CALCULO DE LA PRESION DE VAPOR PARA SUSTANCIAS PURAS

ECUACION DE ANTOINE
log10 Pvap = A - [B / (T C + C)] bar
T=
No. =

40
14

Sustancia = Metilciclopentano

Constantes =
Valor Calculado:

A
4.18199
Pvap =
Pvap =

<---- Ingrese temperatura

<---- Ingrese No. de Sustancia
C6H12
B
1295.543

0.33751
253.1355924

C
238.39
bar
mm Hg

BASE DE DATOS
Ref: POLING, BRUCE; PRAUSNITZ, JOHN & O'CONNELL, JOHN.
"The Properties of Gases and Liquids". 5th edition. McGraw Hill. New York. 2001
No.
1

FORMULA
CH4

A
3.76870

B
395.744

C
266.681

Etano

C2 H6

3.95405

663.720

256.681

Propano

C3 H8

3.92828

803.997

247.040

n-Butano

C4H10

3.93266

935.773

238.789

n-Pentano

C5H12

3.97786

1064.840

232.014

n-Hexano

C6H14

4.00139

1170.875

224.317

n-Heptano

C7H16

4.02023

1263.909

216.432

n-Octano

C8H18

4.05075

1356.360

209.635

n-Nonano

C9H20

4.07356

1438.030

202.694

10

Isobutano

C4H10

4.00272

947.540

248.870

11

Isoctano

C8H18

4.03877

1335.220

213.415

12

Ciclopentano

C5H10

4.06783

1152.574

234.510

13

Ciclohexano

C6H12

3.93002

1182.774

220.618

14

Metilciclopentano

C6H12

4.18199

1295.543

238.390

15

Metilciclohexano

C7H14

3.98232

1290.968

223.701

16

Etileno

C2 H4

3.91382

596.526

256.370

17

Propileno

C3 H6

3.95606

789.624

247.580

18

1-Buteno

C4 H8

3.91780

908.800

238.540

19

cis-2-Buteno

C4 H8

4.00958

967.320

237.873

20

trans-2-Buteno

C4 H8

4.00827

967.500

240.840

21

1-Hexeno

C6H12

4.18199

1295.543

238.390

22

Isobutileno

C4 H8

3.80956

866.250

234.640

23

1,3-Butadieno

C4 H6

3.96640

927.210

238.630

Ciclohexeno

C6H10

24

SUSTANCIA
Metano

25

Acetileno

C2 H2

3.67374

528.670

228.790

26

Benceno

C6 H6

3.98523

1184.240

217.572

27

Tolueno

C7 H8

4.05004

1327.620

217.625

28

Etilbenceno

C8H10

4.06861

1415.770

212.300

29

Cumeno

C9H12

4.06112

1460.766

207.830

30

o-Xileno

C8H10

4.09789

1458.706

212.041

31

m-Xileno

C8H10

4.14051

1468.703

216.120

32

p-Xileno

C8H10

4.10494

1446.832

214.627

33

Estireno

C8 H8

34

Naftaleno

C10H8

4.13555

1733.710

201.859

35

Bifenilo

C12H10

4.18870

1841.480

185.150

36

Formaldehido

CH20

37

Acetaldehido

C2 H4 0

38

Acetato de Metilo

C3 H6 O 2

4.18621

1156.430

219.690

39

Acetato de Etilo

C4 H8 O 2

4.13361

1195.130

212.470

40

Acetona

C3 H6 O

4.21840

1197.010

228.060

41

Metil Etil Cetona

C4 H8 O

4.13860

1232.630

218.690

42

Eter dietlico

C4H10O

4.10962

1090.640

231.200

43

Eter metil t-butlico

C5H12O

3.83648

1052.470

210.880

44

Metanol

CH4O

5.20277

1580.080

239.500

45

Etanol

C2 H6 O

5.33675

1648.220

230.918

46

1-Propanol

C3 H8 O

4.99991

1512.940

205.807

47

1-Butanol

C4H10O

4.64930

1395.140

182.739

48

1-Hexanol

C6H14O

4.18948

1295.590

152.510

49

2-Propanol

C3 H8 O

5.24268

1580.920

219.610

50

Fenol

C6 H6 O

4.26960

1523.420

175.400

51

Etilenglicol

C2 H6 O 2

52

Acido Actico

C2 H4 O 2

4.54456

1555.120

224.650

53

Acido n-butrico

C4 H8 O 2

4.82340

1731.708

195.955

54

Acido Benzoico

C7 H6 O 2

55

Acetonitrilo

C2 H3 N

56

Metilamina

CH5N

4.54420

1050.660

237.830

57

Etilamina

C2 H7 N

4.43400

1102.880

