ANKAN

Cu 1 : Hn hp X gm metylamin (CH3NH2) v 2 ankan kh , c t khi so vi hiro l 18,65. t 2,24 lt hn hp X cn 8,68 lt O2. Cc th tch o iu kin tiu chun. Phn trm th tch metylamin trong hn hp X l : A. 40% B. 25% C. 30% D.36% Cu 2 : Ankan X v xicloankan Y c cng s cacbon. Dn xut iclo ca X c phn t khi bng 0,9407 phn t khi monobrom ca Y. t m gam hn hp R gm X v Y cn 3,528 m gam oxi. Phn trm khi lng ca Y trong hn hp R l : A. 38,125% B. 36,925% C. 39,625% D. 31,825% Cu 3 : t chy 1 ankan X vi lng oxi gp i lng cn dng , hn hp sn phm sau khi ngng t hi nc c hn hp Y c t khi so vi He l 64/7. Cng thc phn t ca X l : A. C7H16 B. C6H14 C. C5H12 D. C4H10 Cu 4 : X, Y, Z l 3 ankan ng ng k tip. Phn trm khi lng cacbon trong hn hp cng s mol gm X v Z l 83,72%. t 0,025 mol Y ri dn vo 400 ml dung dch hn hp A gm KOH 0,1M v Ba(OH)20,4M. Khi lng dung dch A tng hay gim bao nhiu gam? A. Gim 20,22 gam B. Tng 20,22 gam C. Gim 19,8 gam D. Tng 19,8 gam Cu 5 : t chy hon ton 0,56 lt butan (ktc) v cho sn phm chy hp th ht vo 400ml dung dch Ba(OH)2 a mol/l thy to thnh 11,82 gam kt ta. Gi tr ca a l: A. 0,08 M B. 0,1 M C. 0,15 M D. 0,2 M Cu 6 : t chy 1m3 kh t nhin c thnh phn th tch: 94,6% metan, 1% etan, 0,5% propan 3,9% nit cn mt th tch khng kh l: A. 3,982m3 B. 15,616m3 C. 7,808m3 D. 9,760 m3 Cu 7 : t chy hon ton 0,15 mol hn hp 2 ankan thu c 9,45g H2O. Cho sn phm chy vo dung dch Ca(OH)2 d th khi lng kt ta thu c l: A. 37,5g B. 52,5g C. 15g D. 42,5g Cu 8 : t chy hon ton m gam hirocacbon X thu c 3m gam CO2. Hp th ton b sn phm chy sau khi t m gam X vo 50 gam dung dch KOH 22,4% thu c dung dch Y c khi lng l 62,24 gam. Khi lng mui sinh ra trong dung dch Y l :

A. 16,38 gam B. 17,76 gam C. 18,76 gam D. 20,14 gam Cu 9 : Crackinh m gam butan thu c hn hp A gm 5 hirocacbon c =33,14 trong tng khi lng ankan l 13,15 gam v khi lng ca butan d bng 0,985 ln khi lng cc ankan cn li. Gi tr ca m l : A. 37,7 gam B. 31,9 gam C. 20,3 gam D. 26,1 gam Cu 10 : X l hn hp gm etan, propan v hiro. t chy hon ton 9,8 gam hn hp X sau dn ton b sn phm chy vo 100 gam dung dch H2SO4 98% th nng dung dch H2SO4 gim xung cn 83,05% , sau dn kh cn li vo dung dch Ca(OH)2 d thu c m gam kt ta. Tnh m? A.70 gam B.50 gam C.65 gam D.48 gam Cu 11 : Trn a gam hn hp X gm 2 hirocacbon C6H14 v C6H6 theo t l s mol (1:1) vi m gam mt hirocacbon D ri t chy hon ton th thu c v gam H2O. Gi tr m l : A. 2,75 gam. B. 3,75 gam. C. 5 gam. D. 3,5 gam. Cu 12 : t chay hoan toan m gam hn hp gm CH4, C3H6 va C4H10 bng 1 lng khng kh va thu c 10,8g H2O v 1 hn hp kh c t khi so vi hiro l 15 (coi nh khng kh ch gm 80% th tch N2 v cn li l O2). Gi tr ca m l : A. 2 B. 4 C. 6 D. 8. Cu 13 : t chy hon ton mt lng cht hu c cha C, H, Cl thu c 2,2 gam CO2; 0,9 gam H2O. Khi xc nh clo trong lng cht bng dung dch AgNO3 th thu c 14,35 gam AgCl. Cng thc phn t ca hp cht l A. C2H4Cl2. B. C3H6Cl2. C. CH2Cl2. D. CHCl3. Cu 14 : Hn hp X gm hai hirocacbon dng kh ng ng lin tip. T khi ca X so vi heli bng 5,4. Trn a mol CO vo b mol hn hp X thu c hn hp Y. t hn hp Y bng lng oxi va thu c hn hp kh v hi c t khi so vi H2 l c. Gi tr ca c tnh theo a v b l : A. B . C. D. Cu 15 :[b] [/b]Khi dn kh xiclopropan vo dung dch brom trong CCl4 s c hin tng: A. Dung dch brom khng b nht mu. B. S thy c s phn lp hai cht lng. C. Dung dch b nht mu dn. D. S thy dung dch b c v c to kt ta.

