.0476
0.04679
da/dv
da/dv
CALCULO DE (b2)
b2
(V2 - a)
0.66751
V2
( V1 - V2 )
0.7143
0.6667
b2
b2
0.667509
0.537408
0.86956522 -
0.66751
0.0476
0.04679
0.643885332
a
a
bpromedio =
b1 + b2
2
0.660105 + 0.643885
2
= 0.651995047
CALCULAR (V2)
V2 =
V1 (bpromedio) + a
1 + bpromedio
V2 = 0.86956522 ( 0.65199505
1 +
0.651995047
V2 =
0.668500845
CALCULO DE LA T2
T2

T2
= (
360.26135 +
0.65199505 (
298
0.36899556
0.36899556
)- 0.5 (
))
0.651995047
0.00198
) X 46.6873954
T2
1577
T2(ASUMIDA)
K
=
1577
1588
1582
RESUMEN:
N DE
PRUEBA
8
V2
ESTIMADA
b1
b2
0.66751
0.66010
0.64389
t2 k
t2 k
(Calculada
(Asumida)
)
1588
1577
NOVENA PRUEBA
DATOS
DENSIDAD
=
V 1 = 0.869565
T2 asumida
V2
=
=
1.15
cc/gr
gr/cc
1582
0.668500845
cc/gr
INTERPOLANDO
IDEAL CV - GAS
T K
N2
1500
CO2
6.343
500
2000
T ASUMIDA = 1582
12.001
0.272
6.615
0.514
12.515
500
0.272
500
0.514
82
82
X = 0.044608
X = 0.084296
N2
CO2 = 12.0853
= 6.387608

CO2
N2
H2O
:
:
:
1.02096549
5.448603102
39.29050251
mol/kg
mol/kg
mol/kg
x
x
x
T =
1582
12.0853
6.387608
9.290336
cal/mol.k
cal/mol.k
cal/mol.k
SmiCv
SmiCv
=
=
=
=
=
T K
N2
1500
CO2
5.653
10.302
500
0.247
2000
0.582
5.9
T ASUMIDA = 1582
10.884
500
0.247
500
0.582
82
82
X = 0.040508
X = 0.095448
N2 = 5.693508
:
:
:
:
1.02096549
5.448603102
39.29050251
0.927324308
mol/kg
mol/kg
mol/kg
mol/kg
x
x
x
x
10.39745
5.693508
7.663056
28

Sni
1.02096549 +
45.7600711 +
cal/mol.k
cal/mol.k
cal/mol.k
cal/mol.k
SmiCv
SmiCv
=
CO2 = 10.39745
=
=
=
=
=
=
0.92732431 =
10.6154356
31.0216654
301.085321
25.9650806
368.687503
0.3686875
N DE MOLES
5.4486031 + 39.2905025 =

Sni gas- solido
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
CV )
INTERPOLANDO
CO2
N2
H2O
AL2O3
12.3386702
34.8035408
365.02197
412.164181
0.41216418
45.7600711
N DE MOLES
46.68739541
mol/kg
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k

b1
(Sni)(R)+ (SniCv)
= 0.66850084
da/dv
V2
(SniCv)
0.7143
0.6667
b1
= ( 45.76007 )(
0.00198
)+(
0.412164 ) -
0.558865
0.412164181
b1
0.0476
0.04580
0.66096229
da/dv
da/dv
CALCULO DE (b2)
b2
(V2 - a)
0.66850
V2
( V1 - V2 )
0.7143
0.6667
b2
b2
0.668501
0.537908
0.86956522 -
0.66850
0.0476
0.04580
0.649507688
a
a
bpromedio =
b1 + b2
2
0.660962 + 0.649508
2
= 0.655234989
CALCULO DE (V2)
V2 =
V1 (bpromedio) + a
1 + bpromedio
V2 = 0.86956522 ( 0.65523499
1 +
0.655234989
V2 =
0.66919655
CALCULO DE LA T2
T2
T2
= (
360.26135 +
298
0.65523499 (
T2
1576
T2(ASUMIDA)
0.368687503
0.368687503 ))
)- 0.5 (
0.655234989
0.00198
) X 46.6873954
K
=
1576
1582
1579
RESUMEN:
N DE
PRUEBA
9
V2
ESTIMADA
b1
b2
0.66850
0.66096
0.64951
t2 k
t2 k
(Calculada
(Asumida)
)
1582
1576
DECIMA PRUEBA
DATOS
DENSIDAD
=
V 1 = 0.869565
1.15
cc/gr
T2 asumida
V2
1579
0.66919655
cc/gr
=
=
gr/cc
INTERPOLANDO
T K
IDEAL CV - GAS
N2
1500
CO2
6.343
500
12.001
0.272
0.514
2000
6.615
T ASUMIDA = 1579
500
0.272
500
0.514
79
79
X = 0.042976
X = 0.081212
N2
CO2 = 12.08221

CO2
N2
H2O
:
:
:
1.02096549
5.448603102
39.29050251
mol/kg
mol/kg
mol/kg
12.515
x
x
x
= 6.385976
T =
12.08221
6.385976
9.285092
1579
cal/mol.k
cal/mol.k
cal/mol.k
SmiCv
SmiCv
= 12.3355215
= 34.7946486
= 364.81593
= 411.946101
= 0.4119461
T K
N2
1500
CO2
5.653
500
10.302
0.247
2000
0.582
5.9
T ASUMIDA = 1579
:
:
:
:
1.02096549
5.448603102
39.29050251
0.927324308
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
CV )
INTERPOLANDO
CO2
N2
H2O
AL2O3
mol/kg
mol/kg
mol/kg
mol/kg
10.884
500
0.247
500
0.582
79
79
x
x
x
x
X = 0.039026
X = 0.091956
N2
CO2 = 10.39396
= 5.692026
10.39396
5.692026
7.659432
28
cal/mol.k
cal/mol.k
cal/mol.k
cal/mol.k
=
=
=
=
10.6118704
31.0135905
300.942932
25.9650806
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
SmiCv = 368.533474
SmiCv = 0.36853347

