Balance de energa

1173 298
298 298
, 298
R
S E
Q m CpdT m CpdT H K P
| | | |
= + A +
| |
\ . \ .

} }

Hallando
298
,
R K
H

A

( ) ( ) ( )
( ) ( )
( )
298
298 298 2 298 298 298 2
298
298
,
, 10.309 10.309 10.309 10.309
, 10.309 296.8 350.5 205.2
, 10.309 442.1 4557600
R K prod react
R K s g s g
R K
R K
H H H
H H SO H ZnO H ZnS H O
H KJ KJ KJ
H KJ KJ
o |

A = A A
A = A + A A A
A =
A = =

Hallando
1173
298
S
m CpdT
| |
|
\ .

}

Para el ZnO


Multiplicando por su nmero de moles e integrando:
( )
( )
1173
3
1
298
3 2
1
1
10.309 22.38 10.04 10
1173
10.309 22.38 5.02 10
298
10.309 26043.87 / 268486.26
Q x T dT
Q T x T
Q Kmolx J mol KJ

= +
| |
= +
|
\ .
= =
}


Para el SO

( )
3 5
2
, 49.96 4.77 10 10.46 10
g
Cp SO x T x T

= +
Multiplicando por su nmero de moles e integrando:
( )
( )
1173
3 5 2
2
298
3 2 5 1
2
2
10.309 49.96 4.77 10 10.46 10
1173
10.309 49.96 2.385 10 +10.46x10 T
298
10.309 44166.46 / 455312.04
Q x T x T dT
Q T x T
Q Kmolx J mol KJ


= +
| |
= +
|
\ .
= =
}



0
0
( )
3
, 22.38 10.04 10
S
Cp ZnO x T

= +

Para el N

( )
3
2
, 27.87 4.27 10
g
Cp N x T

= +
Multiplicando por su nmero de moles e integrando:

( )
( )
1173
3
3
298
3 2
3
3
65.448 27.87 4.27 10
1173
65.448 27.87 2.135 10
298
65.448 27134.26 / 1775883.05
Q x T dT
Q T x T
Q Kmolx J mol KJ

= +
| |
= +
|
\ .
= =
}

Para el O
( )
3 5 2
2
, 29.96 4.18 10 1.67 10
g
Cp O x T x T

= +
Multiplicando por su nmero de moles e integrando:
( )
( )
1173
3 5 2
4
298
3 2 5 1
4
4
1.933 29.96 4.18 10 1.67 10
1173
1.933 29.96 2.09 10 1.67 10
298
1.933 28487.06 / 55065.49
Q x T x T dT
Q T x T x T
Q Kmolx J mol KJ


= +
| |
= + +
|
\ .
= =
}

1173
1 2 3 4
298
1173
298
1173
298
268486.26 455312.04 1775883.05 55065.49
2554746.84
S
S
S
m CpdT Q Q Q Q
m CpdT
m CpdT KJ
| |
= + + +
|
\ .
| |
= + + +
|
\ .
| |
=
|
\ .

}




Hallando P
( )
int
2
int
2
2
-1.5
0.25 900 100
.
2 1173 373
2 1 5 1 373 1173
11 34.56 800
1
ext
ext
T
P KA
S
W
K S m T C T C
m K
A rh r T K T K
A x x x T
A m T K
P
t t
t t
t
A
=
A
= A = = =

= + = =
= + A =
= = A =

=
( )
( )
2
800
.5
34.56
.
0.25
165888
K
W
x m
m K
m
P W

=

165888 3600
597196.8
J
P x seg
seg
P KJ
=
=

( ) ( )
( ) ( )
1173 298
298 298
, 298
2554746.84 0 4557600 597196.8
1405656.36
K K
R
K K
s e
Q m CpdT m CpdT H K P
Q KJ
Q KJ


= + + A +
= + + +
=

} }

Entradas Kmol KJ Salidas Kmol KJ
Calores sensibles Calores sensibles
Concentrado Calcina
ZnS 10.309 0 ZnO 10.309 268486.26
Aire Gases
O2 17.397 0 SO2 10.309 455312.04
N2 65.448 0 O2 1.933 55065.49
Calor producido N2 65.446 1775883.05
por las reacciones Perdidas de calor
exotrmica P 597196.8
Calor de oxidacin exceso de calor
ZnS ZnO 10.309 4557600 Q 1405656.36
Total 4557600 Total 4557600




0