Cu 16 :[b] [/b]Khi nung nng m gam metan 1500oC, ri lm h nhit nhanh th thu c axetilen v kh hiro. em nung nng mt bnh kn cha metan, ri a v iu kin nh trc khi nung th p sut trong bnh tng gp 1,8 ln trong c 15 gam H2. Gi tr ca m l : A. 108 B. 112 C. 96 D. 100 Cu 17 :[b] [/b]Khi cho propan tc dng vi Br2 theo t l s mol 1 : 1, vi s hin din ca nh sng, th sn phm hu c thu c gm: A. mt dn xut monobrom ca propan c cng thc l C3H7Br B. mt sn phm chnh l 1-brompropan, mt sn phm ph l 2-brompropan C. sn phm nhiu hn l propyl bromua, sn phm t hn l isopropyl bromua D. sn phm nhiu l isopropyl bromua, sn phm t hn l propyl bromua Cu 18 :[b] [/b]t 0,25 mol hn hp X gm C5H12 , C6H8 v C6H14 cn 47,488 lt O2 (ktc). Khi lng C6H14 trong hn hp X l : A. 7,74 gam B. 6,88 gam C. 6,02 gam D. 6,45 gam Cu 19 :[b] [/b]A l mt cht hu c, khi chy ch to CO2 v nc. T khi hi ca A so vi hiro bng 36. A c bao nhiu cng thc phn t ph hp? A. 1 B. 2 C. 3 D. 4 Cu 20 :[b] [/b]X l hn hp gm propan, xiclopropan, butan v xiclobutan. t m gam hn hp X thu c 63,8 gam CO2 v 28,8 gam H2O. Thm 1 lng hiro va vo m gam hn hp X thc hin phn ng m vng (xc tc Ni, t0) thu c hn hp Y c t khi so vi H2 l 26,375. T khi ca hn hp X so vi H2 l A. 23,95 B. 25,75 C. 24,52 D. 22,89 Cu 21 :[b] [/b]Hn hp A gm 1 ankan v H2 c = 20,9u. t hn hp A bng lng oxi va thu c hn hp kh v hi c t khi so vi hiro l a. Gi tr ca a l : A. 11,584 B. 12,786 C. 14,273 D. 13,743 Cu 22 :[b] [/b]Oxi hon ton 0,224 lt (ktc) ca xicloankan X thu c 1,760 gam kh CO2. Bit X lm mt mu dung dch brom. X l : A. Xclopropan B. Xiclobutan C. Metylxiclopropan D. Metylxiclobutan