Smi
1.02096549 +
Smi gas- solido =
45.7600711 +
N DE MOLES
5.4486031 + 39.2905025 =

0.92732431 =
(Smi)(R)+ (SmiCv)
45.7600711
N DE MOLES
46.68739541

b1
cal/kg.k
kcal/kg.k
mol/kg
= 0.66919655
da/dv
V2
(SmiCv)
0.7143
0.6667
b1
= ( 45.76007 )(
0.00198
)+(
0.411946 ) -
0.558427
0.411946101
b1
0.0476
0.04510
0.661517135
da/dv
da/dv
CALCULO DE (b2)
b2
(V2 - a)
0.66920
V2
( V1 - V2 )
0.7143
0.6667
b2
b2
0.669197
0.538259
0.86956522 -
0.66920
0.0476
0.04510
0.653484337
a
a
bpromedio =
b1 + b2
2
0.661517 + 0.653484
2
= 0.657500736
CALCULO DE (V2)
V2 =
V1 (bpromedio) + a
1 + bpromedio
V2 = 0.86956522 ( 0.65750074
1 +
0.657500736
V2 =
0.669682077
CALCULO DE LA T2
T2
T2
= (
360.26135 +
0.65750074 (
T2
1576
T2(ASUMIDA)
298
0.368533474
0.368533474 ))
)- 0.5 (
0.657500736
0.00198
) X 46.6873954
K
=
1576
1579
1577
RESUMEN:
N DE
PRUEBA
10
V2
ESTIMADA
b1
b2
0.66920
0.66152
0.65348
ONCEAVA PRUEBA
DATOS
DENSIDAD
=
V 1 = 0.869565
1.15
cc/gr
gr/cc
t2 k
t2 k
(Calculada
(Asumida)
)
1579
1576
T2 asumida
V2
=
=
1577
0.669682077
cc/gr
INTERPOLANDO
IDEAL CV - GAS
T K
N2
1500
6.343
500
0.514
6.615
T ASUMIDA = 1577
:
:
:
1.02096549
5.448603102
39.29050251
mol/kg
mol/kg
mol/kg
0.272
500
0.514
77
77
X = 0.041888
X = 0.079156
N2
CO2 = 12.08016
x
x
x
= 6.384888
T =
12.08016
6.384888
9.281596
1577
cal/mol.k
cal/mol.k
cal/mol.k
SmiCv
SmiCv
=
=
=
=
=
12.3334224
34.7887206
364.678571
411.800714
0.41180071
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
N2
1500
CV )
INTERPOLANDO
T K
12.515
500
CO2
5.653
500
2000
12.001
0.272
2000
CO2
N2
H2O
CO2
10.302
0.247
5.9
0.582
10.884
T ASUMIDA = 1577
CO2
N2
H2O
AL2O3
:
:
:
:
1.02096549
5.448603102
39.29050251
0.927324308
mol/kg
mol/kg
mol/kg
mol/kg
500
0.247
500
0.582
77
77
x
x
x
x
X = 0.038038
X = 0.089628
N2
CO2 = 10.39163
= 5.691038
10.39163
5.691038
7.657016
28

Sni
1.02096549 +
45.7600711 +
=
=
=
=
=
=
0.92732431 =
(Sni)(R)+ (SniCv)
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
45.7600711
N DE MOLES
46.68739541

b1
10.6094936
31.0082073
300.848006
25.9650806
368.430788
0.36843079
N DE MOLES
5.4486031 + 39.2905025 =

Sni gas- solido
cal/mol.k
cal/mol.k
cal/mol.k
cal/mol.k
SmiCv
SmiCv
mol/kg
= 0.66968208
da/dv
V2
(SniCv)
0.7143
0.6667
b1
= ( 45.76007 )(
0.00198
)+(
0.411801 ) -
0.558121
0.411800714
b1
0.0476
0.04462
0.66190079
da/dv
da/dv
CALCULO DE (b2)
b2
(V2 - a)
( V1 - V2 )
0.66968
V2
0.7143
0.6667
b2
b2
0.669682
0.538504
0.86956522 -
0.66968
0.0476
0.04462
0.656276004
a
a
bpromedio =
b1 + b2
2
0.661901 + 0.656276
2
= 0.659088397
CLCULO DE (V2)
V2 =
V1 (bpromedio) + a
1 + bpromedio
V2 = 0.86956522 (
1 +
V2 =
0.6590884
0.659088397
0.670020908
CALCULO DE LA T2
T2
T2
= (
360.26135 +
0.6590884 (
T2
1575
T2(ASUMIDA)
298
0.368430788
0.368430788 ))
)- 0.5 (
0.659088397
0.00198
) X 46.6873954
K
=
1575
+
2
1577
1576
RESUMEN:
N DE
PRUEBA
11
V2
ESTIMADA
b1
b2
0.66968
0.66190
0.65628
t2 k
t2 k
(Asumida) (Calculada
1577
1575
DOCEAVA PRUEBA
DATOS
DENSIDAD
=
V 1 = 0.869565
T2 asumida
V2
=
=
1.15
cc/gr
gr/cc
1576
0.670020908
cc/gr
INTERPOLANDO
IDEAL CV - GAS
T K
N2
1500
6.343
500
12.001
0.272
2000
0.514
6.615
T ASUMIDA = 1576
:
:
:
1.02096549
5.448603102
39.29050251
mol/kg
mol/kg
mol/kg
12.515
500
0.272
500
0.514
76
76
X = 0.041344
X = 0.078128
N2
CO2 = 12.07913