232.450

58

Nitrometano

59

Tetracloruro de carbono

CCl4

4.10445

1265.632

232.148

60

Cloroformo

CHCl3

3.96288

1106.904

218.552

61

Diclorometano

CH2Cl2

4.07622

1070.070

223.240

62

Cloruro de metilo

CH3Cl

4.16533

920.860

245.580

63

Cloruro de etilo

C2H5Cl

4.09088

1020.630

237.570

64
65
66
67

Clorobenceno
Argn
Kriptn
Xenn

C6H5Cl
Ar
Kr
Xe

4.02012
3.74141
3.75560
3.76779

1378.790
304.227
416.380
566.282

211.700
267.320
264.450
258.660

CH3NO2

68
69

Helio 4
Hidrgeno

He
H2

1.68360
2.94928

8.155
67.508

273.710
275.700

70

Oxgeno

O2

3.81634

319.013

266.700

71

Nitrgeno

N2

3.61947

255.680

266.550

72
73
74

Cloro
Monxido de carbono
Dixido de carbono

Cl2
CO
CO2

4.06280
3.81912

861.340
291.743

246.330
267.996

75

Disulfuro de carbono

CS2

76

Sulfuro de hidrgeno

H2 S

4.22882

806.933

251.390

77

Dixido de Azufre

SO2

4.40720

999.900

237.190

78
79
80
81
82
83

Trixido de Azufre
Oxido Ntrico
Oxido Nitroso
Cloruro de hidrgeno
Cianuro de hidrgeno
Agua

SO3
NO
N2 O
HCl
CNH
H2 O

6.17575
5.86790
4.12884
4.29490

1735.310
682.939
654.260
745.780

236.500
268.270
247.160
258.880

5.11564

1687.537

230.170

84

Amonaco

NH3

4.48540

926.132

240.170

85

Acido Ntrico

86

Acido Sulfurico

HNO3
H2SO4

MODELO SIMTRICO: CONSTANTES PARA MEZCLAS BINARIAS

Rango de
Temperatura
[C]
Componente 1
Componente 2
B
Benceno
56.1 - 80.1
0.405
Metanol
56.1 64.0
0.56
Etil Eter
34.6 - 56.1
0.741
Acetona
Metanol
55.5 - 64.6
0.56
Ciclohexano
80
0.335
Benceno
Cloroformo
40
0.154
Tetracloruro de
Ciclohexano
50
0.094
carbono
2-Butanona
n-Hexano
50 - 70
1.22
Tolueno
76.4 - 110.7
1.757
Acetato de Etilo
71.7 - 78.3
0.896
Etanol
o-Xileno
136 - 144
0.0081
m-Xileno
136 - 139
0.0083
p-Xileno
136 - 138
0.0071
Etilbenceno
Acetato de Etilo
62.1 - 77.1
1.16
Acetato de Metilo
53.7 - 64.6
1.064
Tricloroetileno
65 - 87
1.946
2-Propanol
65 - 82
-0.0754
Metanol
Fuente: SANDLER, STANLEY. (1989). Chemical and Engineering Thermodynamics. John Wiley &
Sons. New York.
O`CONNELL, J. & HAILE, J.M. (2004). Thermodynamics: Fundamentals for Applications.
Cambridge University Press. Cambridge.

MODELO MARGULES: CONSTANTES PARA MEZCLAS BINARIAS

Componente 1

Acetona

Benceno
2-Butanona

Etanol
Metanol
n-Octano

1-Propanol

Componente 2
Benceno

Temperatura
[C]
57.7 76.5

A12
0.316

A21
0.461

Tetracloruro de carbono
Cloroformo
Metanol

56 70.8
57.5 64.4
55.3 64.6

0.764
-0.561
0.579

0.918
-0.84
0.618

Tetracloruro de carbono
Cloroformo
Metanol
n-Hexano
Cloroformo
Benceno
Ciclohexano
n-Hexano
Tolueno
Cloroformo
Etilbenceno
Benceno

76.6 79.9
62 79.2
58 78.6
68.6 77.9
62.9 79.7
67.9 76.9
65 - 74
58.1 78.3
77 110.6
53.5 - 63
125.7 136.2
77 97.2

0.0855
-0.167
1.71
0.516
-0.686
1.472
1.726
1.94
1.571
0.832
0.201
1.336

0.121
-0.236
2.293
0.365
-0.85
1.836
2.473
2.705
1.648
1.736
0.188
1.596

1-Propanol

2-Propanol
Tolueno

Etilbenceno
n-Hexano
Acetato de etilo
Acetona
Benceno
Acetato de etilo
Fenol

97 118.9
66.2 89.6
78 - 96
56.8 79.8
71.8 82.4
75.9 80.3
110.5 172.7

1.33
1.867
0.519
0.514
1.269
0.517
1.034

1.239
1.536
0.641
0.632
1.52
0.476
0.714

Fuente: O`Connell, John and J. Haille. (2004). Thermodynamics: Fundamentals for applications. Cambridge.