Cu 23 :[b] [/b]Hn hp X gm C4H10 v CO c t khi so vi hiro l 23,375. Thm 1 lng oxi vo hn hp X thu c hn hp Y c =34,36. Bt tia la in t chy t chy hn hp Y thu c hn hp kh v hi Z c t khi so vi hiro l a. Gi tr ca a l : A. 14,384 B. 15,026 C. 17,571 D. 16,125 Cu 24 :[b] [/b]Hn hp X gm dn xut th monoclo ca xiclopropan, propan v propen (CH3CH=CH2) c phn trm khi lng clo l 45,95%. Phn trm s mol dn xut th monoclo ca propan trong hn hp X l : A. 36,0% B. 38,1% C. 37,9% D. 38,5% Cu 25 :[b] [/b]Hn hp X gm 2 ankan ng ng k tip . Tch H2 t hn hp X thu c hn hp anken Y. t hn hp X bng lng oxi gp i lng cn dng sau ngng t hi nc thu c hn hp Z. T khi ca Z so vi Y l 0,983. Phn trm s mol ca ankan c phn t khi nh trong X l : A. 35,05% B. 64,95% C. 56,43% D. 43,57% Cu 26 :[b] [/b]Hn hp X gm xiclobutan v 1 ankan c t khi so vi hiro l 26,5. t 1 mol X cn 5,75 mol O2. Phn trm khi lng xiclobutan trong hn hp X l : A. 48,36% B. 75,00% C. 79,25% D. 50,00% Cu 27 :[b] [/b]Thc hin tch H2 t 1 ankan vi hiu sut 75% thu c hn hp X c t khi so vi hiro l 16,571. Thm 0,1 mol C2H4 vo m gam hn hp X thu c hn hp Y. t hn hp Y cn 32,928 lt O2 (ktc). Gi tr ca m l : A. 10,440 gam B. 10,296 gam C. 10,029 gam D. 9,360 gam Cu 28 : t chy hon ton 3,696 gam mt hirocacbon X, dn sn phm chy qua bnh ng dung dch nc vi trong. Sau phn ng thu c 2,8 gam kt ta v thy khi lng dung dch tng 14,336 gam. Cng thc phn t ca X l A. C3H8 B. C3H6 C. C4H10 D. C4H8 Cu 29 : X l mt hirocacbon. Khi t chy ht x mol X ri cho sn phm chy ln lt qua bnh (1) ng H2SO4 m c ri qua bnh (2) ng lng d dung dch xt. Khi lng bnh (1) tng 108x gam, cn bnh (2) tng 264x gam. S oxi ha mi nguyn t cacbon u bng s oxi ha trung bnh ca cacbon trong phn t. A l: A. Xiclobutan B. Xiclohexan C. Xiclopentan D. hexan Cu 30 : Propan tc dng kh clo vi s hin din ca nh sng theo t l mol 1 : 1. (1): y l mt phn ng th.

(2): y khng phi l phn ng oxi ha kh. (3): Sn phm hu c ch gm mt cht duy nht. (4): Thu c sn phm gm ba cht. (5): Thu c hai sn phm hu c vi t l nhiu t khc nhau. Cc sai l: A. (3), (4) B. (2), (3) C. (2), (3), (4) D. (3), (4) Cu 31 : X l mt xicloparafin mt vng. Hi X nng gp 3 ln so vi kh etilen. Khi cho X tc dng vi Cl2 theo t l mol 1 : 1, vi s hin din ca nh sng ch thu mt dn xut clo duy nht. X l: A. Metylxiclopentan B. Xiclohexan C. 1,4-imetylxiclobutan D. Xiclopentan Cu 32 : CFC l ch vit tt ca cc hp cht dn xut clo, flo ca ankan n gin (chlorofluorocarbon, cloflocacbon) nh CFCl3, CF2Cl2,..Trc y, cc hp cht CFC c dng lm cht sinh hn trong t lnh, bnh phun tia to sng cht lng, dung mi...Nhng Cng c Quc t ku gi t nm 1996 cm hon ton s dng CFC. Cc hp cht CFC b cm bi v: A. Cc loi hp cht ny rt c. B. Chng rt bn, lu b phn hy, s lm nhim mi trng. C. Cc hp cht ny rt d b phn hy, to thnh F2 l cht oxi ha rt mnh, d gy chy n, rt nguy him. D. Cc cht ny lm ph hy tng ozon ca kh quyn. Cu 33 : t 2,48 gam 2 ankan ng ng k tip cn 5,454 lt hn hp oxi v ozon (dktc) c t khi so vi hiro l 18,4 . Phn trm khi lng cc ankan trong hn hp u l : A. 53,34% v 46,66% B. 39,89% v 60,11% C. 48,16% v 51,84% D. 62,17% v 37,83% Cu 34 : Hy chn pht biu ng v gc hirocacbon:

A. Mi phn t hirocacbon b mt mt nguyn t ca mt nguyn t ta thu c gc hirocacbon. B. Gc hirocacbon l phn t hu c b mt mt nguyn t hiro. C. Gc hirocacbon l phn t b mt i mt nhm CH2. D. Khi tch mt hoc nhiu nguyn t hiro ra khi mt phn t hirocacbon ta c gc hidrocacbon. Cu 35 : Mt hn hp X gm etan v propan. t chy mt lng hn hp X ta thu c CO2 v hi H2O trong nguyn t oxi chim 78,51% khi lng. Thnh phn % theo th tch ca etan trong X l: A. 45,24% B. 18,52% C. 23,72% D. 25,00% Cu 36 : Xc nh sn phm chnh ca phn ng sau:CH3 CH(CH3)CH2CH3 + Cl2 A. (CH3)2CHCH(Cl)CH3 B. (CH3)2C(Cl)CH2CH3 C. (CH3)2CHCH2CH2Cl D. ClCH2C(CH3)CH2CH3 Cu 37 : Hp cht Y sau y c th to c bao nhiu dn xut monohalogen ?