CO2
N2
H2O
CO2
x
x
x
= 6.384344
T =
12.07913
6.384344
9.279848
CV )
1576
cal/mol.k
cal/mol.k
cal/mol.k
SmiCv
SmiCv
=
=
=
=
=
12.3323728
34.7857565
364.609891
411.72802
0.41172802
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
INTERPOLANDO
T K
N2
1500
CO2
5.653
10.302
500
0.247
2000
5.9
T ASUMIDA = 1576
CO2
N2
H2O
AL2O3
:
:
:
:
1.02096549
5.448603102
39.29050251
0.927324308
mol/kg
mol/kg
mol/kg
mol/kg
10.884
500
0.247
500
0.582
76
76
x
x
x
x
X = 0.037544
X = 0.088464
N2
CO2 = 10.39046
= 5.690544
10.39046
5.690544
7.655808
28

Smi
1.02096549 +
Smi gas- solido =
45.7600711 +
cal/mol.k
cal/mol.k
cal/mol.k
cal/mol.k
SmiCv
SmiCv
=
0.92732431 =
(Smi)(R)+ (SmiCv)
(SmiCv)
10.6083052
31.0055157
300.800543
25.9650806
368.379445
0.36837944
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
N DE MOLES
45.7600711
N DE MOLES
46.68739541

=
=
=
=
=
=
=
5.4486031 + 39.2905025 =
b1
0.582
da/dv
mol/kg
= 0.67002091
V2
0.7143
0.6667
b1
= ( 45.76007 )(
0.00198
)+(
0.41172802
0.411728 ) -
0.557907
0.0476
0.04428
b1
0.662153185
da/dv
da/dv
CALCULO DE (b2)
b2
(V2 - a)
0.67002
V2
( V1 - V2 )
0.7143
0.6667
b2
b2
0.538674
0.86956522 -
0.670021
0.67002
0.0476
0.04428
0.658232252
a
a
bpromedio =
b1 + b2
2
0.662153 + 0.658232
2
= 0.660192718
CLCULO DE (V2)
V2 =
V1 (bpromedio) + a
1 + bpromedio
V2 = 0.86956522 ( 0.66019272
1 +
0.660192718
V2 =
0.670256543
CALCULO DE LA T2
T2

T2
= (
360.26135 +
0.66019272 (
298
0.368379445
0.368379445 ))
)- 0.5 (
0.660192718
0.00198
) X 46.6873954
T2
1575
T2(ASUMIDA)
K
=
1575
1576
1575
RESUMEN:
N DE
PRUEBA
12
V2
ESTIMADA
b1
b2
0.67002
0.66215
0.65823
t2 k
t2 k
(Calculada
(Asumida)
)
1576
1575
TRECEAVA PRUEBA
DATOS
DENSIDAD
=
V 1 = 0.869565
T2 asumida
V2
=
=
1.18
cc/gr
gr/cc
1575
0.670256543
cc/gr
INTERPOLANDO
IDEAL CV - GAS
T K
CO2
N2
1500
6.343
500
2000
T ASUMIDA = 1575
12.001
0.272
6.615
0.514
12.515
500
0.272
500
0.514
75
75
X=
N2
0.0408
=
6.3838
X=
0.0771
CO2 = 12.0781

CO2
N2
H2O
:
:
:
1.02096549
5.448603102
39.29050251
mol/kg
mol/kg
mol/kg
1575
12.0781
6.3838
9.2781
x
x
x
T =
cal/mol.k
cal/mol.k
cal/mol.k
SmiCv
SmiCv
=
=
=
=
=
T K
N2
1500
CO2
5.653
10.302
500
0.247
2000
0.582
5.9
T ASUMIDA = 1575
10.884
500
0.247
500
0.582
75
75
X = 0.03705
X=
N2 = 5.69005
:
:
:
:
1.02096549
5.448603102
39.29050251
0.927324308
mol/kg
mol/kg
mol/kg
mol/kg
x
x
x
x
10.3893
5.69005
7.6546
28

Smi
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
CV )
INTERPOLANDO
CO2
N2
H2O
AL2O3
12.3313233
34.7827925
364.541211
411.655327
0.41165533
1.02096549 +
cal/mol.k
cal/mol.k
cal/mol.k
cal/mol.k
SmiCv
SmiCv
=
CO2 = 10.3893
=
=
=
=
=
=
10.6071168
31.0028241
300.75308
25.9650806
368.328102
0.3683281
N DE MOLES
5.4486031 + 39.2905025 =
0.0873
45.7600711
N DE MOLES
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
Smi gas- solido =
45.7600711 +
0.92732431 =
46.68739541

