1.

a) Kp = _(pNH3)^2 _
(pH2)^3(pN2)

b) (i) Q = .16580
(ii) Kp<Q, so the equation will go in reverse as there are more products that
will have to be reduced in order to achieve equilibrium.

c) 0.00031. Note: Kp should be equal Kc. They are, in reality, the same thing. If
no temp. changes, why should this?

d) Kp = .0083 = .0083/1

(i) Kp = 1/.0083 = 120.4819... This should be the answer as the equation is the
exact opposite of the first one. So, it is only logical to flip the reactants and
products in the original Kp equation as they are flipped in the equation.

(ii)2 x [NH3(g) + H2S(g) →← NH4HS(g)] Kp = (8.3 x 10^−3)2

N2(g) + 3 H2(g) →← 2 NH3(g) Kp = 3.1 °— 10−4
2 H2S(g) + N2(g) + 3 H2(g) →← 2 NH4HS(g) Kp = (8.3 x 10−3)2 (3.1 x 10^−4) =
2.1 x 10^−8

2. a) 85.7 g C x 1 mol C / 12.01 g C= 7.14 mol C

14.3 g H x 1 mol H/1.008 g H= 14.2 mol H
7.14 mol C/7.14= 1
14.2 mol H/7.14= 1.99
CH2= Emperical Formula

b) PV = nRT = mass/molar mass x RT

mass / V x RT / P= density x RT / P
molar mass = 2.0 g L−1 x
(0.0821 x (L atm / mol K) x 323 K) /0.948 atm

molar mass = 56 g mol−1