A. 3 B. 4 C. 5 D. 6 Cu 38 : Khi clo ha mt ankan thu c hn hp 2 dn xut monoclo v 4 dn xut iclo . Cng thc cu to ca ankan l : A. CH3CH2CH3 B. (CH3)2CHCH2CH3 C. (CH3)2CHCH(CH3)2 D. CH3CH2CH2CH3 Cu 39 : Hn hp X gm etan, propan, butan c t khi so vi hiro l 22. t m gam hn hp X cn 5,6 lt O2(ktc). Dn hn hp sn phm vo 560 ml dung dch Ba(OH)2 x mol/l thu c 25,61 gam kt ta. Gi tr ca x l : A. 0,80 B. 0,75 C. 0,25 D. 0,50 Cu 40 : Khi t chy,t l T=s mol O2 : s mol CO2 trong dy ng ng ca ankan nm trong khong no? A. B. C. D. Cu 41 : Hn hp kh A cha mt ankan v mt monoxicloankan. T khi ca A i vi hiro l 26. t chy hon ton 2,496 g A ri hp th ht sn phm chy

vo dung dch Ba(OH)2 d, thu c 34,278 g kt ta. Cng thc phn t ca cc cht trong hn hp A l A. C4H10 v C3H6 B. CH4 v C4H8 C. C2H6 v C4H8 D. C3H8 v C4H8 Cu 42 : Hn hp kh X gm C3H9N v 2 ankan ng ng k tip . t chy 100 ml hn hp X thu c 260 ml CO2 v 375 ml hi H2O v V ml N2 (cc th tch o cng iu kin). Gi tr ca V l : A. 10 ml B. 15ml C. 30ml D. 25ml Cu 43 : A l mt hirocacbon. t chy ht mt lng A cn dng 3,36 gam O2. Cho hp th sn phm chy vo bnh (1) ng H2SO4 m c, v bnh (2) ng nc vi d. Khi lng bnh (1) tng thm 1,62 gam, trong bnh (2) c xut hin kt ta. A l: A. Propan B. Etan C. Metan D. Etilen C2H4 Cu 44 : X l mt monoxicloankan, khi t chy a mol X, thu c 5a mol CO2. X c th c bao nhiu cng thc cu to? A. 5 B. 4 C. 3 D. 6 Cu 45 : X l mt cht hu c. Oxi ha hon ton 9,45 g X, sn phm oxi ha ch gm CO2 v H2O. Cho hp th sn phm oxi ha vo bnh ng lng d dung dch Ba(OH)2, khi lng bnh tng 41,85g. Trong bnh c to 132,875g kt ta. T khi hi ca X so vi metan bng 5,25. Khi cho X tc dng vi Br2, un nng, ch thu mt dn xut monobrom duy nht. X khng cho c phn ng cng hiro. X l: A. Neopentan B. Xiclopentan C. Pentan D. Xiclohexan Cu 46 : A l mt hirocacbon. t chy ht 1 mol A thu c 5 mol CO2. S mol H2O trong sn phm chy > 5 mol. Khi cho A tc dng Cl2 theo t l mol 1 : 1 th ch thu mt sn phm hu c duy nht (ngoi ra cn c sn phm v c). A l: A. neopentan B. Isopentan C. pentan D. xiclopentan Cu 47 : t m gam hn hp 2 ankan cn p gam oxi thu c khi lng CO2 nhiu hn khi lng H2O l 1,343 m gam. Mi lin h gia p v m l : A. p=2,846m B. p=4,125m C. p=3,645m D. p=5,124m Cu 48 : Hn hp X gm CmH2n, CnH2m v CmHn c cng s mol v c t khi so

vi H2 l 23. t 0,21 mol hn hp sau hp th vo 200 gam dung dch NaOH a% thu c dung dch cha 2 mui c tng nng phn trm l 25,19%. Gi tr ca a l : A. 12% B. 18% C. 20% D. 16% Cu 49 : Thc hin phn ng cracking 11,2 lt butan (ktc), thu c hn hp A ch gm cc ankan v anken. Trong hn hp A c cha 4,35 gam mt cht X m khi t chy th thu c 6,72 lt CO2 (ktc) v 6,75 gam H2O. Hiu sut phn ng cracking butan l: A. 80% B. 85% C. 90% D. 95% Cu 50 : Pht biu no khng ng? A. Vi cng thc mt hirocacbon CxHy th tr s cc tiu ca y l bng 2 B. Tt c ankan u nh hn nc C. Trong cc ng ng ca metan: etan, propan, butan th butan d ha lng nht D. Hi nc nng hn khng kh
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