b1
(Smi)(R)+ (SmiCv)
mol/kg
= 0.67025654
da/dv
V2
(SmiCv)
0.7143
0.6667
b1
= ( 45.76007 )(
0.00198
)+(
0.411655 ) -
0.557758
0.411655327
b1
0.0476
0.04404
0.662340555
da/dv
da/dv
CALCULO DE (b2)
b2
(V2 - a)
( V1 - V2 )
0.67026
V2
0.7143
0.6667
b2
b2
0.670257
0.538793
0.86956522 -
0.67026
0.0476
0.04404
0.659596619
a
a
bpromedio =
b1 + b2
2
0.662341 + 0.659597
2
= 0.660968587
CLCULO DE (V2)
V2 =
V1 (bpromedio) + a
V2 = 0.86956522 (
0.66096859
1 + bpromedio
1 +
V2 =
0.660968587
0.670421173
CALCULO DE LA T2
T2
T2
= (
360.26135 +
0.66096859 (
T2
1575
T2(ASUMIDA)
298
0.368328102
0.368328102 ))
0.660968587
)- 0.5 (
0.00198
1575
) X 46.6873954
K
=
1575
+
2
1575 K
RESUMEN:
N DE
PRUEBA
13
V2
ESTIMADA
b1
b2
0.67026
0.66234
0.65960
t2 k
t2 k
(Calculada
(Asumida)
)
1575
1575
ARAMETROS DE
ACIN
IDEAL CV - GAS
H2O
11.321
0.12
0.116
11.437
0.12
X
500
400
X=
13.464
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
0.116
X
0.0928
H2O = 11.4138
kcal/kg.k
AL CV - SOLIDO -GAS
H2O
9.614
0.165
0.21
9.824
0.165
X
500
400
X=
12.171
H2O =
0.21
X
0.168
9.782
AL2O3 =
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
mol/kg
0.64783
cc/gr
V2
da/dv
0.6667
0.56
0.0417
0.03
0.625
0.0417
0.01887
0.59
0.03
x
28
x
da/dv
da/dv
=
=
0.0136
0.56 + 0.013578
0.573578
0.64783
cc/gr
V2
0.6667
0.537
0.0417
0.024
0.625
0.513
0.0417
0.01887
0.024
x
x
a
a
=
=
0.0109
0.537 - 0.010863
0.526137
0.578112122
0.57811212 ) +
0.578112122
0.526137
CALCULADO
t2 k
(Calculada)
1313
IDEAL CV - GAS
H2O
10.567
0.235
0.359
10.926
0.235
500
0.359
356
X = 0.255608
12.99732
H2O = 10.82261
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
L CV - SOLIDO -GAS
H2O
8.656
0.307
0.389
9.045
0.307
500
0.389
356
X = 0.276968
11.51158
H2O = 8.932968
AL2O3 =
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
mol/kg
0.65194576 K
V2
da/dv
28
0.6667
0.56
0.0417
0.03
0.625
0.59
0.0417
0.01475
0.03
x
x
da/dv
da/dv
=
=
0.0106
0.56 + 0.010615
0.570615
0.65195
V2
0.6667
0.537
0.0417
0.024
0.625
0.513
0.0417
0.01475
0.024
x
x
a
a
=
=
0.0085
0.537 - 0.008492
0.528508
0.593516548
0.59351655 ) +
0.593516548
0.528508
CALCULADO
t2 k
(Calculada)
1411
IDEAL CV - GAS
H2O
10.021
0.315
0.546
10.567
0.315
500
0.546
133
X = 0.145236
12.59879
H2O = 10.16624
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
L CV - SOLIDO -GAS
H2O
8.168
0.409
0.488
8.656
0.409
500
0.488
133
X = 0.129808
10.99279
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
H2O = 8.297808
AL2O3 =
28
mol/kg
0.6555374 K
V2
da/dv
0.6667
0.56
0.0417
0.03
0.625
0.59
0.0417
0.01116
0.03
x
x
da/dv
da/dv
=
=
0.0080
0.56 + 0.008031
0.568031
0.65554
V2
0.6667
0.537
0.0417
0.024
0.625
0.513
0.0417
0.01116
0.024
x
x
a
a
=
=
0.0064
0.537 - 0.006425
0.530575
0.608907034
0.60890703 ) +
0.608907034
0.530575
CALCULADO
t2 k
(Calculada)
1495
IDEAL CV - GAS
H2O
9.147
0.514
0.874
10.021
0.514
500
0.874
314
X = 0.548872
12.32379
H2O = 9.695872
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
L CV - SOLIDO -GAS
H2O
7.564
0.582
0.604
8.168
0.582
500
0.604
314
X = 0.379312
10.6675
H2O = 7.943312
AL2O3 =
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
mol/kg
0.65886955 K
V2
da/dv
0.6667
0.56
0.0417
0.03
0.625
0.59
0.0417
0.00783
0.03
x
x
da/dv
da/dv
=
=
0.65887
V2
0.0056
0.56 + 0.005633
0.565633
K
a
28
0.6667
0.537
0.0417
0.024
0.625
0.513
0.0417
0.00783
0.024
x
x
a
a
=
=
0.0045
0.537 - 0.004507
0.532493
0.622678745
0.62267874 ) +
0.622678745
0.532493
CALCULADO
t2 k
(Calculada)
1546
IDEAL CV - GAS
H2O
9.147
0.514
0.874
10.021
0.514
500
0.874
180
X = 0.31464
12.18604
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
H2O = 9.46164
L CV - SOLIDO -GAS
H2O
7.564
0.582
0.604
8.168
0.582
500
0.604
180
X = 0.21744
10.51152
H2O = 7.78144
AL2O3 =
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
mol/kg
0.6618396 K
V2
da/dv
0.6667
0.56
0.0417
0.03
28
0.625
0.59
0.0417
0.00486
0.03
x
x
da/dv
da/dv
=
=
0.0035
0.56 + 0.003497
0.563497
0.66184
V2
0.6667
0.537
0.0417
0.024
0.625
0.513
0.0417
0.00486
0.024
x
x
a
a
=
=
0.0028
0.537 - 0.002797
0.534203
0.633522673
0.63352267 ) +
0.633522673
0.534203
CALCULADO
t2 k
(Calculada)
1568
IDEAL CV - GAS
H2O
9.147
0.514
0.874
10.021
0.514
500
0.874
124
X = 0.216752
12.12847
H2O = 9.363752
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
L CV - SOLIDO -GAS
H2O
7.564
0.582
0.604
8.168
0.582
500
0.604
124
X = 0.149792
10.44634
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
H2O = 7.713792
AL2O3 =
28
mol/kg
0.66426499 K
V2
da/dv
0.6667
0.56
0.0417
0.03
0.625
0.59
0.0417
0.00244
0.03
x
x
da/dv
da/dv
=
=
0.0018
0.56 + 0.001752
0.561752
0.66426
V2
0.6667
0.537
0.0417
0.024
0.625
0.513
0.0417
0.00244
0.024
x
x
a
a
0.641591201
=
=
0.0014
0.537 - 0.001401
0.535599
0.6415912 ) +
0.641591201
t2 k
(Calculada
)
1575
0.535599
IDEAL CV - GAS
H2O
9.147
0.514
0.874
10.021
0.514
500
0.874
99
X = 0.173052
12.10277
H2O = 9.320052
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
L CV - SOLIDO -GAS
H2O
7.564
0.582
0.604
8.168
0.582
500
0.604
99
X = 0.119592
10.41724
H2O = 7.683592
AL2O3 =
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
mol/kg
0.6661244 K
V2
da/dv
0.6667
0.56
0.0417
0.03
0.625
0.59
0.0417
0.00058
0.03
x
x
da/dv
da/dv
=
=
0.66612
0.0004
0.56 + 0.000414
0.560414
V2
0.6667
0.537
0.0417
0.625
0.024
0.513
28
0.0417
0.00058
0.024
x
x
a
a
=
=
0.0003
0.537 - 0.000331
0.536669
0.647543481
0.64754348 ) +
0.647543481
t2 k
(Calculada
)
1577
0.536669
IDEAL CV - GAS
H2O
9.147
0.514
0.874
10.021
0.514
500
0.874
88
X = 0.153824
12.09146
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
L CV - SOLIDO -GAS
H2O = 9.300824
H2O
7.564
0.582
0.604
8.168
0.582
500
0.604
88
X = 0.106304
10.40443
H2O = 7.670304
AL2O3 =
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
mol/kg
0.66750894 K
V2
da/dv
0.7143
0.53
0.0476
0.03
0.6667
0.0476
0.04679
0.56
0.03
x
28
x
da/dv
da/dv
=
=
0.0295
0.53 +
0.559490
0.66751
0.029490
V2
0.7143
0.561
0.0476
0.024
0.6667
0.537
0.0476
0.04679
0.024
x
x
a
a
=
=
0.0236
0.561 0.537408
0.023592
0.651995047
0.65199505 ) +
0.651995047
0.537408
t2 k
(Calculada
)
1577
IDEAL CV - GAS
H2O
9.147
0.514
0.874
10.021
0.514
500
0.874
82
X = 0.143336
12.0853
H2O = 9.290336
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
L CV - SOLIDO -GAS
H2O
7.564
0.582
0.604
8.168
0.582
500
0.604
82
X = 0.099056
10.39745
H2O = 7.663056
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
mol/kg
AL2O3 =
28
0.66850084 K
V2
da/dv
0.7143
0.53
0.0476
0.03
0.6667
0.56
0.0476
0.04580
0.03
x
x
da/dv
da/dv
=
=
0.0289
0.53 + 0.028865
0.558865
0.66850
V2
0.7143
0.561
0.0476
0.024
0.6667
0.537
0.0476
0.04580
0.024
x
x
a
a
=
=
0.0231
0.561 - 0.023092
0.537908
0.655234989
0.65523499 ) +
0.655234989
0.537908
t2 k
(Calculada
)
1576
IDEAL CV - GAS
H2O
9.147
0.514
0.874
10.021
0.514
500
0.874
79
X = 0.138092
12.08221
H2O = 9.285092
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
L CV - SOLIDO -GAS
H2O
7.564
0.582
0.604
8.168
0.582
500
0.604
79
X = 0.095432
10.39396
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
H2O = 7.659432
AL2O3 =
28
cal/kg.k
kcal/kg.k
mol/kg
0.66919655 K
V2
da/dv
0.7143
0.53
0.0476
0.03
0.6667
0.56
0.0476
0.04510
0.03
x
x
da/dv
da/dv
=
=
0.0284
0.53 + 0.028427
0.558427
0.66920
V2
0.7143
0.561
0.0476
0.024
0.6667
0.537
0.0476
0.04510
0.024
x
x
a
a
=
=
0.0227
0.561 - 0.022741
0.538259
0.657500736
0.65750074 ) +
0.657500736
t2 k
(Calculada
)
1576
0.538259
IDEAL CV - GAS
H2O
9.147
0.514
0.874
10.021
0.514
500
0.874
77
X = 0.134596
12.08016
H2O = 9.281596
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
L CV - SOLIDO -GAS
H2O
7.564
0.582
0.604
8.168
0.582
500
0.604
77
X = 0.093016
10.39163
H2O = 7.657016
AL2O3 =
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
mol/kg
0.66968208 K
V2
da/dv
0.7143
0.53
0.0476
0.03
0.6667
0.56
0.0476
0.04462
0.03
x
x
da/dv
da/dv
=
=
0.66968
V2
0.0281
0.53 + 0.028121
0.558121
K
a
28
0.7143
0.561
0.0476
0.024
0.6667
0.537
0.0476
0.04462
0.024
x
x
a
a
=
=
0.0225
0.561 - 0.022496
0.538504
0.659088397
0.6590884 ) +
0.659088397
t2 k
(Calculada
1575
0.538504
IDEAL CV - GAS
H2O
9.147
0.514
0.874
10.021
0.514
500
0.874
76
X = 0.132848
12.07913
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
H2O = 9.279848
L CV - SOLIDO -GAS
H2O
7.564
0.582
0.604
8.168
0.582
500
0.604
76
X = 0.091808
10.39046
H2O = 7.655808
AL2O3 =
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
mol/kg
0.67002091 K
V2
da/dv
0.7143
0.53
0.0476
0.03
0.6667
0.0476
0.04428
0.56
0.03
x
28
x
da/dv
da/dv
=
=
0.0279
0.53 + 0.027907
0.557907
0.67002
V2
0.7143
0.561
0.0476
0.024
0.6667
0.537
0.0476
0.04428
0.024
x
x
a
a
=
=
0.0223
0.561 - 0.022326
0.538674
0.660192718
0.66019272 ) +
0.660192718
0.538674
t2 k
(Calculada
)
1575
IDEAL CV - GAS
H2O
9.147
0.514
0.874
10.021
0.514
500
0.874
75
X=
12.0781
H2O =
0.1311
9.2781
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
L CV - SOLIDO -GAS
H2O
7.564
0.582
0.604
8.168
0.582
500
0.604
75
X=
10.3893
H2O =
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
mol/kg
0.0906
7.6546
AL2O3 =
28
0.67025654 K
V2
da/dv
0.7143
0.53
0.0476
0.03
0.6667
0.56
0.0476
0.04404
0.03
x
x
da/dv
da/dv
=
=
0.0278
0.53 + 0.027758
0.557758
0.67026
V2
0.7143
0.561
0.0476
0.024
0.6667
0.537
0.0476
0.04404
0.024
x
x
a
a
=
=
0.0222
0.561 - 0.022207
0.538793
0.660968587
0.66096859 ) +
0.538793
0.660968587
TEMPERATURA FINAL
EN EQUILIBRIO
t2 k
(Calculada
)
1575
CUADRO DE RESUMEN
N de
Pruebas
1
2
3
4
5
6
7
8
9
10
11
12
13
V2
Estimado
0.6478261
0.6519458
0.6555374
0.6588696
0.6618396
0.664265
0.6661244
0.6675089
0.6685008
0.6691966
0.6696821
0.6700209
0.6702565
b1
b2
0.60743175
0.6198163
0.63395576
0.64555261
0.65259562
0.65645909
0.65875607
0.66010476
0.66096229
0.66151713
0.66190079
0.66215319
0.66234055
0.5487925
0.56721679
0.58385831
0.59980487
0.61444973
0.62672331
0.6363309
0.64388533
0.64950769
0.65348434
0.656276
0.65823225
0.65959662
RESUMEN
5000
4500
4000
3500
T2 K ASUMIDO
T2 K
T2 K
(asumido) (calculado)
4400
1313
2856
1411
2133
1495
1814
1546
1680
1568
1624
1575
1599
1577
1588
1577
1582
1576
1579
1576
1577
1575
1576
1575
1575
1575
3000
2500
2000
1500
1000
500
0
1
T2 K CALCULA
Series1
Series2
K CALCULADO
10
11
12
13
CALCULO DE PARAMETROS DE
EXPLOSIN
DATOS
d1
d3
V1
V3
Qe
T3
=
=
0.08207
P3
Smi .R.T3
V3 - a
T3
T2 - 400 k
360.2613505
Qe
+
(SmiCv)
T3 =
1575
T1
400
1175
PRIMERA PRUEBA
CAPACIDAD DE CALOR PROMEDIO
INTERPOLANDO
T K
N2
1000
CO2
5.323
9.395
500
0.33
1500
1.02096549
5.448603102
39.29050251
0.927324308
mol/kg
mol/kg
mol/kg
mol/kg
x
x
x
x
0.33
500
0.907
500
0.697
175
175
0.1155
=
X =
5.4385
9.71245
5.4385
7.11095
28
cal/mol.k
cal/mol.k
cal/mol.k
cal/mol.k
SmiCv
SmiCv
CO2 =
=
=
=
=
=
=
Qe
SmiCv
T3(calculado)
T1
360.2613505
298
1343
0.344906184
T3(asumida)
= T3 + TCALCULADA =
1259
2
RESUMEN:
N DE
PRUEBA
SmiCv
T2 k
(Asumida)
T2 k
(Calculada)
0.34491
1175
1343
0.31745
X =
9.71245
9.916076274
29.63222797
279.3927988
25.96508062
344.9061837
0.344906184
CALCULO DE T3
T3 =
0.697
7.564
175
N2
:
:
:
:
10.302
500
X =
CO2
N2
H2O
AL2O3
6.867
0.907
5.653
T ASUMIDA = 1175
H2 O
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
H2O =
0.24395
7.11095
AL2O3 =
28
SEGUNDA PRUEBA
T3(asumida)
1259