MODELO DE VAN LAAR: CONSTANTES PARA MEZCLAS BINARIAS

Componente 1

Componente 2

Temperatura
[C]

B12

B21

Acetaldehido
Acetona
Acetona
Acetona
Agua
Benceno
Bisulfuro de
Carbono
Bisulfuro de
Carbono
Etanol
Etanol
Etanol
Etil Acetato
Etil Acetato
Etil Eter
Isobutano
Isobutano
Isopropanol
Metanol
Metanol
Metil Acetato
n-Hexano
n-Propanol
Tetracloruro de
Carbono

Agua
Agua
Agua
Metanol
Fenol
Isopropanol

19.8 - 100
25
56.1 - 100
56.1 - 64.6
100 - 181
71.9 - 82.3

1.59
1.89
2.05
0.58
0.83
1.36

1.8
1.66
1.5
0.56
3.22
1.95

Acetona

39.5 - 56.1

1.28

1.79

Tetracloruro de
Carbono
Agua
Benceno
Ciclohexano
Benceno
Tolueno
Etanol
Furfural
Furfural
Agua
Agua
Agua
Agua
Etanol
Agua

46.3 - 76.7

0.23

0.16

25
67.0 - 80.1
66.3 - 80.8
71.1- 80.2
77.2 - 110.7
34.6 - 78.3
37.8
51.7
82.3 - 100
25
64.6 - 100
57.0 - 100
59.3 - 78.3
88.0 - 100

1.54
1.946
2.102
1.15
0.09
0.97
2.62
2.51
2.4
0.58
0.83
2.99
1.57
2.53

0.97
1.61
1.729
0.92
0.58
1.27
3.02
2.83
1.13
0.46
0.51
1.89
2.58
1.13

Benceno

76.4 - 80.2

0.12

0.11

Fuente: SANDLER, STANLEY.(1989). Chemical and Engineering Thermodynamics. John Wiley & Sons. New York.

ECUACIN DE WILSON: CONSTANTES PARA MEZCLAS BINARIAS

1
2
3
4
5
6
7
8
9
10

SISTEMA
Acetona (1)
Agua (2)
Metanol (1)
Agua (2)
1-Propanol (1)
Agua (2)
Agua (1)
1,4-Dioxano (2)
Metanol (1)
Acetonitrilo (2)
Acetona (1)
Metanol (2)
Metil acetato (1)
Metanol (2)
Metanol (1)
Benceno (2)
Etanol (1)
Tolueno (2)
Metanol (1)
Etanol (2)
Metanol (1)
11 1-Propanol (2)
Etanol (1)
12 1-Propanol (2)

VOLUMEN MOLAR
[cm3/mol]
74.05
18.07
40.73
18.07
75.14
18.07
18.07
85.71
40.73
66.3
74.05
40.73
79.84
40.73
40.73
89.41
58.68
106.85
40.73
58.68
40.73
75.14
58.68
75.14

PARMETROS
a12 [cal/mol]
a21 [cal/mol]
291.27

1,448.01

107.38

469.55

775.48

1,351.90

1,696.98

-219.39

504.31

196.75

-161.88

583.11

-31.19

813.18

1,734.42

183.04

1,556.45

210.52

-326.819

678.595

1846.612

-987.209

3108.881

-829.156

Ref.:
Smith, J.M.; Van Ness,H.C. & Abbott,M.M. 2001. Introduction to Chemical Engineering Thermodynamics. 6th edition.

Skouras, Stathis. En:

http://www.nt.ntnu.no/users/skoge/distillation/nonideal_skouras/ternary/wilson.m. July 2001

ECUACIN NRTL: CONSTANTES PARA MEZCLAS BINARIAS

SISTEMA
1
2
3
4
5

Acetona (1)
Agua (2)
Metanol (1)
Agua (2)
1-Propanol (1)
Agua (2)
Agua (1)
1,4-Dioxano (2)
Metanol (1)
Acetonitrilo (2)

VOLUMEN MOLAR
[cm3/mol]
74.05
18.07
40.73
18.07
75.14
18.07
18.07
85.71
40.73
66.3

PARMETROS NRTL
b12 [cal/mol]
b21 [cal/mol]
631.05

1,197.41

-253.88

845.21

500.4

1,636.57

715.96

548.9

343.7

314.59

6
7
8
9

Acetona (1)
Metanol (2)
Metil acetato (1)
Metanol (2)
Metanol (1)
Benceno (2)
Etanol (1)
Tolueno (2)

74.05
40.73
79.84
40.73
40.73
89.41
58.68
106.85

184.7

222.64

381.46

346.54

730.09

1,175.41

713.57

1,147.86

Ref.: Smith, J.M.; Van Ness,H.C. & Abbott,M.M. (2001). Introduction to Chemical Engineering Thermodynamics. 6th edition.

NARIAS

ETROS NRTL

0.5343
0.2994
0.5081
0.292
0.2981

0.3084
0.2965
0.4743
0.5292

modynamics. 6th edition.