INTERPOLANDO
T K
N2
1000
CO2
5.323
9.395
500
0.33
1500
CO2
N2
H2O
AL2O3
:
:
:
:
1.02096549
5.448603102
39.29050251
0.927324308
mol/kg
mol/kg
mol/kg
mol/kg
10.302
Qe
SmiCv
T3(calculado)
500
0.33
500
0.907
500
0.697
258.76
258.76
X = 0.170782
X =
N2
CO2 =
x
x
x
x
= 5.493782
9.86439
5.493782
7.227711
28
cal/mol.k
cal/mol.k
cal/mol.k
cal/mol.k
SmiCv
SmiCv
=
=
=
=
=
=
298
1327
0.349950128
T3(asumida)
= T3 + TCALCULADA =
1293
2
RESUMEN:
N DE
PRUEBA
SmiCv
T2 k
(Asumida)
T2 k
(Calculada)
0.34995
1259
1327
0.46939
X = 0.360711
9.86439
10.07120227
29.93343518
283.98041
25.96508062
349.950128
0.349950128
T1
360.2613505
0.697
7.564
258.76
CALCULO DE T3
T3
6.867
0.907
5.653
T ASUMIDA = 1259
H2 O
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
H2O = 7.227711
AL2O3 =
28
TERCERA PRUEBA
T3(asumida)
1293

INTERPOLANDO
T K
N2
1000
CO2
5.323
9.395
500
0.33
1500
CO2
N2
H2O
AL2O3
:
:
:
:
1.02096549
5.448603102
39.29050251
0.927324308
mol/kg
mol/kg
mol/kg
mol/kg
10.302
Qe
SmiCv
T3(calculado)
500
0.33
500
0.907
500
0.697
293.11
293.11
x
x
x
x
X = 0.193454
X = 0.531706
X = 0.408599
N2
CO2 = 9.926706
H2O = 7.275599
= 5.516454
9.926706
5.516454
7.275599
28
cal/mol.k
cal/mol.k
cal/mol.k
cal/mol.k
SmiCv
SmiCv
=
=
=
=
=
=
10.1348241
30.0569693
285.8619271
25.96508062
352.0188011
0.352018801
T1
360.2613505
298
1321
0.352018801
T3(asumida)
= T3 + TCALCULADA =
0.697
7.564
293.11
CALCULO DE T3
T3
6.867
0.907
5.653
T ASUMIDA = 1293
H2 O
1307
2
RESUMEN:
N DE
PRUEBA
SmiCv
T2 k
(Asumida)
T2 k
(Calculada)
0.35202
1293
1321
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
AL2O3 =
28
CUARTA PRUEBA
T3(asumida)
1307

INTERPOLANDO
T K
N2
1000
CO2
5.323
9.395
500
0.33
1500
CO2
N2
H2O
AL2O3
:
:
:
:
1.02096549
5.448603102
39.29050251
0.927324308
mol/kg
mol/kg
mol/kg
mol/kg
10.302
Qe
SmiCv
T3(calculado)
500
0.33
500
0.907
500
0.697
307.26
307.26
x
x
x
x
X = 0.202794
X = 0.557376
X = 0.428326
N2
CO2 = 9.952376
H2O = 7.295326
= 5.525794
9.952376
5.525794
7.295326
28
cal/mol.k
cal/mol.k
cal/mol.k
cal/mol.k
SmiCv
SmiCv
=
=
=
=
=
=
10.16103285
30.10785867
286.6370103
25.96508062
352.8709824
0.352870982
T1
360.2613505
298
1319
0.352870982
T3(asumida)
= T3 + TCALCULADA =
0.697
7.564
307.26
CALCULO DE T3
T3
6.867
0.907
5.653
T ASUMIDA = 1307
H2 O
1313
2
RESUMEN:
N DE
PRUEBA
SmiCv
T2 k
(Asumida)
T2 k
(Calculada)
0.35287
1307
1319
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
AL2O3 =
28
QUINTA PRUEBA
T3(asumida)
1313

INTERPOLANDO
T K
N2
1000
CO2
5.323
9.395
500
0.33
1500
CO2
N2
H2O
AL2O3
:
:
:
:
1.02096549
5.448603102
39.29050251
0.927324308
mol/kg
mol/kg
mol/kg
mol/kg
10.302
Qe
SmiCv
T3(calculado)
500
0.33
500
0.907
500
0.697
313.1
313.1
X = 0.206648
X =
N2
CO2 =
x
x
x
x
= 5.529648
9.96297
5.529648
7.303466
28
cal/mol.k
cal/mol.k
cal/mol.k
cal/mol.k
SmiCv
SmiCv
=
=
=
=
=
=
298
1318
0.353222656
T3(asumida)
= T3 + TCALCULADA =
1316
2
RESUMEN:
N DE
PRUEBA
SmiCv
T2 k
(Asumida)
T2 k
(Calculada)
0.35322
1313
1318
0.56797
X = 0.436466
9.96297
10.17184854
30.12885942
286.9568675
25.96508062
353.2226561
0.353222656
T1
360.2613505
0.697
7.564
313.1
CALCULO DE T3
T3
6.867
0.907
5.653
T ASUMIDA = 1313
H2 O
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
H2O = 7.303466
AL2O3 =
28
SEXTA PRUEBA
T3(asumida)
1316

INTERPOLANDO
T K
N2
1000
CO2
5.323
9.395
500
0.33
1500
1.02096549
5.448603102
39.29050251
0.927324308
mol/kg
mol/kg
mol/kg
mol/kg
0.33
500
0.907
500
0.697
315.52
315.52
x
x
x
x
0.20824
=
5.53124
9.967345
5.53124
7.306828
28
cal/mol.k
cal/mol.k
cal/mol.k
cal/mol.k
SmiCv
SmiCv
=
=
=
=
=
=
X = 0.572345
X = 0.439828
CO2 = 9.967345
H2O = 7.306828
10.17631512
30.13753216
287.0889598
25.96508062
353.3678877
0.353367888
CALCULO DE T3
T3
Qe
SmiCv
T3(calculado)
T1
360.2613505
298
1318
0.353367888
T3(asumida)
= T3 + TCALCULADA =
0.697
7.564
500
N2
:
:
:
:
10.302
315.52
X =
CO2
N2
H2O
AL2O3
6.867
0.907
5.653
T ASUMIDA = 1316
H2 O
1317
2
RESUMEN:
N DE
PRUEBA
SmiCv
T2 k
(Asumida)
T2 k
(Calculada)
0.35337
1316
1318
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
AL2O3 =
28
SEPTIMA PRUEBA
T3(asumida)
1317

INTERPOLANDO
T K
N2
1000
CO2
5.323
9.395
500
0.33
1500
CO2
N2
H2O
AL2O3
:
:
:
:
1.02096549
5.448603102
39.29050251
0.927324308
mol/kg
mol/kg
mol/kg
mol/kg
10.302
Qe
SmiCv
T3(calculado)
500
0.33
500
0.907
500
0.697
316.51
316.51
x
x
x
x
X = 0.208898
X = 0.574152
X = 0.441217
N2
CO2 = 9.969152
H2O = 7.308217
= 5.531898
9.969152
5.531898
7.308217
28
cal/mol.k
cal/mol.k
cal/mol.k
cal/mol.k
SmiCv
SmiCv
=
=
=
=
=
=
10.17816025
30.14111482
287.1435264
25.96508062
353.427882
0.353427882
T1
360.2613505
298
1317
0.353427882
T3(asumida)
= T3 + TCALCULADA =
0.697
7.564
316.51
CALCULO DE T3
T3
6.867
0.907
5.653
T ASUMIDA = 1317
H2 O
1317
2
RESUMEN:
N DE
PRUEBA
SmiCv
T2 k
(Asumida)
T2 k
(Calculada)
0.35343
1317
1317
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
cal/kg.k
kcal/kg.k
AL2O3 =
28
ATRS
SIGUIENTE
CUADRO DE RESUMEN
N de
Pruebas
SmiCv
T2 k
(Asumida)
1
2
3
4
5
6
7
0.34490618
0.34995013
0.3520188
0.35287098
0.35322266
0.35336789
0.35342788
1175
1259
1293
1307
1313
1316
1317
T2 k
(Calculada)
1343
1327
1321
1319
1318
1318
1317
1400
1350
T2 k
(Asumida)
1300
1250
1200
1150
1100
1050
1
T2 k
(Calculada)
Series1
Series2

Slurres 40

Cargado por

Información del documento

Derechos de autor

Formatos disponibles

Compartir este documento

Compartir o incrustar documentos

Opciones para compartir

¿Le pareció útil este documento?

¿Este contenido es inapropiado?

Copyright:

Formatos disponibles

Slurres 40

Cargado por

Copyright:

Formatos disponibles

SLURREX 40

CALCULO DE LOS PRAMETROS DE EXPLOSION Y DET

CALCULO DE PARAMETROS DE DETONACION

CALCULO DE PARAMETROS DE EXPLOSION :

atomo gr/Kg = 1000 x N de atomos x %

DENSIDAD 1,15 g/cc

CORRECCION DEL BALANCE DE OXIGENO

DENSIDAD 1,15 g/cc

( 0.264 + 0.375 A + 0.555 B )-( 2 (

1.021 ))-( 0.5 (

SOLUCIN DEL SISTEMA DE ECUACIONES CON DOS INCG

SUMATORIA DE TODOS LOS PORCENTAJES

A 0.4998 A 0.3748 A 0.2499

1.1099 B )-( 2 ( 1.852 )) = 0

NES CON DOS INCGNITAS

ECUACION DE LA REACCION QUIMICA:

HALLANDO COEFICIENTES DEL PRODUCTO:

CALOR DE FORMACION DEL REACTANTE (QR)

CALOR DE FORMACION DEL PRODUCTO (QP)

CALOR LIBERADO POR LA REACCION

ASUMIMOS UNA T (2000 - 6000)

CAPACIDAD DE CALOR IDEAL (Cv)

CAPACIDAD DE CALOR IDEAL

IDEAL CV - SOLIDO -GAS

CALCULO DE COEFICIENTE DE COMPRESIBILIDAD (b 1)

CALCULO DE LAS Sni (GAS + SOLIDO)

CALCULO DE LAS Sni (GAS)

(Q2 + T1(SmiCV)) bpromedio

CAPACIDAD DE CALOR IDEAL (Cv)

CAPACIDAD DE CALOR IDEAL PROMEDIO

CALCULO DE COEFICIENTE DE COMPRESIBILIDAD (b 1)

CALCULO DE LAS Sni (GAS + SOLIDO)

CALCULO DE LAS Sni (GASEOSO)

IDEAL CV - SOLIDO -GAS

(Q2 + T1(SmiCV)) bpromedio

CAPACIDAD DE CALOR IDEAL (Cv)

CAPACIDAD DE CALOR IDEAL PROMEDIO

IDEAL CV - SOLIDO -GAS

CALCULO DE LAS Smi (GASEOSO)

CALCULO DE LAS Smi (GAS + SOLIDO)

CALCULO DE COEFICIENTE DE COMPRESIBILIDAD (b 1)

(Q2 + T1(SniCV)) bpromedio

CAPACIDAD DE CALOR IDEAL (Cv)

CAPACIDAD DE CALOR IDEAL

IDEAL CV - SOLIDO -GAS

CALCULO DE LAS Sni (GASEOSO)

CALCULO DE COEFICIENTE DE COMPRESIBILIDAD (b 1)

CALCULO DE LAS Sni (GAS + SOLIDO)

(Q2 + T1(SniCV)) bpromedio

CAPACIDAD DE CALOR IDEAL (Cv)

CAPACIDAD DE CALOR IDEAL ( CV )

IDEAL CV - SOLIDO -GAS

CALCULO DE LAS Sni (GAS + SOLIDO)

CALCULO DE COEFICIENTE DE COMPRESIBILIDAD (b 1)

CALCULO DE LAS Sni (GASEOSO)

(Q2 + T1(SniCV)) bpromedio

CAPACIDAD DE CALOR IDEAL (Cv)

CAPACIDAD DE CALOR IDEAL

IDEAL CV - SOLIDO -GAS

CALCULO DE LAS Sni (GASEOSO)

CALCULO DE LAS Sni (GAS + SOLIDO)

CALCULO DE COEFICIENTE DE COMPRESIBILIDAD (b 1)

(Q2 + T1(SmiCV)) bpromedio

CAPACIDAD DE CALOR IDEAL